Search Results - "Brunet, Gabriel"

Shining New Light on Multifunctional Lanthanide Single‐Molecule Magnets by Marin, Riccardo, Brunet, Gabriel, Murugesu, Muralee

“…Single‐molecule magnets (SMMs) are at the forefront of new technological advances in quantum information processing and spintronics. Despite the recent…”
Get full text

Significant Enhancement of Energy Barriers in Dinuclear Dysprosium Single-Molecule Magnets Through Electron-Withdrawing Effects by Habib, Fatemah, Brunet, Gabriel, Vieru, Veacheslav, Korobkov, Ilia, Chibotaru, Liviu F., Murugesu, Muralee

“…The effect of electron-withdrawing ligands on the energy barriers of Single-Molecule Magnets (SMMs) is investigated. By introducing highly electron-withdrawing…”
Get full text

Slow Magnetic Relaxation Observed in Dysprosium Compounds Containing Unsupported Near-Linear Hydroxo- and Fluoro-Bridges by Brunet, Gabriel, Habib, Fatemah, Korobkov, Ilia, Murugesu, Muralee

“…The encapsulating N1,N3-bis­(3-methoxysalicylidene)­diethylenetriamine (H2valdien) ligand was employed to isolate two novel DyIII compounds which contain rare…”
Get full text

Exploring the dual functionality of an ytterbium complex for luminescence thermometry and slow magnetic relaxation by Brunet, Gabriel, Marin, Riccardo, Monk, Melissa-Jane, Resch-Genger, Ute, Gálico, Diogo A, Sigoli, Fernando A, Suturina, Elizaveta A, Hemmer, Eva, Murugesu, Muralee

“…We present a comprehensive investigation of the magnetic and optical properties of an ytterbium complex, which combines two desirable and practical features…”
Get full text

Triplet‐State Position and Crystal‐Field Tuning in Opto‐Magnetic Lanthanide Complexes: Two Sides of the Same Coin by Gálico, Diogo A., Marin, Riccardo, Brunet, Gabriel, Errulat, Dylan, Hemmer, Eva, Sigoli, Fernando A., Moilanen, Jani O., Murugesu, Muralee

“…Lanthanide‐complex‐based luminescence thermometry and single‐molecule magnetism are two effervescent fields of research, owing to the great promise they hold…”
Get full text

Stepwise crystallographic visualization of dynamic guest binding in a nanoporous framework by Brunet, Gabriel, Safin, Damir A, Aghaji, Mohammad Z, Robeyns, Koen, Korobkov, Ilia, Woo, Tom K, Murugesu, Muralee

“…Binding sites are at the heart of all host-guest systems, whether biological or chemical. When considering binding sites that form covalent bonds with the…”
Get full text

Hidden Transformations of a Crystalline Sponge: Elucidating the Stability of a Highly Porous Three-Dimensional Metal–Organic Framework by Brunet, Gabriel, Safin, Damir A, Korobkov, Ilia, Cognigni, Andrea, Murugesu, Muralee

“…We present our investigations on the stability of a cobalt thiocyanate-based metal–organic framework (MOF), coordinated by the…”
Get full text

Unprecedented Octanuclear DyIII Cluster Exhibiting Single-Molecule Magnet Behavior by Lacelle, Thomas, Brunet, Gabriel, Holmberg, Rebecca J, Gabidullin, Bulat, Murugesu, Muralee

“…An unprecedented Dy8 cluster, [Dy8(μ4-O)­(μ3-OH)8(vht)4(NO3)2(H2O)8]­(NO3)4, composed of two fused and distorted [Dy4(μ3-OH)4]8+ cubane units is reported. The…”
Get full text

A Barrel‐Shaped Metal–Organic Blue‐Box Analogue with Photo‐/Redox‐Switchable Behavior by Brunet, Gabriel, Suturina, Elizaveta A., George, Guillaume P. C., Ovens, Jeffrey S., Richardson, Paul, Bucher, Christophe, Murugesu, Muralee

“…Donor–acceptor interactions are ubiquitous in the design and understanding of host–guest complexes. Despite their non‐covalent nature, they can readily dictate…”
Get full text

Anion-Dependent Catalytic C-C Bond Cleavage of a Lignin Model within a Cationic Metal-Organic Framework by do Pim, Walace D, Mendonça, Fernanda G, Brunet, Gabriel, Facey, Glenn A, Chevallier, Floris, Bucher, Christophe, Baker, R Tom, Murugesu, Muralee

“…The development of heterogeneous catalysts capable of selectively converting lignin model compounds into products of added value offers an exciting avenue to…”
Get full text

Reversible Redox, Spin Crossover, and Superexchange Coupling in 3 d Transition‐Metal Complexes of Bis ‐azinyl Analogues of 2,2′:6′,2′′‐Terpyridine by Zhang, Yixin, Harriman, Katie L. M., Brunet, Gabriel, Pialat, Amélie, Gabidullin, Bulat, Murugesu, Muralee

