Search Results - "Breton, Tony"

Intrinsic Biodegradability of Plastics and Ecological Risk in the Case of Leakage by Degli Innocenti, Francesco, Breton, Tony

“…Biodegradable materials are used to make compostable products that are expected to be collected and recovered in specialist waste treatment plants. The…”
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Electrografting via Diazonium Chemistry: From Multilayer to Monolayer Using Radical Scavenger by Menanteau, Thibaud, Levillain, Eric, Breton, Tony

“…A simple strategy to avoid the formation of polyaryl layer during the functionalization of carbon surface by diazonium electroreduction is presented. The…”
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Electrografting via Diazonium Chemistry: The Key Role of the Aryl Substituent in the Layer Growth Mechanism by Menanteau, Thibaud, Dias, Marylène, Levillain, Eric, Downard, Alison J, Breton, Tony

“…A series of diazonium salts bearing different para substituents was used to functionalize glassy carbon (GC) and pyrolyzed photoresist film (PPF) under…”
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Enhanced electrocatalytic activity on TEMPO mixed film grafted by diazonium reduction by Cesbron, Marius, Dabos-Seignon, Sylvie, Gautier, Christelle, Breton, Tony

“…Stable mixed organic films were formed on glassy carbon electrode surface via a two-step functionalization, using the electroreduction of a diazonium cation…”
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Enhancing the performance of a diazonium-modified carbon supercapacitor by controlling the grafting process by Menanteau, Thibaud, Benoît, Corentin, Breton, Tony, Cougnon, Charles

“…The activated Norit carbon was modified by grafting the 4-nitrobenzenediazonium salt in the presence or in the absence of a radical scavenger (DPPH:…”
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Diazonium Grafting Control through a Redox Cross‐Reaction: Elucidation of the Mechanism Involved when using 2,2‐Diphenylpicrylhydrazyl as an Inhibitor by López, Isidoro, Cesbron, Marius, Levillain, Eric, Breton, Tony

“…Investigation into the mechanism involved in the control of layer growth through the reduction of diazonium salts by using 2,2‐diphenylpicrylhydrazyl (DPPH)…”
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TEMPO Mixed SAMs: Electrocatalytic Efficiency versus Surface Coverage by Blanchard, Pierre-Yves, Alévêque, Olivier, Breton, Tony, Levillain, Eric

“…Electrocatalytic behavior of TEMPO derivative SAMs on gold has been studied in the presence of benzyl alcohol. The results demonstrate that interfacial…”
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Very Strong Binding for a Neutral Calix[4]pyrrole Receptor Displaying Positive Allosteric Binding by Duedal, Troels, Nielsen, Kent A, Olsen, Gunnar, Rasmussen, Charlotte B. G, Kongsted, Jacob, Levillain, Eric, Breton, Tony, Miyazaki, Eigo, Takimiya, Kazuo, Bähring, Steffen, Jeppesen, Jan O

“…The dual-analyte responsive behavior of tetraTTF-calix[4]­pyrrole receptor 1 has been shown to complex electron-deficient planar guests in a 2:1 fashion by…”
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Impact of the Diazonium Grafting Control on the Interfacial Reactivity: Monolayer versus Multilayer by Menanteau, Thibaud, Dabos‐Seignon, Sylvie, Levillain, Eric, Breton, Tony

“…A very simple strategy to prepare, in two steps, a versatile and sustainable monolayer platform for on‐surface chemistry is presented. The first step consists…”
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Nitroxyl radical self assembled monolayers: Ion pairing investigation in organic and aqueous media by Gautier, Christelle, Alévêque, Olivier, Seladji, Fawzia, Dias, Marylène, Breton, Tony, Levillain, Eric

“…Self assembled monolayers (SAMs) formed from TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl) derivative thiols have been studied by electrochemical quartz crystal…”
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Kinetic and selectivity control of TEMPO electro-mediated oxidation of alcohols by Liaigre, Denis, Breton, Tony, Belgsir, El Mustapha

“…TEMPO electro-mediated oxidation of alcohols has been investigated in aqueous and hydro-organic media. Mono- and poly-saccharides, aryl alcohols and…”
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Metrics for quantifying the circularity of bioplastics: The case of bio-based and biodegradable mulch films by Razza, Francesco, Briani, Cristiana, Breton, Tony, Marazza, Diego

“…•A modification of the macarthur methodology on product circularity (i.e. Material circularity indicator MCI) has been developed to make it applicable to…”
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Aromatization of cyclohexadienes by TEMPO electro-mediated oxidation: Kinetic and structural aspects by Breton, Tony, Liaigre, Denis, Belgsir, El Mustapha

“…Cyclohexadienes are easily converted into the corresponding aromatics in excellent yield (>90%) in the presence of 2,2,6,6-tetramethyl-1-oxopiperidinium ion…”
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Selective TEMPO-Catalyzed Chemicals vs. Electrochemical Oxidation of Carbohydrate Derivatives by Barbier, Maximilien, Breton, Tony, Servat, Karine, Grand, Eric, Kokoh, Boniface, Kovensky, José

“…TEMPO-catalyzed electrochemical oxidation of carbohydrate derivatives was performed and compared with chemical oxidation, which requires the use of…”
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Spontaneous Grafting of Nitrophenyl Groups on Carbon: Effect of Radical Scavenger on Organic Layer Formation by Menanteau, Thibaud, Levillain, Eric, Breton, Tony

“…The effect of a radical scavenger (DPPH: 2,2-diphenyl-1-picrylhydrazyl) on the spontaneous covalent grafting of nitrophenyl functionalities on a vitreous…”
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Harnessing Aryldiazonium Salts Reduction for Tailored Bifunctionalized Surface Engineering by Billon, Julien, Bou Rahhal, Elie, Breton, Tony, Gautier, Christelle

“…The functionalization of various substrates through the reduction of diazonium salts is a widely used and expanding method, leading to the formation of highly…”
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A post-functionalization toolbox for diazonium (electro)-grafted surfaces: review of the coupling methods by Gautier, Christelle, López, Isidoro, Breton, Tony

“…The surface modification by organics has been booming over the past twenty years in the context of the development of 2D nanomaterials for a wide range of…”
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Aryldiazonium reduction mechanism deciphered by scanning electrochemical microscopy through an EC’ process by Kostopoulos, Nikolaos, Shkirskiy, Viacheslav, Combellas, Catherine, Kanoufi, Frédéric, Breton, Tony, Noël, Jean-Marc

“…Homogeneous redox catalysis, often associated to EC’ mechanisms, is an elegant way to investigate electron transfer processes. Among the electrochemical tools…”
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Use of Selective Redox Cross-Inhibitors for the Control of Organic Layer Formation Obtained via Diazonium Salt Reduction by López, Isidoro, Dabos-Seignon, Sylvie, Breton, Tony

“…The controlled electrochemical deposition of a series of four diazonium salts (4-bromobenzene, 4-iodobenzene, 4-methoxybenzene, and 4-diethylaminobenzene…”
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Click Chemistry: A Versatile Method for Tuning the Composition of Mixed Organic Layers Obtained by Reduction of Diazonium Cations by Cesbron, Marius, Levillain, Eric, Breton, Tony, Gautier, Christelle

“…Postfunctionalization of glassy carbon electrodes previously modified by reduction of 4-azidobenzenediazonium was exploited to conveniently synthesize…”
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