Search Results - "CAMINATI, WALTHER"

The Barrier to Proton Transfer in the Dimer of Formic Acid: A Pure Rotational Study by Li, Weixing, Evangelisti, Luca, Gou, Qian, Caminati, Walther, Meyer, Rolf

“…The rotational spectra of three C‐deuterated isotopologues of the dimer of formic acid have been measured, thanks to the small dipole moment induced by…”
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The LAM of the Rings: Large Amplitude Motions in Aromatic Molecules Studied by Microwave Spectroscopy by Nguyen, Ha Vinh Lam, Caminati, Walther, Grabow, Jens-Uwe

“…Large amplitude motions (LAMs) form a fundamental phenomenon that demands the development of specific theoretical and Hamiltonian models. In recent years,…”
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Skeletal Torsion Tunneling and Methyl Internal Rotation: The Coupled Large Amplitude Motions in Phenyl Acetate by Ferres, Lynn, Evangelisti, Luca, Maris, Assimo, Melandri, Sonia, Caminati, Walther, Stahl, Wolfgang, Nguyen, Ha Vinh Lam

“…The rotational spectrum of phenyl acetate, CH COOC H , is measured using a free jet absorption millimeter-wave spectrometer in the range from 60 to 78 GHz and…”
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All Five Forms of Cytosine Revealed in the Gas Phase by Alonso, José L., Vaquero, Vanesa, Peña, Isabel, López, Juan C., Mata, Santiago, Caminati, Walther

“…Give me five! All five tautomers and conformers of cytosine were characterized in the gas phase by laser ablation molecular beam Fourier transform microwave…”
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Conformational Equilibria in Bimolecules of Carboxylic Acids: A Rotational Study of Fluoroacetic Acid–Acrylic Acid by Gou, Qian, Feng, Gang, Evangelisti, Luca, Caminati, Walther

“…The rotational spectra of three conformers of the fluoroacetic acid–acrylic acid bimolecule have been assigned by pulsed jet Fourier Transform microwave…”
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A rotational study of the molecular complex tert-butanol⋯1,4-dioxane by Evangelisti, Luca, Caminati, Walther

“…[Display omitted] ► The axial conformer of tert-butanol⋯1,4-dioxane has been detected. ► The rotational constants increase upon deuteration of the hydroxyl…”
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Proton Transfer in Homodimers of Carboxylic Acids: The Rotational Spectrum of the Dimer of Acrylic Acid by Feng, Gang, Favero, Laura B, Maris, Assimo, Vigorito, Annalisa, Caminati, Walther, Meyer, Rolf

“…The dimer of acrylic acid can exist in two forms, depending on the entgegen or zusammen orientations of the two allyl groups. The latter one (zusammen) has a…”
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Quantum Effects for a Proton in a Low-Barrier, Double-Well Potential: Core Level Photoemission Spectroscopy of Acetylacetone by Feyer, Vitaliy, Prince, Kevin C, Coreno, Marcello, Melandri, Sonia, Maris, Assimo, Evangelisti, Luca, Caminati, Walther, Giuliano, Barbara M, Kjaergaard, Henrik G, Carravetta, Vincenzo

“…We have performed core level photoemission spectroscopy of gaseous acetylacetone, its fully deuterated form, and two derivatives, benzoylacetone and…”
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Relative Strengths of the OH⋅⋅⋅Cl and OH⋅⋅⋅F Hydrogen Bonds by Caminati, Walther, Melandri, Sonia, Maris, Assimo, Ottaviani, Paolo

“…Which bond goes where? The observed conformer of H2O⋅⋅⋅ClFCH2 displays one OH⋅⋅⋅Cl and two weak CH⋅⋅⋅O hydrogen‐bonding interactions. The dissociation energy…”
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From Transient to Induced Permanent Chirality in 2-Propanol upon Dimerization: A Rotational Study by Snow, Mark S, Howard, Brian J, Evangelisti, Luca, Caminati, Walther

“…Five different hydrogen-bonded conformers of the dimer of 2-propanol have been characterized by Fourier transform microwave spectroscopy. In all observed…”
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Weak C−H···O and C−H···F−C Hydrogen Bonds in the Oxirane−Trifluoromethane Dimer by Alonso, José L, Antolínez, Sonia, Blanco, Susana, Lesarri, Alberto, López, Juan C, Caminati, Walther

“…The oxirane−trifluoromethane dimer generated in a supersonic expansion has been characterized by Fourier transform microwave spectroscopy. The rotational…”
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Molecular Recognition of Chiral Conformers: A Rotational Study of the Dimers of Glycidol by Maris, Assimo, Giuliano, Barbara M, Bonazzi, Daria, Caminati, Walther

“…Two homochiral dimers of glycidol, deriving from two different conformers, have been characterized by rotational spectroscopy in a supersonic expansion…”
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Dynamical Behavior and Dipole-Dipole Interactions of Tetrafluoromethane-Water by Caminati, Walther, Maris, Assimo, Dell'Erba, Adele, Favero, Paolo G.

“…Top stuff: The configuration of tetrafluoromethane–water is driven by dipole–dipole interactions rather than hydrogen bonds. The complex, which consists of a…”
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The free jet microwave spectrum of 2-phenylethylamine-water by Melandri, Sonia, Maris, Assimo, Giuliano, Barbara M, Favero, Laura B, Caminati, Walther

“…We observed the rotational spectrum of the 1:1 molecular adduct between 2-phenylethylamine and water (normal and H(2)(18)O species) by free jet absorption…”
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The Conformational Landscape of Nicotinoids: Solving the Conformational Disparity of Anabasine by Lesarri, Alberto, Cocinero, Emilio J., Evangelisti, Luca, Suenram, Richard D., Caminati, Walther, Grabow, Jens-Uwe

“…The conformational landscape of the alkaloid anabasine (neonicotine) has been investigated by using rotational spectroscopy and ab initio calculations. The…”
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Tautomeric equilibrium and hydroxyl group internal rotation in 4-hydroxypyridine by Sanchez, Raquel, Giuliano, B. Michela, Melandri, Sonia, Caminati, Walther

“…The hydroxyl group in 4-hydroxy-pyridine is tunnelling from τ = 0° to τ = 180° with a frequency of 7.97(4) MHz through a barrier to internal rotation V 2 =…”
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Modeling the internal rotation tunnelling in benzyl alcohol by ring fluorination: The rotational spectrum of 3,5-difluorobenzyl alcohol by Evangelisti, Luca, Caminati, Walther

“…[Display omitted] •The MW spectrum of of the 3,5-difluorobenzyl alcohol was recorded and analyzed.•The spectroscopic experimental parameters were compared to…”
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Nucleic Acid Bases in the Gas Phase by Caminati, Walther

“…Laser ablation or desorption overcomes the problem of the thermal instability of some nucleobases upon vaporization for studies of their…”
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Internal dynamics in complexes of water with organic molecules. Details of the internal motions in tert-butylalcohol-water by Evangelisti, Luca, Caminati, Walther

“…The peculiar propensity of water to have a high internal dynamic activity in its molecular complexes with organic molecules is described in this paper. Often,…”
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The Hydrogen Bond and Beyond: Perspectives for Rotational Investigations of Non‐Covalent Interactions by Juanes, Marcos, Saragi, Rizalina T., Caminati, Walther, Lesarri, Alberto

“…In the last decade, experiment and theory have expanded our vision of non‐covalent interactions (NCIs), shifting the focus from the conventional hydrogen bond…”
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