Search Results - "CHRISTOU, George"
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Atomically-precise colloidal nanoparticles of cerium dioxide
Published in Nature communications (13-11-2017)“…Synthesis of truly monodisperse nanoparticles and their structural characterization to atomic precision are important challenges in nanoscience. Success has…”
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2
Magnetostructural Correlation for High-Nuclearity Iron(III)/Oxo Complexes and Application to Fe5, Fe6, and Fe8 Clusters
Published in Inorganic chemistry (05-07-2016)“…The synthesis and characterization are reported of two new polynuclear FeIII complexes containing the anion of 8-hydroxyquinoline (hqnH), an N,O-chelating…”
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3
Synthetic model of the asymmetric [Mn₃CaO₄] cubane core of the oxygen-evolving complex of photosystem II
Published in Proceedings of the National Academy of Sciences - PNAS (14-02-2012)“…The laboratory synthesis of the oxygen-evolving complex (OEC) of photosystem II has been the objective of synthetic chemists since the early 1970s. However,…”
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4
A Record Anisotropy Barrier for a Single-Molecule Magnet
Published in Journal of the American Chemical Society (14-03-2007)“…Structural distortion in a [Mn6] complex switches the magnetic exchange from antiferro- to ferromagnetic, resulting in a single-molecule magnet with a record…”
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5
Enhancing the Quantum Properties of Manganese-Lanthanide Single-Molecule Magnets: Observation of Quantum Tunneling Steps in the Hysteresis Loops of a {Mn₁₂Gd} Cluster
Published in Angewandte Chemie (International ed.) (01-01-2009)“…Quantum tunneling of magnetization (QTM) steps have been observed for a mixed 3d–4f single‐molecule magnet for the first time in the hysteresis loops of…”
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6
Covalently Linked Dimer of Mn3 Single-Molecule Magnets and Retention of Its Structure and Quantum Properties in Solution
Published in Journal of the American Chemical Society (10-06-2015)“…[Mn3O(O2CMe)3(dpd)3/2)]2(I3)2 has been obtained from the reaction of 1,3-di(pyridin-2-yl)propane-1,3-dione dioxime (dpdH2) with triangular [MnIII…”
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7
Family of Double-Cubane Mn4Ln2 (Ln = Gd, Tb, Dy, Ho) and Mn4Y2 Complexes: A New Mn4Tb2 Single-Molecule Magnet
Published in Inorganic chemistry (17-10-2011)“…The synthesis and characterization of a family of Mn2 IIIMn2 IILnIII 2 complexes (Ln = Gd (1), Tb (2), Dy (3), and Ho (4)) of formula…”
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8
Toward a Magnetostructural Correlation for a Family of Mn6 SMMs
Published in Journal of the American Chemical Society (17-10-2007)“…We have structurally and magnetically characterized a total of 12 complexes based on the Single-Molecule Magnet (SMM) [MnIII 6O2(sao)6(O2CH)2(MeOH) 4] (1)…”
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9
Initial Observation of Magnetization Hysteresis and Quantum Tunneling in Mixed Manganese−Lanthanide Single-Molecule Magnets
Published in Journal of the American Chemical Society (08-12-2004)“…The preparation of a new family of mixed transition metal/lanthanide clusters is reported. The reaction of [Mn3O(O2CPh)6(py)2(H2O)] with Ln(NO3)3 (Ln = Nd, Gd,…”
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10
Supramolecular aggregates of single-molecule magnets: exchange-biased quantum tunneling of magnetization in a rectangular [Mn 3 ] 4 tetramer
Published in Chemical science (Cambridge) (2016)“…The syntheses and properties of four magnetically-supramolecular oligomers of triangular Mn units are reported: dimeric [Mn O (O CMe) (CH OH) (pdpd) ] ( ) and…”
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The search for 3d-4f single-molecule magnets: synthesis, structure and magnetic properties of a [Mn(III)2Dy(III)2] cluster
Published in Chemical communications (Cambridge, England) (28-04-2005)“…Tetranuclear [Mn(III)2Ln(III)2] complexes formed using tripodal ligands display frequency dependent out-of-phase ac susceptibility signals and temperature and…”
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12
“Switching On” the Properties of Single-Molecule Magnetism in Triangular Manganese(III) Complexes
Published in Journal of the American Chemical Society (01-08-2007)“…The reaction between oxide-centered, triangular [MnIII 3O(O2CR)6(py)3](ClO4) (R = Me (1), Et (2), Ph (3)) compounds and methyl 2-pyridyl ketone oxime (mpkoH)…”
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13
Spin Switching via Targeted Structural Distortion
Published in Journal of the American Chemical Society (23-05-2007)“…The deliberate “stepwise” structural distortion of the [MnIII 6O2(sao)6(O2CR)2L4] (S = 4, U eff = 28 K) family of SMMs (where sao2- is the dianion of…”
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14
Electronic Structural Changes of Mn in the Oxygen-Evolving Complex of Photosystem II during the Catalytic Cycle
Published in Inorganic chemistry (20-05-2013)“…The oxygen-evolving complex (OEC) in photosystem II (PS II) was studied in the S 0 through S 3 states using 1s2p resonant inelastic X-ray scattering…”
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15
A Fourth Isolated Oxidation Level of the [Mn12O12(O2CR)16(H2O)4] Family of Single-Molecule Magnets
Published in Inorganic chemistry (10-12-2007)“…The Mn12 family of single-molecule magnets (SMMs) has been extended to a fourth isolated member. [Mn12O12(O2CR)16(H2O)4] (1) exhibits three quasi-reversible…”
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Comproportionation Reactions to Manganese(III/IV) Pivalate Clusters: A New Half-Integer Spin Single-Molecule Magnet
Published in Inorganic chemistry (18-01-2013)“…The comproportionation reaction between MnII and MnVII reagents under acidic conditions has been investigated in the presence of pivalic acid as a route to new…”
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17
{Mn6} n Single-Chain Magnet Bearing Azides and Di-2-pyridylketone-Derived Ligands
Published in Inorganic chemistry (02-02-2009)“…The synthesis, structure, and magnetochemical characterization of a new manganese single-chain magnet are reported. The compound is a chain of repeating Mn6…”
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18
Dimeric and Tetrameric Supramolecular Aggregates of Single-Molecule Magnets via Carboxylate Substitution
Published in Inorganic chemistry (04-11-2013)“…[Mn3]2 and [Mn3]4 supramolecular aggregates of weakly exchange-coupled MnIII 3 single-molecule magnets (SMMs) with S = 6 have been prepared by carboxylate…”
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19
Exchange-Biased Dimers of Single-Molecule Magnets in OFF and ON States
Published in Journal of the American Chemical Society (31-10-2007)“…A new Fe9 single-molecule magnet has been synthesized and found to crystallize as head-to-head dimers. Two-thirds of these are exchange-coupled through a…”
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20
CoII4, CoII7, and a Series of CoII2LnIII (LnIII = NdIII, SmIII, GdIII, TbIII, DyIII) Coordination Clusters: Search for Single Molecule Magnets
Published in Inorganic chemistry (17-10-2016)“…We report herein the syntheses and investigation of the magnetic properties of a CoII4 compound, a series of trinuclear CoII2LnIII (LnIII = NdIII, SmIII,…”
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