Search Results - "Brudvig, Gary W"

Progress Toward a Molecular Mechanism of Water Oxidation in Photosystem II by Vinyard, David J, Brudvig, Gary W

“…The active site of photosynthetic water oxidation is the oxygen-evolving complex (OEC) in the photosystem II (PSII) reaction center. The OEC is a Mn 4 CaO 5…”
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The O2‑Evolving Complex of Photosystem II: Recent Insights from Quantum Mechanics/Molecular Mechanics (QM/MM), Extended X‑ray Absorption Fine Structure (EXAFS), and Femtosecond X‑ray Crystallography Data by Askerka, Mikhail, Brudvig, Gary W, Batista, Victor S

“…Efficient photoelectrochemical water oxidation may open a way to produce energy from renewable solar power. In biology, generation of fuel due to water…”
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Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction by Weng, Zhe, Wu, Yueshen, Wang, Maoyu, Jiang, Jianbing, Yang, Ke, Huo, Shengjuan, Wang, Xiao-Feng, Ma, Qing, Brudvig, Gary W., Batista, Victor S., Liang, Yongye, Feng, Zhenxing, Wang, Hailiang

“…Restructuring-induced catalytic activity is an intriguing phenomenon of fundamental importance to rational design of high-performance catalyst materials. We…”
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Electrochemical CO2 Reduction to Hydrocarbons on a Heterogeneous Molecular Cu Catalyst in Aqueous Solution by Weng, Zhe, Jiang, Jianbing, Wu, Yueshen, Wu, Zishan, Guo, Xiaoting, Materna, Kelly L, Liu, Wen, Batista, Victor S, Brudvig, Gary W, Wang, Hailiang

“…Exploration of heterogeneous molecular catalysts combining the atomic-level tunability of molecular structures and the practical handling advantages of…”
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Water-Splitting Chemistry of Photosystem II by McEvoy, James P, Brudvig, Gary W

“…The water-splitting chemistry of the enzyme photosystem II is discussed. In particular, the "donor side" oxidation pathway is examined…”
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Water oxidation chemistry of photosystem II by Brudvig, Gary W

“…Photosystem II (PSII) uses light energy to split water into protons, electrons and O…”
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Highly Active and Robust Cp Iridium Complexes for Catalytic Water Oxidation by Hull, Jonathan F, Balcells, David, Blakemore, James D, Incarvito, Christopher D, Eisenstein, Odile, Brudvig, Gary W, Crabtree, Robert H

“…A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*IrO complex…”
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Photosynthetic Water Oxidation: Insights from Manganese Model Chemistry by Young, Karin J, Brennan, Bradley J, Tagore, Ranitendranath, Brudvig, Gary W

“…Conspectus Catalysts for light-driven water oxidation are a critical component for development of solar fuels technology. The multielectron redox chemistry…”
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Stable iridium dinuclear heterogeneous catalysts supported on metal-oxide substrate for solar water oxidation by Zhao, Yanyan, Yang, Ke R., Wang, Zechao, Yan, Xingxu, Cao, Sufeng, Ye, Yifan, Dong, Qi, Zhang, Xizi, Thorne, James E., Jin, Lei, Materna, Kelly L., Trimpalis, Antonios, Bai, Hongye, Fakra, Sirine C., Zhong, Xiaoyan, Wang, Peng, Pan, Xiaoqing, Guo, Jinghua, Flytzani-Stephanopoulos, Maria, Brudvig, Gary W., Batista, Victor S., Wang, Dunwei

“…Atomically dispersed catalysts refer to substrate-supported heterogeneous catalysts featuring one or a few active metal atoms that are separated from one…”
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Synthesis and Reactivity of Paramagnetic Nickel Polypyridyl Complexes Relevant to C(sp2)–C(sp3)Coupling Reactions by Mohadjer Beromi, Megan, Brudvig, Gary W., Hazari, Nilay, Lant, Hannah M. C., Mercado, Brandon Q.

