Search Results - "Brenner, Peter B"
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Iron-Catalyzed Borylation of Alkyl, Allyl, and Aryl Halides: Isolation of an Iron(I) Boryl Complex
Published in Organometallics (10-11-2014)“…Activation of B2pin2 with tBuLi facilitates the Fe-catalyzed borylation of alkyl, allyl, benzyl, and aryl halides via the formation of Li[B2pin2(tBu)] (1). The…”
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TMEDA in Iron-Catalyzed Kumada Coupling: Amine Adduct versus Homoleptic "ate" Complex Formation
Published in Angewandte Chemie International Edition (10-02-2014)“…The reactions of iron chlorides with mesityl Grignard reagents and tetramethylethylenediamine (TMEDA) under catalytically relevant conditions tend to yield the…”
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3
Investigation of Steric Factors Involved in the Formation of Terminal Cationic Platinum Arylborylene Complexes
Published in Organometallics (08-06-2015)“…The abstraction of halido ligands from PtII diphosphine boryl complexes has previously been shown to yield one of two isomeric products: either T-shaped…”
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Expedient Iron-Catalyzed Coupling of Alkyl, Benzyl and Allyl Halides with Arylboronic Esters
Published in Chemistry : a European journal (23-06-2014)“…While attractive, the iron‐catalyzed coupling of arylboron reagents with alkyl halides typically requires expensive or synthetically challenging diphosphine…”
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5
Iron Phosphine Catalyzed Cross-Coupling of Tetraorganoborates and Related Group 13 Nucleophiles with Alkyl Halides
Published in Organometallics (27-10-2014)“…Iron phosphine complexes prove to be good precatalysts for the cross-coupling of alkyl, benzyl, and allyl halides with not only aryl triorganoborate salts but…”
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6
Palladium-Catalyzed Ortho-Arylation of Carbamate-Protected Estrogens
Published in Journal of organic chemistry (06-05-2016)“…The palladium-catalyzed ortho-arylation of diethyl carbamate-protected estrone and estriol with aryl iodides gives the 2-arylated analogues. Subsequent removal…”
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Correlations and Contrasts in Homo- and Heteroleptic Cyclic (Alkyl)(amino)carbene-Containing Pt(0) Complexes
Published in Chemistry : a European journal (24-08-2015)“…An improved synthetic route to homoleptic complex [Pt(CAAC(Me))2] (CAAC = cyclic (alkyl)(amino)carbenes) and convenient routes to new heteroleptic complexes of…”
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8
Correlations and Contrasts in Homo‐ and Heteroleptic Cyclic (Alkyl)(amino)carbene‐Containing Pt0 Complexes
Published in Chemistry : a European journal (24-08-2015)“…An improved synthetic route to homoleptic complex [Pt(CAACMe)2] (CAAC=cyclic (alkyl)(amino)carbenes) and convenient routes to new heteroleptic complexes of the…”
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9
A Base-stabilized Iodoborylene Complex of Platinum(II)
Published in Zeitschrift für Naturforschung. B, A journal of chemical sciences (01-06-2013)“…The first base-stabilized iodoborylene platinum complex was prepared through the addition of 4-picoline (4-Pic) to a suspension of an iodo-bridged binuclear…”
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10
TMEDA in der Eisen-katalysierten Kumada-Kupplung: homoleptische at-Komplexe statt Diaminaddukte
Published in Angewandte Chemie (10-02-2014)“…Eisenchloride bilden mit Mesityl‐Grignard‐Reagentien und Tetramethylethylendiamin (TMEDA) unter katalyserelevanten Bedingungen nicht den entsprechenden…”
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11
Correlations and Contrasts in Homo‐ and Heteroleptic Cyclic (Alkyl)(amino)carbene‐Containing Pt 0 Complexes
Published in Chemistry : a European journal (24-08-2015)“…An improved synthetic route to homoleptic complex [Pt(CAAC Me ) 2 ] (CAAC=cyclic (alkyl)(amino)carbenes) and convenient routes to new heteroleptic complexes of…”
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12
Correlations and Contrasts in Homo- and Heteroleptic Cyclic (Alkyl)(amino)carbene-Containing Pt super(0) Complexes
Published in Chemistry : a European journal (01-08-2015)“…An improved synthetic route to homoleptic complex [Pt(CAAC super(Me)) sub(2)] (CAAC=cyclic (alkyl)(amino)carbenes) and convenient routes to new heteroleptic…”
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13
TMEDA in der Eisen‐katalysierten Kumada‐Kupplung: homoleptische at‐Komplexe statt Diaminaddukte
Published in Angewandte Chemie (10-02-2014)“…Eisenchloride bilden mit Mesityl‐Grignard‐Reagentien und Tetramethylethylendiamin (TMEDA) unter katalyserelevanten Bedingungen nicht den entsprechenden…”
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