Search Results - "CULLEN, David A"
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Thermally Driven Structure and Performance Evolution of Atomically Dispersed FeN4 Sites for Oxygen Reduction
Published in Angewandte Chemie (International ed.) (19-12-2019)“…FeN4 moieties embedded in partially graphitized carbon are the most efficient platinum group metal free active sites for the oxygen reduction reaction in…”
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Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalyst
Published in Nature communications (17-05-2021)“…Electrochemically converting nitrate, a widespread water pollutant, back to valuable ammonia is a green and delocalized route for ammonia synthesis, and can be…”
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3
Nitrogen‐Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells
Published in Advanced materials (Weinheim) (01-03-2018)“…Due to the Fenton reaction, the presence of Fe and peroxide in electrodes generates free radicals causing serious degradation of the organic ionomer and the…”
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Single Cobalt Sites Dispersed in Hierarchically Porous Nanofiber Networks for Durable and High‐Power PGM‐Free Cathodes in Fuel Cells
Published in Advanced materials (Weinheim) (01-11-2020)“…Increasing catalytic activity and durability of atomically dispersed metal–nitrogen–carbon (M–N–C) catalysts for the oxygen reduction reaction (ORR) cathode in…”
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Selective and Stable Non-Noble-Metal Intermetallic Compound Catalyst for the Direct Dehydrogenation of Propane to Propylene
Published in Journal of the American Chemical Society (31-10-2018)“…A non-noble intermetallic compound catalyst consisting of Ni3Ga nanoparticles supported on Al2O3 that exhibits high selectivity (∼94%), comparable activity…”
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Fabrication of Au25(SG)18–ZIF‐8 Nanocomposites: A Facile Strategy to Position Au25(SG)18 Nanoclusters Inside and Outside ZIF‐8
Published in Advanced materials (Weinheim) (08-02-2018)“…Multifunctional composite materials are currently highly desired for sustainable energy applications. A general strategy to integrate atomically precise…”
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Regulating Catalytic Properties and Thermal Stability of Pt and PtCo Intermetallic Fuel-Cell Catalysts via Strong Coupling Effects between Single-Metal Site-Rich Carbon and Pt
Published in Journal of the American Chemical Society (16-08-2023)“…Developing low platinum-group-metal (PGM) catalysts for the oxygen reduction reaction (ORR) in proton-exchange membrane fuel cells (PEMFCs) for heavy-duty…”
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Harvesting Sub-Bandgap IR Photons by Photothermionic Hot Electron Transfer in a Plasmonic p–n Junction
Published in Nano letters (12-05-2021)“…Plasmonic semiconductors are an emerging class of low-cost plasmonic materials, and the presence of a bandgap and band-bending in these materials offer new…”
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Ionomer-free and recyclable porous-transport electrode for high-performing proton-exchange-membrane water electrolysis
Published in Nature communications (31-07-2023)“…Clean hydrogen production requires large-scale deployment of water-electrolysis technologies, particularly proton-exchange-membrane water electrolyzers…”
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10
Ternary Electrocatalysts for Oxidizing Ethanol to Carbon Dioxide: Making Ir Capable of Splitting C–C Bond
Published in Journal of the American Chemical Society (09-01-2013)“…Splitting the C–C bond is the main obstacle to electrooxidation of ethanol (EOR) to CO2. We recently demonstrated that the ternary PtRhSnO2 electrocatalyst can…”
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Platinum–Ruthenium Nanotubes and Platinum–Ruthenium Coated Copper Nanowires As Efficient Catalysts for Electro-Oxidation of Methanol
Published in ACS catalysis (06-03-2015)“…The sluggish kinetics of methanol oxidation reaction (MOR) is a major barrier to the commercialization of direct methanol fuel cells (DMFCs). In this work, we…”
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12
20%-efficient polycrystalline Cd(Se,Te) thin-film solar cells with compositional gradient near the front junction
Published in Nature communications (21-12-2022)“…Bandgap gradient is a proven approach for improving the open-circuit voltages (V OC s) in Cu(In,Ga)Se 2 and Cu(Zn,Sn)Se 2 thin-film solar cells, but has not…”
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13
Ultrasensitive gas detection of large-area boron-doped graphene
Published in Proceedings of the National Academy of Sciences - PNAS (24-11-2015)“…Heteroatom doping is an efficient way to modify the chemical and electronic properties of graphene. In particular, boron doping is expected to induce ap-type…”
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Atomistic-Scale Simulations of Defect Formation in Graphene under Noble Gas Ion Irradiation
Published in ACS nano (27-09-2016)“…Despite the frequent use of noble gas ion irradiation of graphene, the atomistic-scale details, including the effects of dose, energy, and ion bombardment…”
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15
Ozonated Graphene Oxide Film as a Proton-Exchange Membrane
Published in Angewandte Chemie (International ed.) (01-04-2014)“…Graphene oxide (GO) contains several chemical functional groups that are attached to the graphite basal plane and can be manipulated to tailor GO for specific…”
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Distinct photoluminescence and Raman spectroscopy signatures for identifying highly crystalline WS2 monolayers produced by different growth methods
Published in Journal of materials research (14-04-2016)“…Transition metal dichalcogenides such as WS2 show exciting promise in electronic and optoelectronic applications. Significant variations in the transport,…”
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Highly Efficient Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol over Gold Supported on Zinc Oxide Materials
Published in Journal of physical chemistry. C (31-12-2015)“…Au/ZnO catalysts have been used for liquid-phase selective hydrogenation of cinnamaldehyde to cinnamyl alcohol and compared with Au/Fe2O3 catalysts. To…”
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Pd-Ru pair on Pt surface for promoting hydrogen oxidation and evolution in alkaline media
Published in Nature communications (23-08-2024)“…Hydrogen oxidation reaction in alkaline media is critical for alkaline fuel cells and electrochemical ammonia compressors. The slow hydrogen oxidation reaction…”
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A physical catalyst for the electrolysis of nitrogen to ammonia
Published in Science advances (27-04-2018)“…Ammonia synthesis consumes 3 to 5% of the world's natural gas, making it a significant contributor to greenhouse gas emissions. Strategies for synthesizing…”
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Faradaurate-940: Synthesis, Mass Spectrometry, Electron Microscopy, High-Energy X‑ray Diffraction, and X‑ray Scattering Study of Au∼940±20(SR)∼160±4 Nanocrystals
Published in ACS nano (24-06-2014)“…Obtaining monodisperse nanocrystals and determining their composition to the atomic level and their atomic structure is highly desirable but is generally…”
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