Search Results - "Burini, Alfredo"
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Structures and properties of gold(I) complexes of interest in biochemical applications
Published in Coordination chemistry reviews (01-06-2009)“…Gold(I) compounds have several potential roles in biologically related chemistry. The relatively low toxicity of gold and its lability allows human consumption…”
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Mixed-Metal Triangular Trinuclear Complexes: Dimers of Gold−Silver Mixed-Metal Complexes from Gold(I) Carbeniates and Silver(I) 3,5-Diphenylpyrazolates
Published in Journal of the American Chemical Society (13-04-2005)“…Dimers of trinuclear mixed gold−silver compounds are obtained by the reaction of a gold(I) carbeniate, [Au(μ-C(OEt)NC6H4-p-CH3)]3, with a silver(I)…”
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Reversible C−H Bond Activation of a Bifunctional Phosphine Bridging Ligand across Two Unbonded Metal Centers
Published in Organometallics (07-08-2000)“…Reaction of [{Ir(μ-Cl)(cod)}2] with the short-bite bifunctional N,P-donor ligand (1-benzyl-2-imidazolyl)diphenylphosphine (Ph2PBzIm) gives the yellow complex…”
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Rhodium, iridium and gold complexes of the short-bite ligand 1-benzyl-2-imidazolyldiphenylphosphine
Published in Inorganica Chimica Acta (15-04-2003)“…Reactions of [{M(μ-Cl)(cod)} 2] (M=Rh, Ir) with 1-benzyl-2-imidazolyldiphenylphosphine gave the mononuclear P-bonded compounds [MCl(cod)(Ph 2PBzIm)]. They…”
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Cupriphication of gold to sensitize d10–d10 metal–metal bonds and near-unity phosphorescence quantum yields
Published in Proceedings of the National Academy of Sciences - PNAS (27-06-2017)“…Outer-shell s⁰/p⁰ orbital mixing with d10 orbitals and symmetry reduction upon cupriphication of cyclic trinuclear trigonal-planar gold(I) complexes are found…”
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A study on the inhibition of dihydrofolate reductase (DHFR) from Escherichia coli by gold(i) phosphane compounds. X-ray crystal structures of (4,5-dichloro-1H-imidazolate-1-yl)-triphenylphosphane-gold(i) and (4,5-dicyano-1H-imidazolate-1-yl)-triphenylphosphane-gold(i)
Published in Dalton transactions : an international journal of inorganic chemistry (21-02-2015)“…An unprecedented study on the inhibitory activities of a class of phosphane gold(i) complexes on E. coli dihydrofolate reductase (DHFR) is reported. The…”
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Bioinspired Ion Recognition in Hexanuclear Copper Pyrazolate Metallacycles
Published in European journal of inorganic chemistry (01-07-2012)“…The chemistry of anion‐encapsulation assemblies in copper pyrazolates is reminiscent of the work on the halide‐ and chalcogenide‐centered cubic copper(I)…”
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Soft Metal Cations Trigger Sandwich‐Cluster Luminescence of a New Au(I)‐Vinylimidazolate Cyclic Trinuclear Complex
Published in European journal of inorganic chemistry (18-03-2022)“…The formation of heterobimetallic complexes from parent cyclic trinuclear complexes (CTCs) of gold(I) has become straightforward in recent years with this team…”
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Sulfonate- or carboxylate-functionalized N-heterocyclic bis-carbene ligands and related water soluble silver complexes
Published in Dalton transactions : an international journal of inorganic chemistry (01-01-2009)“…New N-heterocyclic carbene ligand precursors {H(2)C(HTz(R))(2)} and {H(2)C(HIm(R))(2)} (HTz = 1,2,4-triazole; HIm = imidazole; R = PrSO(3) or EtCOO) were…”
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Synthesis and characterization of azolate gold(I) phosphane complexes as thioredoxin reductase inhibiting antitumor agents
