Search Results - "Brezinsky, Kenneth"
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A physics-based approach to modeling real-fuel combustion chemistry – II. Reaction kinetic models of jet and rocket fuels
Published in Combustion and flame (01-07-2018)“…We propose and test an alternative approach to modeling high-temperature combustion chemistry of multicomponent real fuels. The hybrid chemistry (HyChem)…”
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Chemical kinetic simulations behind reflected shock waves
Published in International journal of chemical kinetics (01-02-2006)“…Chemical kinetic simulations that more accurately consider reaction conditions behind reflected shock waves in a high pressure shock tube have been conducted…”
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Experimental and modeling study of the oxidation of F-24 jet fuel, and its mixture with an iso-paraffinic synthetic jet fuel, ATJ
Published in Combustion and flame (01-02-2021)“…Single pulse shock tube experiments were conducted to determine the oxidative decomposition products of F-24. Experiments were performed at 50 bar nominal…”
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Experimental and modeling study on the pyrolysis and oxidation of n-decane and n-dodecane
Published in Proceedings of the Combustion Institute (2013)“…High pressure n-decane and n-dodecane shock tube experiments were conducted to assist in the development of a Jet A surrogate kinetic model. Jet A is a…”
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Isomeric Product Distributions from the Self-Reaction of Propargyl Radicals
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14-07-2005)“…We have investigated the isomeric C6H6 product distributions of the self-reaction of propargyl (C3H3) radicals at two nominal pressures of 25 and 50 bar over…”
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Computational Study on the Thermochemistry of Cyclopentadiene Derivatives and Kinetics of Cyclopentadienone Thermal Decomposition
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (26-02-1998)“…The enthalpies of formation were determined for 15 intermediate species of cyclopentadiene oxidation under combustion conditions by ab initio molecular orbital…”
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Experimental and comparative modeling study of high temperature and very high pressure methylcyclohexane pyrolysis
Published in Fuel (Guildford) (01-02-2019)“…Three sets totaling 118 individual methylcyclohexane shock tube pyrolysis experiments were completed at nominal pressures of 40, 100, and 200 bar to obtain…”
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Shock tube study of natural gas oxidation at propulsion relevant conditions
Published in Proceedings of the Combustion Institute (2023)“…Global climate change and rising crude oil prices have motivated search of clean, sustainable and economic fuel. Methane, having the highest hydrogen to carbon…”
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Theoretical Study of the Formation of Naphthalene from the Radical/π-Bond Addition between Single-Ring Aromatic Hydrocarbons
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (09-06-2011)“…The experimental investigations performed in the 1960s on the o-benzyne + benzene reaction as well as the more recent studies on reactions involving…”
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High pressure study of n-propylbenzene oxidation
Published in Combustion and flame (01-03-2012)“…The high pressure and temperature kinetics of n-propylbenzene oxidation were investigated in the High Pressure Single Pulse Shock Tube at University of…”
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Optimized synthetic data and semi-supervised learning for Derived Cetane Number prediction
Published in Combustion and flame (01-01-2024)Get full text
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High pressure study of 1,3,5-trimethylbenzene oxidation
Published in Combustion and flame (01-11-2012)“…The high pressure and high temperature kinetics of the 1,3,5-trimethylbenzene oxidation were investigated in the High Pressure Single Pulse Shock Tube at…”
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A physics-based approach to modeling real-fuel combustion chemistry - I. Evidence from experiments, and thermodynamic, chemical kinetic and statistical considerations
Published in Combustion and flame (01-07-2018)“…Real distillate fuels usually contain thousands of hydrocarbon components. Over a wide range of combustion conditions, large hydrocarbon molecules undergo…”
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Experimental and modeling study on the oxidation of Jet A and the n-dodecane/iso-octane/n-propylbenzene/1,3,5-trimethylbenzene surrogate fuel
Published in Combustion and flame (01-01-2013)“…Jet A POSF 4658 and n-dodecane/iso-octane/n-propylbenzene/1,3,5-trimethylbenzene (2nd generation surrogate) oxidation experiments were conducted in a shock…”
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Experimental and modeling study on the pyrolysis and oxidation of iso-octane
Published in Proceedings of the Combustion Institute (2013)“…High pressure iso-octane shock tube experiments were conducted to assist in the development of a Jet A surrogate kinetic model. Jet A is a kerosene based jet…”
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Evaluation of Chemical Functional Group Composition of Jet Fuels Using Two-Dimensional Gas Chromatography
Published in Energy & fuels (02-02-2023)“…The growing interest in fuel property prediction models for simplification of fuel characterization has led to techniques for evaluating the chemical…”
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A high pressure shock tube study of pyrolysis of real jet fuel Jet A
Published in Proceedings of the Combustion Institute (2019)“…A typical Jet A fuel was pyrolyzed in a high-pressure shock tube at 25 and 90 atm under highly diluted conditions from 900 to 2200 K. The key species produced…”
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A Raman spectroscopy based chemometric approach to predict the derived cetane number of hydrocarbon jet fuels and their mixtures
Published in Talanta (Oxford) (01-05-2024)“…Fuel ignition quality, measured in the form of Derived Cetane Number (DCN), is an important part of integrating fuels, including sustainable aviation fuels, in…”
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Experimental and modeling study of the pyrolysis and oxidation of an iso-paraffinic alcohol-to-jet fuel
Published in Combustion and flame (01-03-2019)“…Single pulse shock tube experiments were conducted to determine the pyrolytic and oxidative decomposition products of an alcohol-to-jet fuel (ATJ) composed…”
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