Search Results - "Buravov, Lev I."
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A New Charge-Ordered Molecular Conductor: κ-(BEDT-TTF)2K+(18-crown-6)[CoII(NCS)4]∙(H2O)
Published in Crystals (Basel) (01-10-2023)“…A new molecular conductor, i.e., κ-(BEDT-TTF)2K+(18-crown-6)[CoII(NCS)4]∙(H2O), is semiconductive with substantial charge gap values (ΔE) of 0.57 eV (measured)…”
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Multifunctional Compound Combining Conductivity and Single-Molecule Magnetism in the Same Temperature Range
Published in Inorganic chemistry (05-03-2018)“…We report the first highly conducting single-molecule magnet, (BEDO)4[ReF6]·6H2O [1; BEDO = bis(ethylenedioxo)tetrathiafulvalene], whose conductivity and…”
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New Radical-Cation Salts Based on the TMTTF and TMTSF Donors with Iron and Chromium Bis(Dicarbollide) Complexes: Synthesis, Structure, Properties
Published in Crystals (Basel) (01-09-2021)“…New radical-cation salts based on tetramethyltetrathiafulvalene (TMTTF) and tetramethyltetraselenefulvalene (TMsTSF) with metallacarborane anions…”
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Influence of the Size and Shape of Halopyridines Guest Molecules G on the Crystal Structure and Conducting Properties of Molecular (Super)Conductors of (BEDT-TTF)4A+[M3+(C2O4)3]·G Family
Published in Magnetochemistry (04-06-2021)“…New organic (super)conductors of the β″-(BEDT-TTF)4A+[M3+(C2O4)3]G family, where BEDT-TTF is bis(ethylenedithio)tetrathiafulvalene; M is Fe; A is the…”
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New Radical Cation Salts Based on BDH-TTP Donor: Two Stable Molecular Metals with a Magnetic [ReF6]2− Anion and a Semiconductor with a [ReO4]− Anion
Published in Magnetochemistry (20-04-2021)“…Three radical cation salts of BDH-TTP with the paramagnetic [ReF6]2− and diamagnetic [ReO4]− anions have been synthesized: κ-(BDH-TTP)4ReF6 (1),…”
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Specific Structural Disorder in an Anion Layer and Its Influence on Conducting Properties of New Crystals of the (BEDT-TTF)4A+[M3+(ox)3]G Family, Where G Is 2-Halopyridine; M Is Cr, Ga; A+ Is [K0.8(H3O)0.2]
Published in Crystals (Basel) (10-02-2018)“…New crystals (1-4) of organic conductors based on the radical cation salts of the bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) with paramagnetic and…”
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Metal-Insulator Interplays Rendered by Lattice Transformations and Structural Disorder in DOEO Salts
Published in European journal of inorganic chemistry (01-08-2014)“…Three salts, β‐DOEO2NO3(H2O) (I), β″‐DOEO2NO3(H2O) (II), and β″‐DOEO2HSO4(H2O) (III), have been synthesized and characterized by means of four‐probe…”
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Solvent and Dihalide Substituent Effects on Crystal Structure, Spin‐Crossover Behavior and Conductivity of the Cationic Mn(III) Complexes with Electroactive TCNQ Counteranions
Published in European journal of inorganic chemistry (20-06-2024)“…Cationic Mn(III) complexes with 3,5‐Hal‐sal2323 (Hal=diCl, diBr, BrCl) ligands containing electroactive TCNQ anions as counterions have been synthesized:…”
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The Conducting Spin-Crossover Compound Combining Fe(II) Cation Complex with TCNQ in a Fractional Reduction State
Published in Inorganic chemistry (06-09-2016)“…The radical anion salt [Fe{HC(pz)3}2](TCNQ)3 demonstrates conductivity and spin-crossover (SCO) transition associated with Fe(II) complex cation subsystem…”
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Synthesis and study of C -substituted methylthio derivatives of cobalt bis(dicarbollide)
Published in RSC advances (16-01-2020)“…The -methylthio derivatives of cobalt bis(dicarbollide) were synthesized by reaction of anhydrous CoCl with -carborane [7-MeS-7,8-C B H ] and isolated as a…”
