Search Results - "Buschhorn, Drew T"
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Influence of the d-Electron Count on CO Binding by Three-Coordinate [(tBu2PCH2SiMe2)2N]Fe, -Co, and -Ni
Published in Inorganic chemistry (21-01-2008)“…Reduction of (PNP)MCl [PNP = (tBu2PCH2SiMe2)2N] with Mg gives three-coordinate, T-shaped (PNP)M for M = Fe(S = 3/2) and Ni. Their reactivity was tested toward…”
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Journal Article -
2
Influence of the Metal Orbital Occupancy and Principal Quantum Number on Organoazide (RN3) Conversion to Transition-Metal Imide Complexes
Published in Inorganic chemistry (06-10-2008)“…The reaction of phenyl azide with (PNP)Ni, where PNP = (tBu2PCH2SiMe2)2N−, promptly evolves N2 and forms a PN bond in the product (PNPNPh)NiI. A similar…”
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Journal Article