Search Results - "Cai, Li‐Xuan"
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Water-Soluble Redox-Active Cage Hosting Polyoxometalates for Selective Desulfurization Catalysis
Published in Journal of the American Chemical Society (11-04-2018)“…Transformations within container-molecules provide a good alternative between traditional homogeneous and heterogeneous catalysis, as the containers themselves…”
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Adaptive self-assembly and induced-fit transformations of anion-binding metal-organic macrocycles
Published in Nature communications (16-06-2017)“…Container-molecules are attractive to chemists due to their unique structural characteristics comparable to enzymes and receptors in nature. We report here a…”
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Combinatorial Self‐Assembly of Coordination Cages with Systematically Fine‐Tuned Cavities for Efficient Co‐Encapsulation and Catalysis
Published in Angewandte Chemie International Edition (15-08-2022)“…Controllable arrangement of different ligands in a single assembly will not only bring increased complexity but also offers a new route to fine‐tune the…”
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Guest-Driven Self-Assembly and Chiral Induction of Photofunctional Lanthanide Tetrahedral Cages
Published in Journal of the American Chemical Society (09-03-2022)“…Chiral luminescent lanthanide–organic cages have many potential applications in enantioselective recognition, sensing, and asymmetric catalysis. However, due…”
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Counteranion-mediated efficient iodine capture in a hexacationic imidazolium organic cage enabled by multiple non-covalent interactions
Published in Nature communications (28-09-2023)“…Developing efficient adsorbents to capture radioactive iodine produced from nuclear wastes is highly desired. Here we report the facial synthesis of a…”
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An Organo‐Palladium Host Built from a Dynamic Macrocyclic Ligand: Adaptive Self‐Assembly, Induced‐Fit Guest Binding, and Catalysis
Published in Angewandte Chemie International Edition (17-10-2022)“…Artificial hosts with rich conformational dynamics are attractive to supramolecular chemists due to their adaptive guest‐binding properties and enzyme‐like…”
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Self‐Assembled Bright Luminescent Lanthanide‐Organic Polyhedra for Ratiometric Temperature Sensing
Published in Chemistry : a European journal (11-05-2018)“…Luminescent lanthanide‐containing compounds have a lot of stimulating applications. However, the fine‐tuning of the optical properties of multi‐nuclear…”
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Guest‐Reaction Driven Cage to Conjoined Twin‐Cage Mitosis‐Like Host Transformation
Published in Angewandte Chemie International Edition (21-12-2020)“…We report here a guest‐reaction‐induced mitosis‐like host transformation from a known Pd4L2 cage 1 to a conjoined Pd6L3 twin‐cage 2 featuring two separate…”
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From a mononuclear FeL2 complex to a Fe4L4 molecular square: Designed assembly and spin-crossover property
Published in Nano research (01-02-2021)“…By introduction of a new Fe(L 1 ) 2 spin-crossover (SCO) unit into the polynuclear system, a nano-scale Fe 4 (L 2 ) 4 molecular square architecture is designed…”
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10
Designing a highly stable coordination-driven metallacycle for imaging-guided photodynamic cancer theranostics
Published in Chemical science (Cambridge) (14-08-2020)“…Coordination-driven self-assembly features good predictability and directionality in the construction of discrete metallacycles and metallacages with…”
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Self-Assembly of a Tetraphenylethylene-Based Capsule Showing Both Aggregation- and Encapsulation-Induced Emission Properties
Published in Inorganic chemistry (02-04-2018)“…Functional molecular capsules have attracted a lot of attention in recent years because of their potential applications as chemosensors, catalysis, drug…”
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Ionic Radius Dependent Kinetic Behavior for the Self‐Assemblyand Chiral Amplification of Lanthanide Tetrahedral Cages
Published in Chinese journal of chemistry (01-04-2023)“…Comprehensive Summary Understanding the kinetic process during the self‐assembly and chiral amplification of metal‐organic polyhedra (MOPs) is critical for the…”
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Coordination‐Assembled Lanthanide‐Organic Ln3L3 Sandwiches or Ln4L4 Tetrahedron: Structural Transformation and Luminescence Modulation
Published in Chinese journal of chemistry (01-07-2019)“…Summary of main observation and conclusion Photo‐functional supramolecular lanthanides assemblies have shown great potential in the materials and biomedical…”
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14
Polycatenation-Driven Self-Assembly of Nanoporous Frameworks Based on a 1D Ribbon of Rings: Regular Structural Evolution, Interpenetration Transformation, and Photochemical Modification
Published in Chemistry : a European journal (24-02-2014)“…A series of nanoporous frameworks constructed by a polycatenated isoreticular 1D ribbon of rings have been developed. The orientation of catenated ribbons can…”
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Targeted Functionalization of Porous Materials for Separation of Alcohol/Water Mixtures by Modular Assembly
Published in Chemistry : a European journal (03-11-2014)“…Three isoreticular hydrogen‐bonded frameworks with functionalized pore structures were constructed by a modular self‐assembly process in which a series of…”
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Reversible luminescence switching between single and dual emissions of bipyridinium-type organic crystals
Published in Chemical communications (Cambridge, England) (01-01-2012)“…An excitation-wavelength-dependent luminescence behavior of a bipyridinium derivative, together with its luminescence switching between single- and…”
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Photooxidase Mimicking with Adaptive Coordination Molecular Capsules
Published in Journal of the American Chemical Society (06-10-2021)“…One important feature of enzyme catalysis is the induced-fit conformational change after binding substrates. Herein, we report a biomimetic water-soluble…”
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Hexameric Lanthanide–Organic Capsules with Tertiary Structure and Emergent Functions
Published in Journal of the American Chemical Society (28-04-2021)“…Biological macromolecules always function through a collective behavior of the aggregated constituents, which usually are self-assembled together via…”
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Coordination-Assembled Water-Soluble Anionic Lanthanide Organic Polyhedra for Luminescent Labeling and Magnetic Resonance Imaging
Published in Journal of the American Chemical Society (23-09-2020)“…Lanthanide-containing functional complexes have found a variety of applications in materials science and biomedicine because of their unique electroptical and…”
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Controlled Self-Assembly and Multistimuli-Responsive Interconversions of Three Conjoined Twin-Cages
Published in Journal of the American Chemical Society (03-02-2021)“…Stimuli-responsive structural transformations between discrete coordination supramolecular architectures not only are essential to construct smart functional…”
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