Search Results - "Calter, Michael A"
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Asymmetric Total Syntheses of (−)-Variabilin and (−)-Glycinol
Published in Organic letters (15-07-2011)“…Total syntheses of (−)-variabilin and (−)-glycinol have been accomplished, using the catalytic, asymmetric “interrupted” Feist–Bénary reaction (IFB) as the…”
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2
Catalytic, Asymmetric, “Interrupted” Feist−Bénary Reactions
Published in Journal of the American Chemical Society (26-10-2005)“…Pyrimidine derivatives of the cinchona alkaloids function as excellent asymmetric catalysts for the “Interrupted” Feist−Bénary Reaction. This reaction produces…”
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3
Catalytic, Asymmetric Preparation of Ketene Dimers from Acid Chlorides
Published in Organic letters (27-11-2003)“…The cinchona alkaloid-catalyzed dimerization of monosubstituted ketenes generated in situ from the reaction of acid chlorides and diisopropylethylamine yields…”
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Catalytic, Asymmetric, Aldol/O‑Conjugate Addition Sequence for the Construction of Highly Substituted Furanoids
Published in Organic letters (20-03-2015)“…A new method for the enantioselective synthesis of highly functionalized dihydrofurans has been developed. This process, related to the interrupted…”
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Catalytic, Asymmetric Michael Reactions of Cyclic Diketones with β,γ-Unsaturated α-Ketoesters
Published in Organic letters (21-05-2009)“…Newly synthesized cinchona alkaloid-derived pyrimidines function as effective asymmetric catalysts for the Michael reaction between cyclic diketones and…”
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Scope and Diastereoselectivity of the “Interrupted” Feist−Bénary Reaction
Published in Organic letters (24-01-2002)“…The base-promoted condensation of β-dicarbonyl compounds with α-haloketones, the Feist−Bénary reaction, conveniently produces highly substituted dihydrofurans…”
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Catalytic, asymmetric, interrupted Feist-Bénary reactions of α-tosyloxyacetophenones
Published in Organic letters (02-12-2011)“…A new variant of the Interrupted Feist-Bénary (IFB) reaction uses α-tosyloxyacetophenones as electrophiles and proceeds in good yields and excellent…”
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Rapid Synthesis of the 7-Deoxy Zaragozic Acid Core
Published in Organic letters (24-01-2002)“…We have developed an efficient synthesis of the 7-deoxy zaragozic acid core. The synthesis begins with a Feist−Bénary reaction that assembles all three carbons…”
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Synthesis of the C21–C34-segment of the aplyronines using the dimer of methylketene
Published in Tetrahedron (01-08-2002)Get full text
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10
Synthesis of the C1–C27 portion of the aplyronines
Published in Tetrahedron letters (01-06-2004)Get full text
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Immobilized Enzymes as Catalytically-Active Tools for Nanofabrication
Published in Journal of the American Chemical Society (16-10-2002)“…One efficient strategy for creating nanostructures on surfaces is to use the catalytic properties of a surface molecule. This strategy benefits from the…”
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One-Pot, Catalytic, Asymmetric Syntheses of All Four Stereoisomers of a Dipropionate Synthon
Published in Journal of organic chemistry (07-08-1998)Get full text
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13
Fundamentals of Asymmetric Catalysis
Published in Journal of the American Chemical Society (29-04-2009)Get full text
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14
Formation of Disubstituted β-Lactones Using Bifunctional Catalysis
Published in Organic letters (28-04-2005)“…Acid chlorides and aromatic aldehydes react in the presence of a stoichiometric amount of a tertiary amine and catalytic amounts of a cinchona alkaloid…”
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15
First Total Synthesis of a Natural Product Containing a Chiral, β-Diketone: Synthesis and Stereochemical Reassignment of Siphonarienedione and Siphonarienolone
Published in Journal of the American Chemical Society (06-11-2002)“…The first total syntheses of siphonarienolone and siphonarienedione are described. The development of a stereoselective synthesis of β-diketones facilitated…”
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Catalytic, Asymmetric Dimerization of Methylketene
Published in Journal of organic chemistry (15-11-1996)Get full text
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Catalytic Asymmetric Synthesis of Quaternary Carbon Centers. Exploratory Studies of Intramolecular Heck Reactions of (Z)-α,β-Unsaturated Anilides and Mechanistic Investigations of Asymmetric Heck Reactions Proceeding via Neutral Intermediates
Published in Journal of the American Chemical Society (08-07-1998)“…Intramolecular Heck reactions of seven (Z)-α,β-unsaturated 2-iodoanilides catalyzed by Pd−BINAP were surveyed using two reaction conditions: (1)…”
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Catalytic, Asymmetric Synthesis of the C1 ‘−C10 ‘ Segment of Pamamycin 621A
Published in Organic letters (01-06-2000)“…This paper describes a catalytic, asymmetric approach to the C1 ‘−C10 ‘ segment of pamamycin 621A. We synthesize this segment in a convergent manner, with each…”
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Catalytic, Asymmetric Synthesis and Diastereoselective Aldol Reactions of Dipropionate Equivalents
Published in Journal of organic chemistry (20-02-2004)“…The dimer of methylketene can be conveniently prepared in one step and high enantiomeric excess from propionyl chloride, using a catalytic amount of a…”
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20
The direct aldol reaction using bifunctional catalysts
Published in Tetrahedron letters (21-07-2003)“…In this paper, we describe an approach to the direct aldol reaction using a bifunctional catalyst containing Lewis acidic and basic functional groups. To…”
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