Search Results - "Ca', Nicola Della"
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Pd/Norbornene: A Winning Combination for Selective Aromatic Functionalization via C–H Bond Activation
Published in Accounts of chemical research (19-07-2016)“…Direct C–H bond activation is an important reaction in synthetic organic chemistry. This methodology has the potential to simplify reactions by avoiding the…”
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2
Palladium(0)/benzoic acid catalysis merges sequences with D2O-promoted labelling of C–H bonds
Published in Chemical science (Cambridge) (28-11-2019)“…The combination of a Pd(0) complex with benzoic acid in the presence of D2O enables the synthesis of valuable families of highly deuterated organics through…”
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3
Inter/Intramolecular Cascade of 1,6-Enynes Catalyzed by All-Metal Aromatic Tripalladium Complexes and Carboxylic Acids
Published in Journal of organic chemistry (05-11-2021)“…Trinuclear all-metal aromatic clusters are an original class of molecules with a cyclic and planar metal core. Characterized by peculiar metal–metal…”
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4
An Unprecedented Pd‐Catalyzed Carbonylative Route to Fused Furo[3,4‐b]indol‐1‐ones
Published in Chemistry : a European journal (03-04-2018)“…A novel and efficient catalytic approach to functionalized furo[3,4‐b]indol‐1‐ones is reported. It is based on a palladium‐catalyzed sequential process…”
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5
Continuous-Flow Synthesis of Pyrylium Tetrafluoroborates: Application to Synthesis of Katritzky Salts and Photoinduced Cationic RAFT Polymerization
Published in Organic letters (19-03-2021)“…Katritzky salts have emerged as effective alkyl radical sources upon metal- or photocatalysis. These are typically prepared from the corresponding…”
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6
Of the Ortho Effect in Palladium/Norbornene-Catalyzed Reactions: A Theoretical Investigation
Published in Journal of the American Chemical Society (08-06-2011)“…Mechanistic questions concerning palladium and norbornene catalyzed aryl–aryl coupling reactions are treated in this paper: how aryl halides react with the…”
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7
Recent Advances in the Chemical Fixation of Carbon Dioxide: A Green Route to Carbonylated Heterocycle Synthesis
Published in Catalysts (01-06-2019)“…Carbon dioxide produced by human activities is one of the main contributions responsible for the greenhouse effect, which is modifying the Earth's climate…”
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8
Homogeneous and Gas–Liquid Catellani‐Type Reaction Enabled by Continuous‐Flow Chemistry
Published in Chemistry : a European journal (20-09-2018)“…A practical homogeneous and gas‐liquid palladium‐catalyzed Catellani‐type reaction using a continuous‐flow platform is described. The implementation of…”
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9
Synthesis of Imidazolidin-2-ones and Imidazol-2-ones via Base-Catalyzed Intramolecular Hydroamidation of Propargylic Ureas under Ambient Conditions
Published in Journal of organic chemistry (15-03-2019)“…The first organo-catalyzed synthesis of imidazolidin-2-ones and imidazol-2-ones via intramolecular hydroamidation of propargylic ureas is reported. The…”
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10
Synthesis of Carbolines via Palladium/Carboxylic Acid Joint Catalysis
Published in Organic letters (01-06-2018)“…The combination of a Pd(0) complex with benzoic acid converts propargylic tryptamines to the corresponding tetrahydro-β-carbolines. The method uses unprotected…”
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11
PdI2-Based Catalysis for Carbonylation Reactions: A Personal Account
Published in Catalysts (01-07-2019)“…In this account, we review our efforts in the field of carbonylation reactions promoted by palladium iodide-based catalysts, which have proven to be…”
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12
Catalytic Oxidative Carbonylation of Amino Moieties to Ureas, Oxamides, 2-Oxazolidinones, and Benzoxazolones
Published in ChemSusChem (08-07-2015)“…The direct syntheses of ureas, oxamides, 2‐oxazolidinones, and benzoxazolones by the oxidative carbonylation of amines, β‐amino alcohols, and 2‐aminophenols…”
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13
Phenolic Dienes as Highly Selective Dienophiles in the Asymmetric Organocatalyzed Three-Component Vinylogous Povarov Reaction
Published in Journal of organic chemistry (06-09-2024)“…Our study presents a novel enantioselective route for the synthesis of 1,2,3,4-tetrahydroquinolines via a chiral phosphoric acid-catalyzed three-component…”
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14
Palladium-Catalyzed Reactions
Published in Catalysts (01-05-2021)“…Palladium is probably the most versatile and exploited transition metal in catalysis due to its capability to promote a myriad of organic transformations both…”
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15
A Regio‐ and Stereoselective Carbonylative Approach to Alkyl (Z)‐2‐[3‐Oxoisobenzofuran‐1‐(3H)‐ylidene]acetates
Published in Advanced synthesis & catalysis (19-02-2019)“…The first example of the oxidative carbonylation of 2‐ethynylbenzoic acid derivatives, leading to alkyl (Z)‐2‐[3‐oxoisobenzofuran‐1‐(3H)‐ylidene]acetates in a…”
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16
Pd-Catalyzed/Iodide-Promoted α‑Arylation of Ketones for the Regioselective Synthesis of Isocoumarins
Published in Journal of organic chemistry (04-08-2017)“…A variety of isocoumarins have been synthesized directly from 2-halobenzoates and ketones through a palladium-catalyzed α-arylation step followed by an…”
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17
Effective Guanidine-Catalyzed Synthesis of Carbonate and Carbamate Derivatives from Propargyl Alcohols in Supercritical Carbon Dioxide
Published in Advanced synthesis & catalysis (10-01-2011)“…The reactions of propargyl alcohols with carbon dioxide in supercritical carbon dioxide or in acetonitrile with gaseous carbon dioxide in the presence of…”
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18
Catalytic Sequential Reactions Involving Palladacycle-Directed Aryl Coupling Steps
Published in Accounts of chemical research (18-11-2008)“…Catalytic methods are important tools for the synthesis of C−C bonds under mild and ambient conditions. Palladium chemistry predominates in this area because…”
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19
Catalytic Carbonylative Double Cyclization of 2‑(3-Hydroxy-1-yn-1-yl)phenols in Ionic Liquids Leading to Furobenzofuranone Derivatives
Published in Journal of organic chemistry (07-06-2019)“…A catalytic carbonylative double cyclization method for the synthesis of furo[3,4-b]benzofuran-1(3H)-ones is reported. It is based on the reaction between…”
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20
A Direct Palladium‐Catalyzed Route to Selectively Substituted Carbazoles through Sequential CC and CN Bond Formation: Synthesis of Carbazomycin A
Published in Advanced synthesis & catalysis (06-10-2008)“…The present paper offers a synthetically simple one‐pot procedure for the catalytic preparation of the biologically interesting class of carbazoles. The new…”
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