Published in Dalton transactions : an international journal of inorganic chemistry (07-05-2012)“…Following an increasing interest in the gold drug therapy field, nine new neutral azolate gold(I) phosphane compounds have been synthesized and tested as…”
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Solventless Supramolecular Chemistry via Vapor Diffusion of Volatile Small Molecules upon a New Trinuclear Silver(I)-Nitrated Pyrazolate Macrometallocyclic Solid: An Experimental/Theoretical Investigation of the Dipole/Quadrupole Chemisorption Phenomena
Published in Inorganic chemistry (16-12-2013)“…A comparative study on the tendency of a new trinuclear silver(I) pyrazolate, namely, [N,N-(3,5-dinitropyrazolate)Ag]3 (1), and a similar compound known…”
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Cupriphication of gold to sensitize d^sup 10^-d^sup 10^ metal-metal bonds and near-unity phosphorescence quantum yields
Published in Proceedings of the National Academy of Sciences - PNAS (27-06-2017)“…Outer-shell s0/p0 orbital mixing with d10 orbitals and symmetry reduction upon cupriphication of cyclic trinuclear trigonal-planar gold(I) complexes are found…”
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Copper(I) and copper(II) metallacycles as catalysts for microwave assisted selective oxidation of cyclohexane
Published in Polyhedron (25-09-2017)“…Cu(I) and Cu(II) metallocycles were prepared with pyrazolates having CF3 or NO2 groups in the 3 and 5 positions. According to similar reaction routes, they…”
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Halide and Nitrite Recognizing Hexanuclear Metallacycle Copper(II) Pyrazolates
Published in Inorganic chemistry (07-02-2011)“…Halide-centered hexanuclear, anionic copper(II) pyrazolate complexes [trans-Cu6((3,5-CF3)2pz)6(OH)6X]−, X = Cl, Br, I are isolated in a good yield from the…”
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Cupriphication of gold to sensitize d 10 -d 10 metal-metal bonds and near-unity phosphorescence quantum yields
Published in Proceedings of the National Academy of Sciences - PNAS (27-06-2017)“…Outer-shell s /p orbital mixing with d orbitals and symmetry reduction upon cupriphication of cyclic trinuclear trigonal-planar gold(I) complexes are found to…”
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Gold(I) and Silver(I) Mixed-Metal Trinuclear Complexes: Dimeric Products from the Reaction of Gold(I) Carbeniates or Benzylimidazolates with Silver(I) 3,5-Diphenylpyrazolate
Published in Inorganic chemistry (18-09-2006)“…Trinuclear mixed-metal gold−silver compounds are obtained by the reaction of gold(I) carbeniate [Au(μ-C(OEt)NC6H4-p-CH3)]3, TR(carb), or gold(I) imidazolate…”
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Self-assembly of a High-Nuclearity Chloride-Centered Copper(II) Cluster. Structure and Magnetic Properties of [Au(PPh3)2][trans-Cu6(μ-OH)6{μ-(3,5-CF3)2pz}6Cl]
Published in Inorganic chemistry (02-04-2007)“…A chloride-centered hexanuclear copper(II) pyrazolate [Au(PPh3)2][trans-Cu6(μ-OH)6{μ-(3,5-CF3)2pz}6Cl] is isolated from the reaction of the trinuclear…”
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Mono and Tetranuclear Gold(I) Complexes of Tris(1-benzylimidazole-2-yl)phosphine
Published in Inorganic chemistry (18-01-2010)“…The reaction of tris(1-benzylimidazole-2-yl)phosphine, (Bzim)3P, 1, with Ph3AsAuCl in 1:1 stoichiometric ratio produced (Bzim)3PAuCl, 2. The reaction of…”
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CYCLIC TRINUCLEAR GOLD(I) COMPOUNDS: SYNTHESIS, STRUCTURES AND SUPRAMOLECULAR ACID-BASE π-STACKS
Published in Comments on modern chemistry. Part A, Comments on inorganic chemistry (01-09-2003)“…Trinuclear 9-membered rings can be formed by gold(I) ions with exobidentate C,N or N,N monoanionic ligands. They are generally slightly irregular and puckered…”
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