Search Results - "Carlson, Robert M."
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Overcoming lability of extremely long alkane carbon–carbon bonds through dispersion forces
Published in Nature (London) (15-09-2011)“…Strength at length in carbon–carbon bonds The synthesis of alkane hydrocarbons containing extremely long carbon–carbon (C–C) bonds, the longest observed in…”
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2
Vertical-Substrate MPCVD Epitaxial Nanodiamond Growth
Published in Nano letters (08-03-2017)“…Color center-containing nanodiamonds have many applications in quantum technologies and biology. Diamondoids, molecular-sized diamonds have been used as seeds…”
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3
Sterically controlled mechanochemistry under hydrostatic pressure
Published in Nature (London) (22-02-2018)“…‘Molecular anvil’ molecules consisting of a compressible mechanophore and incompressible ligands react under hydrostatic pressure to produce elemental metal…”
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4
Stable Alkanes Containing Very Long Carbon–Carbon Bonds
Published in Journal of the American Chemical Society (22-08-2012)“…The metal-induced coupling of tertiary diamondoid bromides gave highly sterically congested hydrocarbon (hetero)dimers with exceptionally long central C–C…”
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5
Synthesis and Transformation of Linear Adamantane Assemblies inside Carbon Nanotubes
Published in ACS nano (23-10-2012)“…We report the assembly and thermal transformation of linear diamondoid assemblies inside carbon nanotubes. Our calculations and observations indicate that…”
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Evidence of Diamond Nanowires Formed inside Carbon Nanotubes from Diamantane Dicarboxylic Acid
Published in Angewandte Chemie International Edition (25-03-2013)“…Carbon is a girl′s best friend: Carbon‐based nanowires have been produced during thermal annealing of diamantane‐4,9‐dicarboxylic acid in carbon nanotubes…”
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Template Synthesis of Linear-Chain Nanodiamonds Inside Carbon Nanotubes from Bridgehead-Halogenated Diamantane Precursors
Published in Angewandte Chemie International Edition (07-09-2015)“…A simple method for the synthesis of linear‐chain diamond‐like nanomaterials, so‐called diamantane polymers, is described. This synthetic approach is primarily…”
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London Dispersion Directs On-Surface Self-Assembly of [121]Tetramantane Molecules
Published in ACS nano (26-09-2017)“…London dispersion (LD) acts between all atoms and molecules in nature, but the role of LD interactions in the self-assembly of molecular layers is still poorly…”
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Hybrid metal–organic chalcogenide nanowires with electrically conductive inorganic core through diamondoid-directed assembly
Published in Nature materials (01-03-2017)“…Controlling inorganic structure and dimensionality through structure-directing agents is a versatile approach for new materials synthesis that has been used…”
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10
Assigning the absolute configuration of single aliphatic molecules by visual inspection
Published in Nature communications (20-06-2018)“…Deciphering absolute configuration of a single molecule by direct visual inspection is the next step in compound identification, with far-reaching implications…”
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Ultralow effective work function surfaces using diamondoid monolayers
Published in Nature nanotechnology (01-03-2016)“…Air-stable monolayers of diamondoids can rival cesium's work-function-lowering ability and can dramatically increase field emission current through a radical…”
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Spatially resolved electronic and vibronic properties of single diamondoid molecules
Published in Nature materials (01-01-2008)“…Diamondoids are a unique form of carbon nanostructure best described as hydrogen-terminated diamond molecules. Their diamond-cage structures and tetrahedral…”
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13
Monochromatic Photocathodes from Graphene-Stabilized Diamondoids
Published in Nano letters (14-02-2018)“…The monochromatic photoemission from diamondoid monolayers provides a new strategy to create electron sources with low energy dispersion and enables compact…”
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14
Effects of Molecular Geometry on the Properties of Compressed Diamondoid Crystals
Published in The journal of physical chemistry letters (17-11-2016)“…Diamondoids are an intriguing group of carbon-based nanomaterials, which combine desired properties of inorganic nanomaterials and small hydrocarbon molecules…”
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15
Optical response of diamond nanocrystals as a function of particle size, shape, and symmetry
Published in Physical review letters (24-07-2009)“…The optical spectra of hydrogen-passivated diamond clusters (diamondoids) precisely defined in size and shape have been measured in the gas phase, i.e., under…”
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Origin of the Monochromatic Photoemission Peak in Diamondoid Monolayers
Published in Nano letters (01-01-2009)“…Recent photoemission experiments have discovered a highly monochromatized secondary electron peak emitted from diamondoid self-assembled monolayers on metal…”
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17
Functionalized Nanodiamonds: Triamantane and [121]Tetramantane
Published in Journal of organic chemistry (01-09-2006)“…The selective functionalizations of the fundamental hydrogen-terminated nanodiamonds triamantane 1, as well as the most symmetrical representative of the…”
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18
Covalent Attachment of Diamondoid Phosphonic Acid Dichlorides to Tungsten Oxide Surfaces
Published in Langmuir (06-08-2013)“…Diamondoids (nanometer-sized diamond-like hydrocarbons) are a novel class of carbon nanomaterials that exhibit negative electron affinity (NEA) and strong…”
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19
Selective Preparation of Diamondoid Phosphonates
Published in Journal of organic chemistry (06-06-2014)“…We present an effective sequence for the preparation of phosphonic acid derivatives of the diamondoids diamantane, triamantane, [121]tetramantane, and…”
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Near-Edge X-ray Absorption Fine Structure Spectroscopy of Diamondoid Thiol Monolayers on Gold
Published in Journal of the American Chemical Society (13-08-2008)“…Diamondoids, hydrocarbon molecules with cubic-diamond-cage structures, have unique properties with potential value for nanotechnology. The availability and…”
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