Search Results - "Broadwater, Steven J."

The Continuous-Flow Synthesis of Ibuprofen by Bogdan, Andrew R., Poe, Sarah L., Kubis, Daniel C., Broadwater, Steven J., McQuade, D. Tyler

“…Let relief flow forth! A three‐step, continuous‐flow synthesis of ibuprofen was accomplished using a simplified microreactor. By designing a synthesis in which…”
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A New Interpretation of the Baylis−Hillman Mechanism by Price, Kristin E, Broadwater, Steven J, Walker, Brian J, McQuade, D. Tyler

“…On the basis of reaction rate data, we have proposed a new mechanism for the Baylis−Hillman reaction involving the formation of a hemiacetal intermediate. We…”
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Baylis−Hillman Mechanism:  A New Interpretation in Aprotic Solvents by Price, Kristin E, Broadwater, Steven J, Jung, Hyun M, McQuade, D. Tyler

“…Using reaction rate data collected in aprotic solvents, we have determined that the Baylis−Hillman rate-determining step is second order in aldehyde and first…”
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One-pot multi-step synthesis: a challenge spawning innovation by Broadwater, Steven J, Roth, Shoshannah L, Price, Kristin E, Kobaslija, Muris, McQuade, D Tyler

“…Creating one-pot synthetic routes is a challenge that is already spawning new chemistry, enzymes, materials, and mechanistic insight. Through one-pot…”
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Investigating PdEnCat Catalysis by Broadwater, Steven J, McQuade, D. Tyler

“…The catalytic behavior of three commercially available PdEnCat catalysts was explored. When the three-phase test was used, it was demonstrated that these…”
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Microencapsulated Linear Polymers:  “Soluble” Heterogeneous Catalysts by Price, Kristin E, Mason, Brian P, Bogdan, Andrew R, Broadwater, Steven J, Steinbacher, Jeremy L, McQuade, D. Tyler

“…A new strategy for supporting catalysts based on the microencapsulation of linear polymers is presented. In this paper, we present a DMAP capsule that is…”
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Self-Diffusion of Linear Polymers within Microcapsules by Price, Kristin E, Broadwater, Steven J, Bogdan, Andrew R, Keresztes, Ivan, Steinbacher, Jeremy L, McQuade, D. Tyler

“…We present a new strategy for the heterogenization of catalysts. The strategy relies on the containment of soluble polymers within a polyurea microcapsule…”
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A Comparison of Crystalline- and Graft Polymer-Based Chemosensors by Broadwater, Steven J, Hickey, Mary Kay, McQuade, D. Tyler

“…Herein, we report a highly sensitive luminescent thin film chemosensor constructed out of a small-molecule donor/acceptor system. Two types of films were…”
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Hydrolysis of cyclic phosphates by ribonuclease A: A computational study using a simplified ab initio quantum model by Wladkowski, Brian D., Ostazeski, Paul, Chenoweth, Sarah, Broadwater, Steven J., Krauss, Morris

“…The second step in the enzyme‐catalyzed hydrolysis of phosphate esters by ribonuclease A (RNase A) was studied using an ab initio quantum‐based model of the…”
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Determination of the Rotameric Stability of 1,2-Dihaloethanes Using Infrared Spectroscopy. A Combined Experimental and Computational Project for the Physical Chemistry Laboratory by Wladkowski, Brian D, Broadwater, Steven J

“…The effects of structure and environment on the rotameric energy difference between gauche and trans conformations of 1,2-disubstituted ethanes are determined…”
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The Continuous-Flow Synthesis of Ibuprofen by Bogdan, Andrew R., Poe, Sarah L., Kubis, Daniel C., Broadwater, Steven J., McQuade, D. Tyler

“…In einem einfachen Mikroreaktor gelang die dreistufige Synthese von Ibuprofen unter Flussbedingungen. Durch die Entwicklung einer Synthese, bei der Überschüsse…”
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Determination of the rotametric stability of 1,2-dihaloethanes using infrared spectroscopy by Wladkowski, Brian D, Broadwater, Steven J

“…Wladkowski and Broadwater present a study using a series of dihaloethanes including 1,2-dichloroethane (DCE), 1,2-dibromoethane (DBE), and 1,2-diiodoethane…”
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The Continuous‐Flow Synthesis of Ibuprofen by Bogdan, Andrew R., Poe, Sarah L., Kubis, Daniel C., Broadwater, Steven J., McQuade, D. Tyler

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