Search Results - "Campos, Jésus"

Cobalt Boryl Complexes: Enabling and Exploiting Migratory Insertion in Base-Metal-Mediated Borylation by Frank, René, Howell, James, Campos, Jésus, Tirfoin, Rémi, Phillips, Nicholas, Zahn, Stefan, Mingos, D. Michael P., Aldridge, Simon

“…Cobalt boryl complexes, which have only been sporadically reported, can be accessed systematically with remarkable (but controllable) variation in the nature…”
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Dihydrogen and Acetylene Activation by a Gold(I)/Platinum(0) Transition Metal Only Frustrated Lewis Pair by Campos, Jesús

“…The first example of a frustrated Lewis pair (FLP) solely constructed around transition metal centers is described in this work. We have focused on the…”
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Bimetallic cooperation across the periodic table by Campos, Jesús

“…Organometallic chemistry and its applications in homogeneous catalysis have been dominated by mononuclear transition-metal complexes. The catalytic performance…”
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N‐nacnac Stabilized Tetrelenes: Formation of an N,P‐Heterocyclic Germylene via C–C Bond Insertion by Do, Dinh Cao Huan, Protchenko, Andrey V., Vasko, Petra, Campos, Jésus, Kolychev, Eugene L., Aldridge, Simon

“…The use of an amino‐functionalized β‐diketiminate (“N‐nacnac”) ligand in low‐valent germanium chemistry is reported, with a view to comparison with…”
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Cooperativity in Transition Metal Tetrylene Complexes by Somerville, Rosie J., Campos, Jesús

“…Cooperative reactivity between transition metals and ligands, or between two metals, has created significant opportunities for the development of new…”
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Living Polymerization of Ethylene and Copolymerization of Ethylene/Methyl Acrylate Using “Sandwich” Diimine Palladium Catalysts by Allen, Kate E, Campos, Jesús, Daugulis, Olafs, Brookhart, Maurice

“…Cationic Pd­(II) catalysts incorporating bulky 8-p-tolylnaphthyl substituted diimine ligands have been synthesized and investigated for ethylene polymerization…”
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Efficient selective and atom economic catalytic conversion of glycerol to lactic acid by Sharninghausen, Liam S., Campos, Jesús, Manas, Michael G., Crabtree, Robert H.

“…The availability of glycerol is rapidly increasing due to the expanding biodiesel industry, which produces this polyol as the main waste material. Several…”
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A stable heavier group 14 analogue of vinylidene by Rit, Arnab, Campos, Jesús, Niu, Haoyu, Aldridge, Simon

“…Vinylidene (H 2 C=C) is a member of the family of compounds of composition CH (and isomeric with ethyne, HC≡CH), but it has been observed only transiently—with…”
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Catalytic Borylation using an Air-Stable Zinc Boryl Reagent: Systematic Access to Elusive Acylboranes by Campos, Jesús, Aldridge, Simon

“…The use of borylzinc reagents in palladium‐catalyzed borylation chemistry is described (i.e. a boron analogue of the Negishi coupling), including a one‐pot…”
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Electrochemical Activation of Cp Iridium Complexes for Electrode-Driven Water-Oxidation Catalysis by Thomsen, Julianne M, Sheehan, Stafford W, Hashmi, Sara M, Campos, Jesús, Hintermair, Ulrich, Crabtree, Robert H, Brudvig, Gary W

“…Organometallic iridium complexes bearing oxidatively stable chelate ligands are precursors for efficient homogeneous water-oxidation catalysts (WOCs), but…”
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Methanol Dehydrogenation by Iridium N‑Heterocyclic Carbene Complexes by Campos, Jesús, Sharninghausen, Liam S, Manas, Michael G, Crabtree, Robert H

“…A series of homogeneous iridium bis­(N-heterocyclic carbene) catalysts are active for three transformations involving dehydrogenative methanol activation:…”
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Catalytic B–N Dehydrogenation Using Frustrated Lewis Pairs: Evidence for a Chain-Growth Coupling Mechanism by Mo, Zhenbo, Rit, Arnab, Campos, Jesús, Kolychev, Eugene L, Aldridge, Simon

“…The catalytic dehydrogenation of ammonia- and amine-boranes by a dimethylxanthene-derived frustrated Lewis pair is described. Turnover is facilitated on a…”
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Facile Reversibility by Design: Tuning Small Molecule Capture and Activation by Single Component Frustrated Lewis Pairs by Mo, Zhenbo, Kolychev, Eugene L, Rit, Arnab, Campos, Jesús, Niu, Haoyu, Aldridge, Simon

“…A series of single component FLPs has been investigated for small molecule capture, with the finding that through tuning of both the thermodynamics of…”
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A Cavity-Shaped Gold(I) Fragment Enables CO2 Insertion into Au–OH and Au–NH Bonds by Navarro, Miquel, Holzapfel, Markus, Campos, Jesús

“…A cavity-shaped linear gold­(I) hydroxide complex acts as a platform to access unusual gold monomeric species. Notably, this sterically crowded gold fragment…”
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Small molecule activation with bimetallic systems: a landscape of cooperative reactivity by Navarro, Miquel, Moreno, Juan José, Pérez-Jiménez, Marina, Campos, Jesús

“…There is growing interest in the design of bimetallic cooperative complexes, which have emerged due to their potential for bond activation and catalysis, a…”
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Rhodium and Iridium Complexes of Bulky Tertiary Phosphine Ligands. Searching for Isolable Cationic MIII Alkylidenes by Campos, Jesús, Carmona, Ernesto

“…Cyclometalated chloride complexes of rhodium and iridium based on (η5-C5Me5)­MIII fragments that result from the metalation of the xylyl substituent of a…”
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A Phase 2 Trial of Peresolimab for Adults with Rheumatoid Arthritis by Tuttle, Jay, Drescher, Edit, Simón-Campos, Jesus Abraham, Emery, Paul, Greenwald, Maria, Kivitz, Alan, Rha, Hyungmin, Yachi, Pia, Kiley, Christina, Nirula, Ajay

“…In this phase 2 placebo-controlled trial, peresolimab, a humanized monoclonal antibody that stimulates the programmed cell death protein 1 inhibitory pathway,…”
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Do transition metal sigma complexes of main group metal E–C bonds exist? by Pérez-Jiménez, Marina, Campos, Jesús

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Reactivity of [Pt(P t Bu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity by Hidalgo, Nereida, Romero-Pérez, Carlos, Maya, Celia, Fernández, Israel, Campos, Jesús

“…Metal-only Lewis pairs (MOLPs) based on zinc electrophiles are particularly interesting due to their relevance to Negishi cross-coupling reactions. Zinc-based…”
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Evaluation of the use of chamomile in isolation and in association with laser photobiomodulation in the healing of rats oral mucosa by Fortuna, Tila, Dantas, Juliana Borges, Santana, Rejane Conceição, Della Cella, Hortência Resende, de Jesus Campos, Elisângela, Martins, Gabriela Botelho

“…Laser photobiomodulation (LPBM) has been shown to be one of the possible modulating agents of inflammation. Similarly, medicinal plants, such as chamomile…”
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