Search Results - "Burek, Bastien O."
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Modeling and Optimization of the Photocatalytic Reduction of Molecular Oxygen to Hydrogen Peroxide over Titanium Dioxide
Published in ACS catalysis (04-01-2019)“…This study focuses on understanding the mechanisms for optimization of the photocatalytic hydrogen peroxide production over TiO2 (Aeroxide P25). Via precise…”
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Selective Activation of C−H Bonds in a Cascade Process Combining Photochemistry and Biocatalysis
Published in Angewandte Chemie International Edition (27-11-2017)“…Selective oxyfunctionalizations of inert C−H bonds can be achieved under mild conditions by using peroxygenases. This approach, however, suffers from the poor…”
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Hydrocarbon Synthesis via Photoenzymatic Decarboxylation of Carboxylic Acids
Published in Journal of the American Chemical Society (20-02-2019)“…A recently discovered photodecarboxylase from Chlorella variabilis NC64A (CvFAP) bears the promise for the efficient and selective synthesis of hydrocarbons…”
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Artificial Light‐Harvesting Complexes Enable Rieske Oxygenase Catalyzed Hydroxylations in Non‐Photosynthetic cells
Published in Angewandte Chemie International Edition (02-03-2020)“…In this study, we coupled a well‐established whole‐cell system based on E. coli via light‐harvesting complexes to Rieske oxygenase (RO)‐catalyzed…”
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Intensification of Photobiocatalytic Decarboxylation of Fatty Acids for the Production of Biodiesel
Published in ChemSusChem (18-02-2021)“…Light‐driven biocatalytic processes are notoriously hampered by poor penetration of light into the turbid reaction media. In this study, wirelessly powered…”
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Kinetic effects and oxidation pathways of sacrificial electron donors on the example of the photocatalytic reduction of molecular oxygen to hydrogen peroxide over illuminated titanium dioxide
Published in Catalysis today (01-09-2019)“…[Display omitted] •Intermediates of electron donors have a great impact on the photocatalytic reaction.•Proposal of a reaction pathway for complete t-butanol…”
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Cascading g‑C3N4 and Peroxygenases for Selective Oxyfunctionalization Reactions
Published in ACS catalysis (02-08-2019)“…Peroxygenases are very interesting catalysts for specific oxyfunctionalization chemistry. Instead of relying on complicated electron transport chains, they…”
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Robust Light Driven Enzymatic Oxyfunctionalization via Immobilization of Unspecific Peroxygenase
Published in ChemSusChem (07-12-2023)“…Unspecific peroxygenases have attracted interest in synthetic chemistry, especially for the oxidative activation of C−H bonds, as they only require hydrogen…”
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Photochemistry at Scale: Wireless Light Emitters Drive Sustainability in Process Research & Development
Published in European journal of organic chemistry (04-02-2022)“…Carbon−carbon bond formation by dual Iridium‐Nickel photoredox catalysis has gained a lot of attention for late‐stage cross‐couplings of alkyls with aryls…”
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Photoenzymatic Hydroxylation of Ethylbenzene Catalyzed by Unspecific Peroxygenase: Origin of Enzyme Inactivation and the Impact of Light Intensity and Temperature
Published in ChemCatChem (04-07-2019)“…Photoenzymatic cascades can be used for selective oxygenation of C−H‐Bonds under mild conditions circumventing the hydrogen peroxide mediated peroxygenase…”
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Combined anodic and cathodic peroxide production in an undivided carbonate/bicarbonate electrolyte with 144% combined current efficiency
Published in Frontiers in catalysis (17-05-2024)“…In recent years, the electrochemical synthesis of peroxides has attracted renewed interest as a potential environmentally friendly production compared to the…”
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Process Intensification as Game Changer in Enzyme Catalysis
Published in Frontiers in catalysis (21-03-2022)“…Enzyme catalysis, made tremendous progress over the last years in identification of new enzymes and new enzymatic reactivity’s as well as optimization of…”
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Artifizielle Lichtsammelkomplexe ermöglichen Rieske‐Oxygenase‐ katalysierte Hydroxylierungen in nicht‐photosynthetischen Zellen
Published in Angewandte Chemie (02-03-2020)“…In dieser Studie wurde ein auf E. coli basierendes Ganzzellsystem über Lichtsammelkomplexe an Rieske‐Oxygenasen(RO)‐katalysierte Hydroxylierungen in vivo…”
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Selektive C‐H‐Bindungsaktivierung durch eine Kaskade aus Photochemie und Biokatalyse
Published in Angewandte Chemie (27-11-2017)“…Abstract Selektive Oxyfunktionalisierungen von inerten C‐H‐Bindungen können unter milden Bedingungen durch den Einsatz von Peroxygenasen erreicht werden…”
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Fate and Reactivity of Peroxides Formed over BiVO4 Anodes in Bicarbonate Electrolytes
Published in ACS energy letters (10-03-2023)Get full text
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The Importance of Precise Reaction Condition Control for the Comparison of Photocatalyst Materials on the Example of Hydrogen Peroxide Formation over Polymeric Carbon Nitrides
Published in ChemPhotoChem (01-11-2023)“…In our study, we aimed to show how different reaction parameters can affect production rates using photocatalytic hydrogen peroxide formation by different…”
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Front Cover: Photochemistry at Scale: Wireless Light Emitters Drive Sustainability in Process Research & Development (Eur. J. Org. Chem. 5/2022)
Published in European journal of organic chemistry (04-02-2022)“…The Front Cover shows free‐moving wirelessly‐powered light emitters, which can be used to internally illuminate photochemical reactions. This enables easier…”
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Fate and Reactivity of Peroxides Formed over BiVO 4 Anodes in Bicarbonate Electrolytes
Published in ACS energy letters (10-03-2023)Get full text
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Cascading g-C 3 N 4 and Peroxygenases for Selective Oxyfunctionalization Reactions
Published in ACS catalysis (02-08-2019)Get full text
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Selektive C‐H‐Bindungsaktivierung durch eine Kaskade aus Photochemie und Biokatalyse
Published in Angewandte Chemie (27-11-2017)“…Selektive Oxyfunktionalisierungen von inerten C‐H‐Bindungen können unter milden Bedingungen durch den Einsatz von Peroxygenasen erreicht werden. Dieser Ansatz…”
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