Search Results - "Cadenbach, Thomas"
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Enhanced Visible-Light Photocatalytic Activity of Bismuth Ferrite Hollow Spheres Synthesized via Evaporation-Induced Self-Assembly
Published in Molecules (Basel, Switzerland) (01-08-2024)“…Semiconductor hollow spheres have garnered significant attention in recent years due to their unique structural properties and enhanced surface area, which are…”
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Hydrothermal Synthesis of Bismuth Ferrite Hollow Spheres with Enhanced Visible-Light Photocatalytic Activity
Published in Molecules (Basel, Switzerland) (29-06-2023)“…In recent years, semiconductor hollow spheres have gained much attention due to their unique combination of morphological, chemical, and physico-chemical…”
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Zincate-Mediated Arylation Reactions of Acridine: Pre- and Postarylation Structural Insights
Published in Organometallics (08-06-2015)“…This study explores the synthetic utility of homo(aryl) lithum zincate reagents [LiZnPh3] (2) and [Li2ZnPh4] (3), made by cocomplexation of variable amounts…”
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Nanocasting synthesis of BiFeO3 nanoparticles with enhanced visible-light photocatalytic activity
Published in Beilstein journal of nanotechnology (07-12-2020)“…In this work, monodisperse BiFeO 3 nanoparticles with a particle diameter of 5.5 nm were synthesized by a nanocasting technique using mesoporous silica SBA-15…”
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Macrocyclic Platforms for the Construction of Tetranuclear Oxo and Hydroxo Zinc Clusters
Published in Organometallics (08-06-2015)“…The design of ligands that can act as platforms for the controlled, “bottom-up” synthesis of transition-metal clusters is a promising approach to accessing…”
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Twelve One-Electron Ligands Coordinating One Metal Center: Structure and Bonding of [Mo(ZnCH₃)₉(ZnCp)₃]
Published in Angewandte Chemie (International ed.) (01-01-2008)“…Surrounded by zinc: The reaction of [Mo(GaCp*)6] and Zn(CH3)2 zinc yields the exceptionally high‐coordinate title compound (see picture; Mo red, Zn green, C…”
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Co-complexation Syntheses, Structural Characterization, and DFT Studies of a Novel Series of Polymeric Alkali-Metal Tetraorganogallates
Published in Organometallics (28-01-2013)“…Exploring the co-complexation reactions between the gallium alkyl Ga(CH2SiMe3)3 and alkali-metal alkyl MCH2SiMe3 (M = Li, Na, or K) using an arene/hexane…”
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Methylgallium as a Terminal Ligand in [(CpGa)₄Rh(GaCH₃)]
Published in Angewandte Chemie (International ed.) (21-04-2008)“…The smallest possible gallium alkyl species, the otherwise elusive GaCH3, has been generated by protolytic cleavage of Cp*H from a coordinated a {Ga(CH3)Cp*}…”
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Molecular Alloys: Experimental and Theoretical Investigations on the Substitution of Zinc by Cadmium and Mercury in the Homologous Series [Mo(M′R)12] and [M(M′R)8] (M=Pd, Pt; M′=Zn, Cd, Hg)
Published in Chemistry : a European journal (03-12-2010)“…The synthesis and structural characterization of novel, metal‐rich, highly coordinated compounds [Mo(M′R)12] and [M(M′R)8] (M: Pd, Pt, Mo; M′: Zn, Cd; R:…”
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Homoleptic Hexa and Penta Gallylene Coordinated Complexes of Molybdenum and Rhodium
Published in Inorganic chemistry (20-06-2011)“…The reactions of molybdenum(0) and rhodium(I) olefin containing starting materials with the carbenoid group 13 metal ligator ligand GaR (R = Cp*, DDP; Cp* =…”
