Search Results - "Brendler, Erica"
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75As Nuclear Magnetic Resonance Spectroscopic Investigation of the Thioarsenate Speciation in Strongly Alkaline Sulfidic Leaching Solutions
Published in Molecules (Basel, Switzerland) (14-06-2024)“…Copper ores and concentrates thereof feature an increasingly notable content of impurities such as arsenic and other hazardous elements. As an alternative to…”
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P-Ru-Complexes with a Chelate-Bridge-Switch: A Comparison of 2-Picolyl and 2-Pyridyloxy Moieties as Bridging Ligands
Published in Molecules (Basel, Switzerland) (27-04-2022)“…Starting from [Ru(pyO) (nbd)] and a N,P,N-tridentate ligand ( : PhP(pic) , : PhP(pyO) ) (nbd = 2,5-norbornadiene, pic = 2-picolyl = 2-pyridylmethyl, pyO =…”
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Isolation and Structure Analysis of Chitin Obtained from Different Developmental Stages of the Mulberry Silkworm ( Bombyx mori )
Published in Molecules (Basel, Switzerland) (01-05-2024)“…Chitin, a ubiquitous biopolymer, holds paramount scientific and economic significance. Historically, it has been primarily isolated from marine crustaceans…”
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Molecular Structures of the Pyridine-2-olates PhE(pyO)3 (E = Si, Ge, Sn)—[4+3]-Coordination at Si, Ge vs. Heptacoordination at Sn
Published in Crystals (Basel) (01-12-2022)“…The phenyltetrel pyridine-2-olates PhE(pyO)3 (E = Si, Ge, Sn; pyO = pyridine-2-olate) were synthesized from the respective chlorides PhECl3 and…”
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Two Modifications of Nitrilotris(methylenephenylphosphinic) Acid: A Polymeric Network with Intermolecular (O=P–O–H)3 vs. Monomeric Molecules with Intramolecular (O=P–O–H)3 Hydrogen Bond Cyclotrimers
Published in Crystals (Basel) (01-07-2024)“…Nitrilotris(methylenephenylphosphinic) acid (NTPAH3) was silylated using hexamethyldisilazane to produce the tris(trimethylsilyl) derivative NTPA(SiMe3)3. From…”
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Spider Chitin: An Ultrafast Microwave-Assisted Method for Chitin Isolation from Caribena versicolor Spider Molt Cuticle
Published in Molecules (Basel, Switzerland) (16-10-2019)“…Chitin, as a fundamental polysaccharide in invertebrate skeletons, continues to be actively investigated, especially with respect to new sources and the…”
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Copper Complexes of Silicon Pyridine-2-olates RSi(pyO)3 (R = Me, Ph, Bn, Allyl) and Ph2Si(pyO)2
Published in Inorganics (01-01-2023)“…The organosilicon pyridine-2-olates 1a–1d (RSi(pyO)3, R = Me (a), Ph (b), Bn (c), Allyl (d); pyO = pyridine-2-olate) may serve as tripodal ligands toward CuCl…”
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Synthesis of Silylium and Germylium Ions by a Substituent Exchange Reaction
Published in Organometallics (09-09-2013)“…The reaction of diarylalkylsilanes and -germanes with trityl cation in the presence of a weakly coordinating anion to give the corresponding triarylsilylium or…”
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A Non-Hydrolytic Sol-Gel Route to Organic-Inorganic Hybrid Polymers: Linearly Expanded Silica and Silsesquioxanes
Published in Gels (02-04-2023)“…Condensation reactions of chlorosilanes (SiCl and CH SiCl ) and bis(trimethylsilyl)ethers of rigid, quasi-linear diols (CH ) SiO- -OSi(CH ) ( =…”
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Molecular Structures of the Silicon Pyridine-2-(thi)olates Me3Si(pyX), Me2Si(pyX)2 and Ph2Si(pyX)2 (py = 2-Pyridyl, X = O, S), and Their Intra- and Intermolecular Ligand Exchange in Solution
