Search Results - "Bren, Kara"
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Hydrogen Evolution from Neutral Water under Aerobic Conditions Catalyzed by Cobalt Microperoxidase-11
Published in Journal of the American Chemical Society (08-01-2014)“…A molecular electrocatalyst is reported that reduces protons to hydrogen (H2) in neutral water under aerobic conditions. The biomolecular catalyst is made from…”
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Beyond fossil fuel-driven nitrogen transformations
Published in Science (American Association for the Advancement of Science) (25-05-2018)“…Nitrogen is fundamental to all of life and many industrial processes. The interchange of nitrogen oxidation states in the industrial production of ammonia,…”
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Cobalt Metallopeptide Electrocatalyst for the Selective Reduction of Nitrite to Ammonium
Published in Journal of the American Chemical Society (12-12-2018)“…A cobalt-tripeptide complex (CoGGH) is developed as an electrocatalyst for the selective six-electron, eight-proton reduction of nitrite to ammonium in aqueous…”
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Biological Significance and Applications of Heme c Proteins and Peptides
Published in Accounts of chemical research (21-07-2015)“…Hemes are ubiquitous in biology and carry out a wide range of functions. The heme group is largely invariant across proteins with different functions, although…”
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Hydrogen Evolution from Water under Aerobic Conditions Catalyzed by a Cobalt ATCUN Metallopeptide
Published in Inorganic chemistry (15-02-2016)“…The cobalt complex of an amino-terminal copper and nickel (ATCUN) motif model tripeptide (CoGGH) is shown to act as an electrocatalyst for hydrogen evolution…”
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Engineered Biomolecular Catalysts
Published in Journal of the American Chemical Society (18-10-2017)Get full text
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Photochemical Hydrogen Evolution from Neutral Water with a Cobalt Metallopeptide Catalyst
Published in Inorganic chemistry (16-12-2019)“…CoGGH, a Gly-Gly-His tripeptide coordinated to a cobalt ion, is shown to catalyze the reduction of aqueous protons to hydrogen (H2) in a light-driven reaction…”
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Bioinspired and biomolecular catalysts for energy conversion and storage
Published in FEBS letters (01-01-2023)“…Metalloenzymes are remarkable for facilitating challenging redox transformations with high efficiency and selectivity. In the area of alternative energy,…”
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Hydrogen evolution from water catalyzed by cobalt-mimochrome VIa, a synthetic mini-protein
Published in Chemical science (Cambridge) (07-12-2018)“…A synthetic enzyme is reported that electrocatalytically reduces protons to hydrogen (H ) in water near neutral pH under aerobic conditions. Cobalt mimochrome…”
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Electrocatalytic Multielectron Nitrite Reduction in Water by an Iron Complex
Published in ACS catalysis (04-12-2020)“…Catalytic reduction of nitrite by an iron complex in water near neutral pH to form hydroxylamine and ammonium is reported. The catalyst is an iron center…”
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Discovery of the magnetic behavior of hemoglobin: A beginning of bioinorganic chemistry
Published in Proceedings of the National Academy of Sciences - PNAS (27-10-2015)“…Two articles published by Pauling and Coryell in PNAS nearly 80 years ago described in detail the magnetic properties of oxy- and deoxyhemoglobin, as well as…”
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Tuning Mechanism through Buffer Dependence of Hydrogen Evolution Catalyzed by a Cobalt Mini-enzyme
Published in Biochemistry (Easton) (31-03-2020)“…Cobalt-mimochrome VI*a (CoMC6*a) is a synthetic mini-protein that catalyzes aqueous proton reduction to hydrogen (H2). In buffered water, there are multiple…”
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Light‐driven catalysis with engineered enzymes and biomimetic systems
Published in Biotechnology and applied biochemistry (01-07-2020)“…Efforts to drive catalytic reactions with light, inspired by natural processes like photosynthesis, have a long history and have seen significant recent…”
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Semisynthetic and Biomolecular Hydrogen Evolution Catalysts
Published in Inorganic chemistry (19-01-2016)“…There has been great interest in the development of stable, inexpensive, efficient catalysts capable of reducing aqueous protons to hydrogen (H2), an…”
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A cobalt mimochrome for photochemical hydrogen evolution from neutral water
Published in Journal of inorganic biochemistry (01-05-2022)“…A system for visible light-driven hydrogen production from water is reported. This system makes use of a synthetic mini-enzyme known as a mimochrome (CoMC6*a)…”
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Photochemical hydrogen evolution from cobalt microperoxidase-11
Published in Journal of inorganic biochemistry (01-04-2021)“…A photochemical system utilizing the semisynthetic biomolecular catalyst acetylated cobalt microperoxidase-11 (CoMP11-Ac) along with [Ru(bpy)3]2+ as a…”
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Investigations of heme distortion, low-frequency vibrational excitations, and electron transfer in cytochrome c
Published in Proceedings of the National Academy of Sciences - PNAS (06-05-2014)“…Cytochrome (cyt) c is an important electron transfer protein. The ruffling deformation of its heme cofactor has been suggested to relate to its electron…”
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Engineered Enzymes and Bioinspired Catalysts for Energy Conversion
Published in ACS energy letters (13-09-2019)“…Metalloenzymes play critical roles in the environment by catalyzing redox reactions in biogeochemical cycles. The elucidation of structure–function…”
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Hydrogen evolution catalysis by a cobalt porphyrin peptide: A proposed role for porphyrin propionic acid groups
Published in Journal of inorganic biochemistry (01-12-2023)“…Cobalt microperoxidase-11 (CoMP11-Ac) is a cobalt porphyrin-peptide catalyst for hydrogen (H2) evolution from water. Herein, we assess electrocatalytic…”
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Going with the Electron Flow: Heme Electronic Structure and Electron Transfer in Cytochrome c
Published in Israel journal of chemistry (01-10-2016)“…Heme is an essential and functionally versatile cofactor. Our understanding of how the environment of a heme in a protein tunes its function has benefited from…”
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