Search Results - "Camasso, Nicole M"

Design, synthesis, and carbon-heteroatom coupling reactions of organometallic nickel(IV) complexes by Camasso, Nicole M., Sanford, Melanie S.

“…Homogeneous nickel catalysis is used for the synthesis of pharmaceuticals, natural products, and polymers. These reactions generally proceed via nickel…”
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Role of Silver Salts in Palladium-Catalyzed Arene and Heteroarene C–H Functionalization Reactions by Lotz, Monica D, Camasso, Nicole M, Canty, Allan J, Sanford, Melanie S

“…Silver carboxylate salts are widely used as additives in palladium-catalyzed C–H functionalization reactions. However, the role of these silver additives is…”
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Nickel(IV)-Catalyzed C–H Trifluoromethylation of (Hetero)arenes by Meucci, Elizabeth A, Nguyen, Shay N, Camasso, Nicole M, Chong, Eugene, Ariafard, Alireza, Canty, Allan J, Sanford, Melanie S

“…This Article describes the development of a stable NiIV complex that mediates C­(sp2)–H trifluoro­methylation reactions. This reactivity is first demonstrated…”
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Carbon–Carbon Bond-Forming Reductive Elimination from Isolated Nickel(III) Complexes by Bour, James R, Camasso, Nicole M, Meucci, Elizabeth A, Kampf, Jeff W, Canty, Allan J, Sanford, Melanie S

“…This manuscript describes the design, synthesis, characterization, and reactivity studies of organometallic NiIII complexes of general structure…”
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Experimental and Computational Studies of High-Valent Nickel and Palladium Complexes by Camasso, Nicole M, Canty, Allan J, Ariafard, Alireza, Sanford, Melanie S

“…This article describes a detailed comparison of the organometallic chemistry of high-valent nickel and palladium model complexes supported by…”
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Oxidation of Ni(II) to Ni(IV) with Aryl Electrophiles Enables Ni-Mediated Aryl–CF3 Coupling by Bour, James R, Camasso, Nicole M, Sanford, Melanie S

“…This communication describes the synthesis and reactivity of NiIV(aryl)­(CF3)2 complexes supported by tris­pyrazolyl­borate and 4,4′-di-tert-butyl­bipyridine…”
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C(sp³)-O bond-forming reductive elimination from Pd(IV) with diverse oxygen nucleophiles by Camasso, Nicole M, Pérez-Temprano, Mónica H, Sanford, Melanie S

“…This article describes an investigation of C(sp(3))-O bond-forming reductive elimination reactions from Pd(IV) complexes. Phenoxide, acetate, difluoroacetate,…”
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Impact of Oxidation State on Reactivity and Selectivity Differences between Nickel(III) and Nickel(IV) Alkyl Complexes by Roberts, Courtney C., Camasso, Nicole M., Bowes, Eric G., Sanford, Melanie S.

“…Described is a systematic comparison of factors impacting the relative rates and selectivities of C(sp3)−C and C(sp3)−O bond‐forming reactions at high‐valent…”
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Impact of Oxidation State on Reactivity and Selectivity Differences between Nickel(III) and Nickel(IV) Alkyl Complexes by Roberts, Courtney C., Camasso, Nicole M., Bowes, Eric G., Sanford, Melanie S.

“…Described is a systematic comparison of factors impacting the relative rates and selectivities of C(sp3)−C and C(sp3)−O bond‐forming reactions at high‐valent…”
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C(sp 3 )–O Bond-Forming Reductive Elimination from Pd IV with Diverse Oxygen Nucleophiles by Camasso, Nicole M., Pérez-Temprano, Mónica H., Sanford, Melanie S.

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An Organometalllic Ni IV Complex That Participates in Competing Transmetalation and C(sp 2 )–O Bond-Forming Reductive Elimination Reactions by Meucci, Elizabeth A., Camasso, Nicole M., Sanford, Melanie S.

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Oxidation of Ni(II) to Ni(IV) with Aryl Electrophiles Enables Ni-Mediated Aryl–CF 3 Coupling by Bour, James R., Camasso, Nicole M., Sanford, Melanie S.

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Impact of Oxidation State on Reactivity and Selectivity Differences between NiIII and NiIV Alkyl Complexes by Roberts, Courtney C, Camasso, Nicole M, Bowes, Eric G, Sanford, Melanie

“…This report describes a systematic comparison of factors impacting the relative rates and selectivities of C(sp3)-C and C(sp3)-O bond-forming reactions at high…”
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An Organometalllic NiIV Complex That Participates in Competing Transmetalation and C(sp2)–O Bond-Forming Reductive Elimination Reactions by Meucci, Elizabeth A, Camasso, Nicole M, Sanford, Melanie S

“…This communication describes the synthesis of an organometallic NiIV complex bearing a labile trifluoroacetate (OTFA) ligand via the oxidation of a NiII…”
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C(sp3)–O Bond-Forming Reductive Elimination from PdIV with Diverse Oxygen Nucleophiles by Camasso, Nicole M, Pérez-Temprano, Mónica H, Sanford, Melanie S

“…This article describes an investigation of C­(sp3)–O bond-forming reductive elimination reactions from PdIV complexes. Phenoxide, acetate, difluoroacetate,…”
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