Published in Crystals (Basel) (01-08-2022)“…A series of pyridine-2-olates (pyO) and pyridine-2-thiolates (pyS) of silicon was studied in solid state and in solution. The crystal structures of Me3Si(pyO)…”
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Chemometric Combination of Ultrahigh Resolving Mass Spectrometry and Nuclear Magnetic Resonance Spectroscopy for a Structural Characterization of Lignin Compounds
Published in ACS omega (09-01-2024)“…In recent years, the potential of lignins as a resource for material-based applications has been highlighted in many scientific and nonscientific publications…”
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New Method for Determining the Degree of Cellulose I Crystallinity by Means of FT Raman Spectroscopy
Published in Cellulose (London) (01-06-2005)“…A Raman crystallinity index – XcRaman – characterizing the degree of crystallinity of partially crystalline cellulose I samples was created, utilizing the…”
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(2-Pyridyloxy)silanes as Ligands in Transition Metal Coordination Chemistry
Published in Inorganics (01-12-2018)“…Proceeding our initial studies of compounds with formally dative TM→Si bonds (TM = Ni, Pd, Pt), which feature a paddlewheel arrangement of four (N,S) or (N,N)…”
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Disilanes with Pentacoordinate Si Atoms by Carbon Dioxide Insertion into Aminodisilanes: Syntheses, Molecular Structures, and Dynamic Behavior
Published in ACS omega (22-03-2022)“…The insertion of carbon dioxide into the Si–N bonds of aminodisilanes ((RR′N) n Me3–n Si)2 affords carbamoyloxydisilanes ((RR′NC(O)O) n Me3–n Si)2. Some of…”
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The Hexacoordinate Si Complex SiCl4(4-Azidopyridine)2—Crystallographic Characterization of Two Conformers and Probing the Influence of SiCl4-Complexation on a Click Reaction with Phenylacetylene
Published in Inorganics (01-12-2023)“…4-Azidopyridine (1) and SiCl4 react with the formation of the hexacoordinate silicon complex SiCl4(4-azidopyridine)2 (2). Upon dissolving in warm chloroform,…”
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2-Acylpyrroles as Mono-anionic O,N-Chelating Ligands in Silicon Coordination Chemistry
Published in Chemistry : a European journal (21-07-2014)“…Kryptopyrrole (2,4‐dimethyl‐3‐ethylpyrrole) was acylated with, for example, benzoyl chloride to afford 2‐benzoyl‐3,5‐dimethyl‐4‐ethylpyrrole (L1H). With SiCl4…”
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Metallasilatranes: Palladium(II) and Platinum(II) as Lone-Pair Donors to Silicon(IV)
Published in Angewandte Chemie (International ed.) (01-01-2010)Get full text
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Solid-state properties and colloidal stability of thorium(IV)–silica nanoparticles
Published in Geochimica et cosmochimica acta (15-02-2013)“…Thorium(IV) is able to form meta-stable colloids with silica in aqueous solution at pH⩾7 which results in concentrations of colloid-borne Th(IV) of 10−3M. The…”
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Chlorosilanes and 3,5-Dimethylpyrazole: Multinuclear Complexes, Acetonitrile Insertion and 29Si NMR Chemical-Shift Anisotropy Studies
Published in European journal of inorganic chemistry (01-06-2013)“…The multinuclear silicon complexes [{H2ClSi(μ‐pz*)2}2SiH2] (1) and [Cl2Si(μ‐pzRR)2SiCl2] (2, R = Me; 3, R = Ph) were formed by the reaction of dichlorosilane…”
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Molecular structures of pyridinethiolato complexes of Sn(II), Sn(IV), Ge(IV), and Si(IV)
Published in Main group metal chemistry (01-12-2013)“…Complexes of Sn(II), Sn(IV), Ge(IV), and Si(IV) with the ambidentate pyridine-2-thiolato ligand (PyS-) were synthesized and characterized by multinuclear NMR…”
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