“…A number of new transition metal catalyzed methods for the formation of C(sp2)–C(sp3) bonds have recently been described. These reactions often utilize…”
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Mechanistic Study of an Improved Ni Precatalyst for Suzuki–Miyaura Reactions of Aryl Sulfamates: Understanding the Role of Ni(I) Species by Mohadjer Beromi, Megan, Nova, Ainara, Balcells, David, Brasacchio, Ann M, Brudvig, Gary W, Guard, Louise M, Hazari, Nilay, Vinyard, David J

“…Nickel precatalysts are potentially a more sustainable alternative to traditional palladium precatalysts for the Suzuki–Miyaura coupling reaction. Currently,…”
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Facet-Dependent Photoelectrochemical Performance of TiO2 Nanostructures: An Experimental and Computational Study by Li, Chuanhao, Koenigsmann, Christopher, Ding, Wendu, Rudshteyn, Benjamin, Yang, Ke R, Regan, Kevin P, Konezny, Steven J, Batista, Victor S, Brudvig, Gary W, Schmuttenmaer, Charles A, Kim, Jae-Hong

“…The behavior of crystalline nanoparticles depends strongly on which facets are exposed. Some facets are more active than others, but it is difficult to…”
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Electrocatalytic Water Oxidation by a Copper(II) Complex of an Oxidation-Resistant Ligand by Fisher, Katherine J, Materna, Kelly L, Mercado, Brandon Q, Crabtree, Robert H, Brudvig, Gary W

“…The copper­(II) complex Cu­(pyalk)2 (pyalk = 2-pyridyl-2-propanoate) is a robust homogeneous water-oxidation electrocatalyst under basic conditions (pH >…”
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Heme biomolecule as redox mediator and oxygen shuttle for efficient charging of lithium-oxygen batteries by Ryu, Won-Hee, Gittleson, Forrest S., Thomsen, Julianne M., Li, Jinyang, Schwab, Mark J., Brudvig, Gary W., Taylor, André D.

“…One of the greatest challenges with lithium-oxygen batteries involves identifying catalysts that facilitate the growth and evolution of cathode species on an…”
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Functional models for the oxygen-evolving complex of photosystem II by Cady, Clyde W., Crabtree, Robert H., Brudvig, Gary W.

“…In the last 10 years, a number of advances have been made in the study of the oxygen-evolving complex (OEC) of photosystem II (PSII). Along with this new…”
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Hematite-Based Solar Water Splitting in Acidic Solutions: Functionalization by Mono- and Multilayers of Iridium Oxygen-Evolution Catalysts by Li, Wei, Sheehan, Stafford W., He, Da, He, Yumin, Yao, Xiahui, Grimm, Ronald L., Brudvig, Gary W., Wang, Dunwei

“…Solar water splitting in acidic solutions has important technological implications, but has not been demonstrated to date in a dual absorber…”
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Comparing Photosynthetic and Photovoltaic Efficiencies and Recognizing the Potential for Improvement by Blankenship, Robert E., Tiede, David M., Barber, James, Brudvig, Gary W., Fleming, Graham, Ghirardi, Maria, Gunner, M. R., Junge, Wolfgang, Kramer, David M., Melis, Anastasios, Moore, Thomas A., Moser, Christopher C., Nocera, Daniel G., Nozik, Arthur J., Ort, Donald R., Parson, William W., Prince, Roger C., Sayre, Richard T.

“…Comparing photosynthetic and photovoltaic efficiencies is not a simple issue. Although both processes harvest the energy in sunlight, they operate in…”
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Structure of a monomeric photosystem II core complex from a cyanobacterium acclimated to far-red light reveals the functions of chlorophylls d and f by Gisriel, Christopher J., Shen, Gaozhong, Ho, Ming-Yang, Kurashov, Vasily, Flesher, David A., Wang, Jimin, Armstrong, William H., Golbeck, John H., Gunner, Marilyn R., Vinyard, David J., Debus, Richard J., Brudvig, Gary W., Bryant, Donald A.

“…Far-red light (FRL) photoacclimation in cyanobacteria provides a selective growth advantage for some terrestrial cyanobacteria by expanding the range of…”
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Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis by Blakemore, James D, Schley, Nathan D, Balcells, David, Hull, Jonathan F, Olack, Gerard W, Incarvito, Christopher D, Eisenstein, Odile, Brudvig, Gary W, Crabtree, Robert H

“…Iridium half-sandwich complexes of the types Cp*Ir(N−C)X, [Cp*Ir(N−N)X]X, and [CpIr(N−N)X]X are catalyst precursors for the homogeneous oxidation of water to…”
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Cytochrome b₅₅₉ and cyclic electron transfer within photosystem II by Shinopoulos, Katherine E, Brudvig, Gary W

“…Cytochrome b₅₅₉ (Cyt b₅₅₉), β-carotene (Car), and chlorophyll (Chl) cofactors participate in the secondary electron-transfer pathways in photosystem II (PSII),…”
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