Search Results - "CLARK, Robert W"
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1
Understanding Internal Chirality Induction of Triarylsilyl Ethers Formed from Enantiopure Alcohols
Published in Journal of organic chemistry (16-09-2016)“…Chirality transmission from point chirality to helical chirality was explored using triarylsilyl ethers. Circular dichroism (CD) spectroscopy was employed to…”
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2
Polystyrene-Supported Triphenylsilyl Chloride for the Silylation-Based Kinetic Resolution of Secondary Alcohols
Published in ChemCatChem (18-05-2015)“…A silyl chloride derivatized styrene polymer was employed in the silylation‐based kinetic resolution of secondary alcohols for chromatography‐free separation…”
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3
Disparate effects of constant and annually-cycling daylength and water temperature on reproductive maturation of striped bass ( Morone saxatilis)
Published in Aquaculture (12-09-2005)“…Adult striped bass ( Morone saxatilis) were exposed to various combinations of constant or anually-cycling daylength and water temperature. Constant conditions…”
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4
Chemistry of the Aromatic 9-Germafluorenyl Dianion and Some Related Silicon and Carbon Species
Published in Journal of the American Chemical Society (16-10-2002)“…Dipotassio-9-germafluorenyl dianion (3b) was synthesized by reduction of 9,9-dichloro-9-germafluorene (4b) with sodium/potassium alloy in tetrahydrofuran. The…”
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5
N-nitrosamine impurity risk assessment in pharmaceuticals: Utilizing In vivo mutation relative potency comparison to establish an acceptable intake for NTTP
Published in Regulatory toxicology and pharmacology (01-09-2024)“…The finding of N-nitrosodiethylamine (NDEA) and N-nitrosodimethylamine (NDMA) in marketed drugs has led to implementation of risk assessment processes intended…”
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6
Unexpected NO-Dependent DNA Binding by the CooA Homolog from Carboxydothermus hydrogenoformans
Published in Proceedings of the National Academy of Sciences - PNAS (24-01-2006)“…CooA, the CO-sensing heme protein from Rhodospirillum rubrum, regulates the expression of genes that encode a CO-oxidation system, allowing R. rubrum to use CO…”
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7
Silylation-Based Kinetic Resolution of α‑Hydroxy Lactones and Lactams
Published in Organic letters (20-12-2013)“…A silylation-based kinetic resolution has been developed for α-hydroxy lactones and lactams employing the chiral isothiourea catalyst (−)-benzotetramisole and…”
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8
Polymers and Kinetic Resolutions: The Insolubility of It All
Published in ChemCatChem (07-03-2016)“…Kinetic resolution is a powerful technique to obtain enantioenriched compounds. A major drawback to conventional kinetic resolutions is that the final…”
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9
Cu spectroscopy from a z-pinch plasma
Published in Physica scripta (01-11-2014)“…Recent improvements in diagnostic techniques at the Sandia Laboratories Z accelerator have facilitated the production of very detailed x-ray spectral data in…”
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10
Analysis of the L116K Variant of CooA, the Heme-containing CO Sensor, Suggests the Presence of an Unusual Heme Ligand Resulting in Novel Activity
Published in The Journal of biological chemistry (13-09-2002)“…CooA is the CO-sensing transcriptional activator from Rhodospirillum rubrum, in which CO binding to its heme prosthetic group triggers a conformational change…”
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11
A Look at Leadership: An Examination of Career and Technical Administrator Preparation in the United States
Published in Career and technical education research (01-04-2015)“…The study is designed to examine the perceptions of U.S. State Directors of Career and Technical Education (CTE) of the state of administrator preparation…”
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12
Guanidine Hydrochloride-Induced Unfolding of the Three Heme Coordination States of the CO-Sensing Transcription Factor, CooA
Published in Biochemistry (Easton) (21-07-2009)“…CooA is a heme-dependent CO-sensing transcription factor that has three observable heme coordination states. There is some evidence that each CooA heme state…”
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13
Silica-bound copper(II)triazacyclononane as a phosphate esterase: effect of linker length and surface hydrophobicity
Published in Dalton transactions : an international journal of inorganic chemistry (01-01-2009)“…A series of silica-bound Cu(ii) triazacyclononane materials was prepared to study the effect of linker length and surface hydrophobicity on the hydrolysis of…”
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14
A Case Study on Collaboration: Sharing the Responsibility of Economic Development in Juniata Valley, Pennsylvania
Published in Community college journal of research and practice (01-07-2013)“…In an attempt to better understand the need and importance of the community college's role in economic development, this article takes a closer look at how…”
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15
A Tale of Two Bridges: Dangerous and Still Standing
Published in Leadership and management in engineering (01-10-2008)“…Engineers hold the keys needed to inform the public about the seriousness of an impending crisis. The monumental effort that will be required to rebuild the…”
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16
The Redox Behavior of the Heme in Cystathionine β-synthase Is Sensitive to pH
Published in Biochemistry (Easton) (23-11-2004)“…Human cystathionine β-synthase (CBS) is a unique pyridoxal-5‘-phosphate-dependent enzyme in which heme is also present as a cofactor. Because the function of…”
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17
Time-Integrated Synthetic X-Ray Spectroscopy for Stainless Steel Wire Array Z-Pinches
Published in IEEE transactions on plasma science (01-04-2010)“…We have used a collisional-radiative spectroscopic model to generate a stainless steel (SS) atomic model to analyze the implosion dynamics of an array of SS…”
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18
Modeling proline ligation in the heme-dependent CO sensor, CooA, using small-molecule analogs
Published in Journal of biological inorganic chemistry (01-07-2006)“…CooA, the only protein known to employ proline as a heme ligand, is a CO-activated transcription factor found in the bacterium Rhodospirillum rubrum. Proline…”
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19
DNA binding by an imidazole-sensing CooA variant is dependent on the heme redox state
Published in Journal of biological inorganic chemistry (01-02-2007)“…CooA is a transcription factor from Rhodospirillum rubrum that is regulated by the binding of the small molecule effector, CO, to a heme moiety in the protein…”
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20
Scaling of K-Shell Emission From Z -Pinches: Z to ZR
Published in IEEE transactions on plasma science (01-06-2007)“…Experiments in the last few years at the 20-MA Z Accelerator have produced significant K-shell X-ray output from a variety of initial load materials, including…”
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