Search Results - "C. F. Jones, Raymond"
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Palladium Catalyzed Oxidative Coupling of α‑Enolic Dithioesters: A New Entry to 3,4,5-Trisubstituted 1,2-Dithioles via a Double Activation Strategy
Published in Organic letters (18-10-2013)“…An operationally simple, facile, and convenient one-pot straightforward method for the construction of 3,4,5-trisubstituted 1,2-dithioles has been explored and…”
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Isoxazole to oxazole: a mild and unexpected transformation
Published in Chemical communications (Cambridge, England) (21-01-2015)“…3-Aryltetrahydrobenzisoxazoles prepared en route to the coleophomone natural products and analogues, were found to undergo a remarkable base-mediated…”
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3
Coenzyme-inspired chemistry 2: 4,5-dihydroimidazolium ylides (NHCs) and the reactions of 2-(1-hydroxyalkyl)-4,5-dihydroimidazoles
Published in Organic & biomolecular chemistry (21-09-2013)“…Ketones are prepared from aldehydes via 1-benzyl-2-(1-hydroxyalkyl)-4,5-dihydroimidazoles (adducts of the aldehydes with…”
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A New 3-(Ethoxycarbonylmethyl)isoxazolopyridone as a Precursor to Acylpyridones
Published in Heterocycles (2012)Get full text
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5
New routes towards reutericyclin analogues
Published in Chemical communications (Cambridge, England) (01-01-2014)“…A range of N-acylpyrrolo[3,4-c]isoxazoles and derived N-acyltetramides has been prepared via a nitrile oxide dipolar cycloaddition approach, as analogues of…”
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Preparation of highly substituted pyrrolidines via an organometallic dipole
Published in Organic & biomolecular chemistry (01-01-2006)“…Highly substituted pyrrolidines are prepared by formal cycloaddition of imines to a metal-stabilised 'Nicholas' dipole derived from an alkyne-cyclopropane…”
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Imidazolium ylides from a conjugate addition-proton transfer route and their cycloaddition reactions
Published in Chemical communications (Cambridge, England) (28-07-2011)“…4,5-Dihydroimidazolium ylides formed by conjugate addition-proton transfer from dihydroimidazoles and doubly-activated electron-deficient alkenes afford 2:1…”
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An enantioselective route to pyrrolidines: removal of the chiral template from homochiral pyrroloimidazoles
Published in Tetrahedron (18-11-2011)“…Two-step reductive removal of the chiral template from optically active pyrroloimidazoles, available from 1,3-dipolar cycloaddition of homochiral…”
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Novel formation and use of a Nicholas carbocation in the synthesis of highly substituted tetrahydrofurans
Published in Chemical communications (Cambridge, England) (07-11-2004)“…The first formation of a Nicholas carbocation through cleavage of a carbon-carbon sigma bond has allowed the preparation of highly substituted tetrahydrofurans…”
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Synthesis of the Pyoverdin Chromophore by a Biomimetic Oxidative Cyclization
Published in Organic letters (02-04-2009)“…The fluorescent dihydropyrimido[1,2-a]quinoline chromophore of the pyoverdin siderophores has been synthesized by a biomimetic oxidative cyclization using an…”
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An Unexpected Stereochemical Course of Dihydroimidazolium Ylide Cycloadditions
Published in Chemistry, an Asian journal (01-03-2010)“…Turning the tables: We have observed an unexpected switch of cycloaddition mode from endo to exo for sulfone‐activated dipolarophiles with achiral…”
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12
Aldol elaboration of 4,5,6,7-tetrahydroisoxazolo[4,3-c]pyridin-4-ones, masked precursors to acylpyridones
Published in Beilstein journal of organic chemistry (27-02-2012)“…A core 4,5,6,7-tetrahydroisoxazolo[4,3-c]pyridine-4-one scaffold is elaborated at C-3(Me) by base-mediated aldol condensation to give new…”
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In(OTf)3-catalysed one-pot versatile pyrrole synthesis through domino annulation of α-oxoketene-N,S-acetals with nitroolefins
Published in Organic & biomolecular chemistry (07-08-2014)“…In(OTf)3-catalyzed robust and sustainable one-pot access to previously unknown and synthetically demanding polysubstituted pyrroles via [3 + 2] annulation of…”
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Regioselective quadruple domino aldolization/aldol condensation/Michael/SNAr-cyclization: construction of hexacyclic indeno-fused C-nor-D-homo-steroid frameworks
Published in Tetrahedron (25-03-2014)“…An operationally simple and highly atom-economic anionic quadruple domino reaction sequence for the synthesis of hexacyclic indeno-fused naphthalene/quinoline…”
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Coenzyme-inspired chemistry 1: the C-2 alkylation of 4,5-dihydroimidazoles
Published in Tetrahedron (20-05-2013)“…Alkylation of 4,5-dihydroimidazoles at C-2 is accomplished using a double umpolung of the reactivity of that position, via sulfenylation of a nucleophilic C-2…”
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ISOLATION OF NOVEL PARA-PENTYL PHENYL BENZOATE FROM MONDIA WHITEI. (HOOK.F.) SKEELS (PERIPLOCACEAE), ITS STRUCTURE, SYNTHESIS AND NEUROPHARMACOLOGICAL EVALUATION
Published in African journal of traditional, complementary, and alternative medicines (01-01-2017)“…Background: Mondia whitei L. (Hook. F.) Skeels (Periplocaceae) is a medicinal plant used locally in managing pain, fever, loss of appetite and as aphrodiasc in…”
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Cycloaddition of homochiral dihydroimidazoles: a 1,3-dipolar cycloaddition route to optically active pyrrolo[1,2-a]imidazoles
Published in Organic & biomolecular chemistry (01-01-2011)“…N-Alkylation of optically active 1-benzyl-4-phenyl-4,5-dihydroimidazole with active alkyl halides and treatment of the so-formed 4,5-dihydroimidazolium ions…”
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Explorations of an intramolecular route to pyrrolo[3,4-b]isoxazoles: an unexpected retro-Claisen reaction
Published in ARKIVOC (07-04-2013)Get full text
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Novel heterocyclic α-amino acids with sulfur-containing side-chains
Published in ARKIVOC (17-01-2011)Get full text
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20
Dehydrogenation–halogenation of a 4,5,6,7-tetrahydroisoxazolo[4,3-c]pyridin-4-one to provide a scaffold for acylpyridones
Published in ARKIVOC (04-05-2012)Get full text
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