“…The terpyridine‐inspired tridentate ligand, 2,6‐bis(5,6‐dialkyl‐1,2,4‐triazin‐3‐yl)‐pyridine (BTP), was synthesized and utilized to isolate five [M II (BTP) 2…”
Get full text

Unprecedented Octanuclear Dy III Cluster Exhibiting Single-Molecule Magnet Behavior by Lacelle, Thomas, Brunet, Gabriel, Holmberg, Rebecca J., Gabidullin, Bulat, Murugesu, Muralee

Get full text

Reversible Redox, Spin Crossover, and Superexchange Coupling in 3d Transition‐Metal Complexes of Bis‐azinyl Analogues of 2,2′:6′,2′′‐Terpyridine by Zhang, Yixin, Harriman, Katie L. M., Brunet, Gabriel, Pialat, Amélie, Gabidullin, Bulat, Murugesu, Muralee

“…The terpyridine‐inspired tridentate ligand, 2,6‐bis(5,6‐dialkyl‐1,2,4‐triazin‐3‐yl)‐pyridine (BTP), was synthesized and utilized to isolate five [MII(BTP)2]2+…”
Get full text

Exploring the dual functionality of an ytterbium complex for luminescence thermometry and slow magnetic relaxation† †Electronic supplementary information (ESI) available: Additional crystallographic details, and full characterization (magnetic plots, quantum yield and lifetime measurements, and Stark sublevel determination) of the described complex. CCDC 1856853. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc00343f by Brunet, Gabriel, Marin, Riccardo, Monk, Melissa-Jane, Resch-Genger, Ute, Gálico, Diogo A., Sigoli, Fernando A., Suturina, Elizaveta A., Hemmer, Eva, Murugesu, Muralee

“…A combined experimental and theoretical approach reveals the intricacies related to an Yb III complex, which functions dually as a SMM and a luminescent…”
Get full text

Traveling/non-traveling phase transition and non-ergodic properties in the random transverse-field Ising model on the Cayley tree by Chakrabarti, Ankita, Martins, Cyril, Laflorencie, Nicolas, Georgeot, Bertrand, Brunet, Éric, Lemarié, Gabriel

“…We study the random transverse field Ising model on a finite Cayley tree. This enables us to probe key questions arising in other important disordered quantum…”
Get full text

Design Strategy for the Controlled Generation of Cationic Frameworks and Ensuing Anion-Exchange Capabilities by Brunet, Gabriel, Robeyns, Koen, Huynh, Racheal P. S, Lin, Jian-Bin, Collins, Sean P, Facey, Glenn A, Shimizu, George K. H, Woo, Tom K, Murugesu, Muralee

“…Cationic frameworks are an emerging class of exceptional solid adsorbents capable of encapsulating highly toxic and persistent anionic pollutants. The…”
Get full text

A tunable lanthanide cubane platform incorporating air-stable radical ligands for enhanced magnetic communication by Brunet, Gabriel, Hamwi, Milad, Lemes, Maykon A., Gabidullin, Bulat, Murugesu, Muralee

“…The unique properties of polynuclear cluster-aggregates have long been staples in the molecular magnetism community. The initial success observed in high…”
Get full text

Stepwise crystallographic visualization of dynamic guest binding in a nanoporous frameworkElectronic supplementary information (ESI) available: Materials and instrumentations, synthesis and characterization, experimental details, X-ray refinement details, TGA, DRS and FTIR. CCDC 1475220 (2), 1475221 (3), 1475222 (4). Full crystallographic data for the solved structures have been deposited in the Cambridge Crystallographic Data Center. For ESI and crystallographic data in CIF or other electronic by Brunet, Gabriel, Safin, Damir A, Aghaji, Mohammad Z, Robeyns, Koen, Korobkov, Ilia, Woo, Tom K, Murugesu, Muralee

“…Binding sites are at the heart of all host-guest systems, whether biological or chemical. When considering binding sites that form covalent bonds with the…”
Get full text

Stepwise crystallographic visualization of dynamic guest binding in a nanoporous framework† †Electronic supplementary information (ESI) available: Materials and instrumentations, synthesis and characterization, experimental details, X-ray refinement details, TGA, DRS and FTIR. CCDC 1475220 (2), 1475221 (3), 1475222 (4). Full crystallographic data for the solved structures have been deposited in the Cambridge Crystallographic Data Center. For ESI and crystallographic data in CIF or other electron by Brunet, Gabriel, Safin, Damir A., Aghaji, Mohammad Z., Robeyns, Koen, Korobkov, Ilia, Woo, Tom K., Murugesu, Muralee

“…The dynamic uptake behaviour of a gaseous guest has been observed crystallographically, yielding a unique and ever-changing set of host–guest interactions that…”
Get full text

Multifunktionale Einzelmolekülmagnete auf Lanthanoidbasis in neuem Licht by Marin, Riccardo, Brunet, Gabriel, Murugesu, Muralee

“…Einzelmolekülmagnete (SMMs) stehen bei neuen technischen Entwicklungen in der Quanteninformationsverarbeitung und Spintronik im Vordergrund. Trotz der…”
Get full text