Search Results - "Buckley, Aya K."
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Electrocatalysis at Organic–Metal Interfaces: Identification of Structure–Reactivity Relationships for CO2 Reduction at Modified Cu Surfaces
Published in Journal of the American Chemical Society (08-05-2019)“…The limited selectivity of existing CO2 reduction catalysts and rising levels of CO2 in the atmosphere necessitate the identification of specific…”
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Bimetallic Coordination Insertion Polymerization of Unprotected Polar Monomers: Copolymerization of Amino Olefins and Ethylene by Dinickel Bisphenoxyiminato Catalysts
Published in Journal of the American Chemical Society (13-03-2013)“…Dinickel bisphenoxyiminato complexes based on highly substituted p- and m-terphenyl backbones were synthesized, and the corresponding atropisomers were…”
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CO₂ reduction on pure Cu produces only H₂ after subsurface O is depleted: Theory and experiment
Published in Proceedings of the National Academy of Sciences - PNAS (08-06-2021)“…We elucidate the role of subsurface oxygen on the production of C₂ products from CO₂ reduction over Cu electrocatalysts using the newly developed grand…”
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Nanomaterials for carbon dioxide conversion at industrial scale
Published in Nature nanotechnology (01-08-2022)“…Using our company’s CO 2 electrolysers as a model, we describe the challenges involved in incorporating nanomaterial catalysts into industrial-scale…”
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Stereoelectronic Effects on the Binding of Neutral Lewis Bases to CdSe Nanocrystals
Published in Journal of the American Chemical Society (13-06-2018)“…Using 31P nuclear magnetic resonance (NMR) spectroscopy, we monitor the competition between tri-n-butylphosphine (Bu3P) and various amine and phosphine ligands…”
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Approaching 100% Selectivity at Low Potential on Ag for Electrochemical CO2 Reduction to CO Using a Surface Additive
Published in ACS catalysis (06-08-2021)“…We report the discovery of a quaternary ammonium surface additive for CO2 reduction on Ag surfaces that changes the Faradaic efficiency for CO from 25% on Ag…”
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Cu Based Dilute Alloys for Tuning the C2+ Selectivity of Electrochemical CO2 Reduction
Published in Small (Weinheim an der Bergstrasse, Germany) (01-11-2024)“…Electrochemical CO2 reduction is a promising technology for replacing fossil fuel feedstocks in the chemical industry but further improvements in catalyst…”
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Cu Based Dilute Alloys for Tuning the C 2+ Selectivity of Electrochemical CO 2 Reduction
Published in Small (Weinheim an der Bergstrasse, Germany) (12-07-2024)“…Electrochemical CO reduction is a promising technology for replacing fossil fuel feedstocks in the chemical industry but further improvements in catalyst…”
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2022 roadmap on low temperature electrochemical CO2 reduction
Published in JPhys Energy (01-10-2022)“…Electrochemical CO2 reduction (CO2R) is an attractive option for storing renewable electricity and for the sustainable production of valuable chemicals and…”
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10
Electrocatalysis at Organic-Metal Interfaces: Identification of Structure-Reactivity Relationships for CO 2 Reduction at Modified Cu Surfaces
Published in Journal of the American Chemical Society (08-05-2019)“…The limited selectivity of existing CO reduction catalysts and rising levels of CO in the atmosphere necessitate the identification of specific…”
Get full text
Journal Article -
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Aluminum Metal–Organic Framework Triggers Carbon Dioxide Reduction Activity
Published in ACS applied energy materials (24-02-2020)“…Confinement of metal centers is a powerful tool to manipulate reactivity and tune selectivity in chemical transformations. While aluminum as a foil is inactive…”
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2022 roadmap on low temperature electrochemical CO 2 reduction
Published in JPhys Energy (03-10-2022)“…Electrochemical CO 2 reduction (CO 2 R) is an attractive option for storing renewable electricity and for the sustainable production of valuable chemicals and…”
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Journal Article -
13
Cu Based Dilute Alloys for Tuning the C2+ Selectivity of Electrochemical CO2 Reduction
Published in Small (Weinheim an der Bergstrasse, Germany) (12-07-2024)“…Abstract Electrochemical CO 2 reduction is a promising technology for replacing fossil fuel feedstocks in the chemical industry but further improvements in…”
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Effect of Gold Catalyst Surface Morphology on Wetting Behavior and Electrochemical CO2 Reduction Performance in a Large-Area Zero-Gap Gas Diffusion Electrolyzer
Published in Journal of physical chemistry. C (09-11-2022)“…Catalyst surface area and wetting behavior are key factors in determining the performance of gas diffusion electrode (GDE) electrolyzers for electrochemical…”
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CO 2 reduction on pure Cu produces only H 2 after subsurface O is depleted: Theory and experiment
Published in Proceedings of the National Academy of Sciences - PNAS (08-06-2021)“…Electrochemical reduction of CO 2 to fuels and valuable chemicals is a global imperative to address energy and climate challenges. Despite enormous efforts,…”
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Approaching 100% Selectivity at Low Potential on Ag for Electrochemical CO 2 Reduction to CO Using a Surface Additive
Published in ACS catalysis (06-08-2021)“…We report the discovery of a quaternary ammonium surface additive for CO2 reduction on Ag surfaces that changes the Faradaic efficiency for CO from 25% on Ag…”
Get full text
Journal Article -
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Carbon Dioxide Reduction at Organic-Metal Interfaces
Published 01-01-2019“…Chapter 1 – The rising levels of CO2 in the atmosphere necessitate further investigation into methods of converting CO2 into more valuable products. In this…”
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Dissertation