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Substituent-Free Gallium by Hydrogenolysis of Coordinated GaCp: Synthesis and Structure of Highly Fluxional [Ru₂(Ga)(GaCp)₇(H)₃]
Published in Angewandte Chemie (International ed.) (01-01-2009)“…All change: Complete ligand exchange through the hydrogenation of [Ru(η⁴-cod)(η⁶-cot)] in the presence of GaCp* under mild conditions leads to the title…”
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Syntheses and Crystal Structures of Ruthenium and Rhodium Olefin Complexes Containing GaCp
Published in Inorganic chemistry (01-06-2009)“…The reactivity of olefin containing complexes of the d8 metals Ru0 and RhI toward GaCp* and AlCp* is presented. [Ru(η4-butadiene)(PPh3)3] reacts with GaCp* to…”
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"Naked" Ga+ and In+ as Pure Acceptor Ligands: Structure and Bonding of [GaPt(GaCp)4][BArF]
Published in Angewandte Chemie International Edition (04-08-2006)“…In the buff: The reaction of [Pt(GaCp*)4] with the Ga+ source [Ga2Cp*][BArF] (Cp*=C5Me5; BArF=B{C6H3(3,5‐CF3)2}4) leads to the title complex, which exhibits a…”
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The [Ga2(C5Me5)]+ Ion: Bipyramidal Double-Cone Structure and Weakly Coordinated, Monovalent Ga+
Published in Angewandte Chemie International Edition (06-02-2006)“…Partial protolysis of GaCp* with [H(OEt2)2]+[BArF]− afforded the GaI compound [Ga2Cp*]+[BArF]− (see structure). Experimental and computational studies confirm…”
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Organometallic Chemistry of Ga+: Formation of an Unusual Gallium Dimer in the Coordination Sphere of Ruthenium
Published in Chemistry : a European journal (26-11-2008)“…New insights into the distinct organometallic chemistry of the Ga+ ion are presented. Ga+ reacts as a strong electrophile with the electron rich ligand…”
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Nickel Olefin Complexes Supported by GaI(DDP)
Published in Organometallics (13-08-2007)“…The reactions of the low-valent group 13 bis-imidinate ligand Ga(DDP) [DDP = 2-{(2,6-diisopropylphenyl)amino}-4-{(2,6-diisopropylphenyl)imino}-2-pentene] with…”
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Adsorption enhanced photocatalytic degradation of Rhodamine B using GdxBi1-xFeO3@SBA-15 (x= 0, 0.05, 0.10, 0.15) nanocomposites under visible light irradiation
Published in Ceramics international (15-10-2021)“…BiFeO3 nanomaterials have recently generated much interest due to their relatively narrow band gap energies (~2.0–2.8 eV), their stability and low cost which…”
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Synthesis and Characterization of the Novel AlI Compound Al(C5Me4Ph): Comparison of the Coordination Chemistry of Al(C5Me5) and Al(C5Me4Ph) at d10 Metal Centers1
Published in Zeitschrift für anorganische und allgemeine Chemie (1950) (01-10-2005)“…The synthesis of the novel AlI compound AlCp*Ph (Cp*Ph = C5Me4Ph) is presented. This compound is characterized by 1H, 13C, 27Al NMR spectroscopy, elemental…”
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Synthesis of doped and undoped Bi1-xMxFeO3 porous networks (M = La, Gd, Nd; x = 0, 0.03, 0.05, 0.10) with enhanced visible-light photocatalytic activity
Published in Journal of photochemistry and photobiology. A, Chemistry. (01-07-2021)“…[Display omitted] •Synthesis of Bi1-xMxFeO3 porous networks by autocombustion.•Micrometer sized catalysts with nanometer sized optical absorption…”
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Accessing Sodium Ferrate Complexes Containing Neutral and Anionic N‑Heterocyclic Carbene Ligands: Structural, Synthetic, and Magnetic Insights
Published in Inorganic chemistry (21-09-2015)“…This study reports the synthesis and single-crystal X-ray crystallographic, NMR spectroscopic, and magnetic characterization of a series of sodium ferrates…”
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