Search Results - "Breitwieser, Kevin"
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Crystal structure of a 1,1-dibutyl-1H,3H-naphtho[1,8-cd][1,2,6]oxastannaborinin-3-ol
Published in Acta crystallographica. Section E, Crystallographic communications (01-02-2021)“…A novel oxastannaborininol, 1,1-dibutyl-1 H ,3 H -naphtho[1,8- cd ][1,2,6]oxastannaborinin-3-ol, has been synthesized and crystallized. It is the first…”
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Pd8(PDip)6: Cubic, Unsaturated, Zerovalent
Published in Advanced science (01-07-2024)“…Atomically precise nanoclusters hold promise for supramolecular assembly and (opto)electronic‐ as well as magnetic materials. Herein, this work reports that…”
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Development of the “Diverted Heck” Reaction for the Synthesis of Five-Membered Rings
Published in Organometallics (22-03-2021)“…The “diverted Heck” reaction has been shown to be a potent method to synthesize cyclopropanes from electron-rich olefins and iodomethyl trifluoroborate…”
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Gauging Radical Stabilization with Carbenes
Published in Angewandte Chemie International Edition (12-09-2022)“…Carbenes, including N‐heterocyclic carbene (NHC) ligands, are used extensively to stabilize open‐shell transition metal complexes and organic radicals. Yet, it…”
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5
On the Effect of Iodide and Acids in the Metolachlor Process
Published in Organometallics (26-12-2022)“…Iridium-catalyzed asymmetric imine hydrogenation is the key step in the industrial syntheses of dextromethorphan and metolachlor. Nevertheless, the mechanism…”
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Crystal structure of a 1,1-dibutyl-1 H ,3 H -naphtho[1,8- cd ][1,2,6]oxastannaborinin-3-ol
Published in Acta crystallographica. Section E, Crystallographic communications (01-02-2021)“…The title oxastannaborininol compound, [Sn(C H ) (C H BO )], has been synthesized and crystallized. While heterocycles containing a C-O-B group are common,…”
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7
Crystal structure of a 1,1-dibutyl-1H,3H-naphtho1,8-cd1,2,6oxastannaborinin-3-ol
Published in Acta crystallographica. Section E, Crystallographic communications (01-02-2021)“…The title oxastannaborininol compound, [Sn(C4H9)2(C10H7BO2)], has been synthesized and crystallized. While heterocycles containing a C-O-B group are common,…”
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8
The synthesis and characterization of an iron(VII) nitrido complex
Published in Nature chemistry (01-04-2024)“…Complexes of iron in high oxidation states are captivating research subjects due to their pivotal role as active intermediates in numerous catalytic processes…”
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Palladium Terminal Imido Complexes with Nitrene Character
Published in Journal of the American Chemical Society (25-05-2022)“…Whereas triplet-nitrene complexes of the late transition metals are isolable and key intermediates in catalysis, singlet-nitrene ligands remain elusive. Herein…”
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10
Gauging Radical Stabilization with Carbenes
Published in Angewandte Chemie (12-09-2022)“…Carbenes, including N‐heterocyclic carbene (NHC) ligands, are used extensively to stabilize open‐shell transition metal complexes and organic radicals. Yet, it…”
Get full text
Journal Article -
11
Pd 8 (PDip) 6 : Cubic, Unsaturated, Zerovalent
Published in Advanced science (01-07-2024)“…Atomically precise nanoclusters hold promise for supramolecular assembly and (opto)electronic- as well as magnetic materials. Herein, this work reports that…”
Get full text
Journal Article