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New Fulvalenium Salts of Cobalt Bis(dicarbollide): Crystal Structures and Electrical Conductivities
Published in Crystals (Basel) (06-01-2012)“…New radical cation salts (BEDT-TTF)[8,8',(7)-Cl2(Cl0.09)-3,3'-Co(1,2-C2B9H9.91)(1',2'-C2B9H10)] (1), (BEDT-TTF)[8,8'-Br0.75Cl1.25-3,3'-Co(1,2-C2B9H10)2] (2),…”
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First charge-transfer complexes between tetrathiafulvalene and 1,2,5-chalcogenadiazole derivatives: Design, synthesis, crystal structures, electronic and electrical properties
Published in Synthetic metals (31-12-2012)“…[Display omitted] ► The first CT complexes of TTF with 1,2,5-chalcogenadiazoles are designed. ► These complexes were synthesized and characterized by…”
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Metallic Bi- and Monolayered Radical Cation Salts Based on Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) with the Tris(oxalato)gallate Anion
Published in European journal of inorganic chemistry (01-08-2014)“…New metallic triclinic (1) and monoclinic (2) crystals of the (BEDT‐TTF)4AI[MIII(C2O4)3]G family of organic molecular conductors have been prepared:…”
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π-Donor BETS Based Bifunctional Superconductor with Polymeric Dicyanamidomanganate(II) Anion Layer: κ-(BETS)2Mn[N(CN)2]3
Published in Journal of the American Chemical Society (11-06-2008)“…Crystals of the bis(ethylenedithio)tetraselenafulvalene (BETS) radical cation salt with dicyanamidomanganate(II) anion, κ-(BETS)2Mn[N(CN)2]3, were synthesized,…”
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15
Molecular Conductors with a 8-Hydroxy cobalt Bis(dicarbollide) Anion
Published in Inorganic chemistry (17-01-2011)“…Molecular conductors based on the 8-hydroxy cobalt bis(dicarbollide) anion, (TMTTF)[8-HO-3,3′-Co(1,2-C2B9H10)(1′,2′-C2B9H11)] (1),…”
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The Highly Conducting Spin-Crossover Compound Combining Fe(III) Cation Complex with TCNQ in a Fractional Reduction State. Synthesis, Structure, Electric and Magnetic Properties
Published in Magnetochemistry (01-03-2017)“…Three systems [Fe(III)(sal2-trien)](TCNQ)n·X (n = 1, 2, X = MeOH, CH3CN, H2O) showing spin-crossover transition, conductivity and ferromagnetic coupling were…”
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A New Charge-Ordered Molecular Conductor: Iκ/I
Published in Crystals (Basel) (01-10-2023)“…A new molecular conductor, i.e., κ-(BEDT-TTF)[sub.2]K[sup.+](18-crown-6)[Co[sup.II](NCS)[sub.4]]∙(H[sub.2]O), is semiconductive with substantial charge gap…”
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First radical cation salts based on dibenzotetrathiafulvalene (DBTTF) with metallacarborane anions: Synthesis, structure, properties
Published in Journal of organometallic chemistry (21-12-2020)“…•(DBTTF)[3,3′-Fe(1,2-C2B9H11)2] and (DBTTF)2[3,3′-Cr(1,2-C2B9H11)2] were synthesized.•Both these compounds are semiconductors at room temperature.•The chromium…”
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First EOTT and BPDT-TTF based molecular conductors with [8,8′-Cl2–3,3′-Fe(1,2-C2B9H10)2]− anion – synthesis, structure, properties
Published in Journal of organometallic chemistry (15-09-2021)“…•(EOTT)2[8,8′-Cl2–3,3′-Fe(1,2-C2B9H10)2] and (BPDT)2[8,8′-Cl2–3,3′-Fe(1,2-C2B9H10)2] were synthesized.•Solid state structures of these compounds were…”
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First hybrid radical-cation salts with halogen substituted iron bis(dicarbollide) anions – synthesis, structure, properties
Published in Journal of organometallic chemistry (01-11-2017)“…New radical-cation salts based on bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF or ET) were synthesized: (ЕТ)2[8,8′-Br2-3,3′-Fe(1,2-C2B9H10)2] (1) and…”
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