Search Results - "Bray, Travis H"
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Gas-Phase Uranyl, Neptunyl, and Plutonyl: Hydration and Oxidation Studied by Experiment and Theory
Published in Inorganic chemistry (18-06-2012)“…The following monopositive actinyl ions were produced by electrospray ionization of aqueous solutions of AnVIO2(ClO4)2 (An = U, Np, Pu): UVO2 +, NpVO2 +, PuVO2…”
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Understanding Fluxes as Media for Directed Synthesis: In Situ Local Structure of Molten Potassium Polysulfides
Published in Journal of the American Chemical Society (06-06-2012)“…Rational exploratory synthesis of new materials requires routes to discover novel phases and systematic methods to tailor their structures and properties…”
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Electron transfer dissociation of dipositive uranyl and plutonyl coordination complexes
Published in Journal of mass spectrometry. (01-12-2011)“…Reported here is a comparison of electron transfer dissociation (ETD) and collision‐induced dissociation (CID) of solvent‐coordinated dipositive uranyl and…”
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Experience Gained from the Development and Execution of a Multidisciplinary Multi-syndrome Hereditary Colon Cancer Family Conference
Published in Journal of cancer education (01-12-2019)“…Genetic healthcare professionals provide genetic cancer risk assessment and follow-up care for patients facing hereditary cancers. To meet the needs of those…”
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Periodic Trends in Actinide Phosphonates: Divergence and Convergence between Thorium, Uranium, Neptunium, and Plutonium Systems
Published in Inorganic chemistry (18-05-2009)“…The hydrothermal reactions of both PuO2 2+ and PuO2 with phosphonates results in the formation of Pu(IV) phosphonates. Pu(CH3PO3)2, Pu[CH2(PO3)2](H2O), and…”
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Novel Dinuclear Uranyl Complexes with Asymmetric Schiff Base Ligands: Synthesis, Structural Characterization, Reactivity, and Extraction Studies
Published in Inorganic chemistry (01-10-2007)“…The reaction of uranyl nitrate with asymmetric [3O, N] Schiff base ligands in the presence of base yields dinuclear uranyl complexes, [UO2(HL1)]2·DMF (1),…”
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Further Examples of the Failure of Surrogates to Properly Model the Structural and Hydrothermal Chemistry of Transuranium Elements: Insights Provided by Uranium and Neptunium Diphosphonates
Published in Inorganic chemistry (02-06-2008)“…In situ hydrothermal reduction of Np(VI) to Np(IV) in the presence of methylenediphosphonic acid (C1P2) results in the crystallization of Np[CH2(PO3)2](H2O)2…”
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In Situ Hydrothermal Reduction of Neptunium(VI) as a Route to Neptunium(IV) Phosphonates
Published in Inorganic chemistry (24-12-2007)“…A lamellar neptunium(IV) methylphosphonate, Np(CH3PO3)(CH3PO3H)(NO3)(H2O)·H2O, has been prepared under hydrothermal conditions via the in situ reduction of…”
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Why Does Kevlar Decompose, while Nomex Does Not, When Treated with Aqueous Chlorine Solutions?
Published in The journal of physical chemistry. B (24-05-2007)“…Kevlar and Nomex are high-performance polymers which have wide varieties of applications in daily life. Recently, they have been proposed to be biocidal…”
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Redox Chemistry of Heteropolyacid Microemulsions
Published in ChemElectroChem (15-07-2014)“…Insight from electroanalysis studies of dense fluid phases (known as “third” phases) in the Keggin heteropolyacid tri‐n‐butyl phosphate (TBP) system is…”
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Synthesis and structure of [C6H14N2][(UO2)4(HPO4)2(PO4)2(H2O)] H2O : An expanded open-framework amine-bearing uranyl phosphate
Published in Journal of solid state chemistry (01-09-2008)Get full text
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Structural Polarity Induced by Cooperative Hydrogen Bonding and Lone-Pair Alignment in the Molecular Uranyl Iodate Na2[UO2(IO3)4(H2O)]
Published in Inorganic chemistry (02-10-2006)“…Na2[UO2(IO3)4(H2O)] has been synthesized under mild hydrothermal conditions. Its structure consists of Na+ cations and [UO2(IO3)4(H2O)]2- anions. The…”
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Critical Role of Water Content in the Formation and Reactivity of Uranium, Neptunium, and Plutonium Iodates under Hydrothermal Conditions: Implications for the Oxidative Dissolution of Spent Nuclear Fuel
Published in Inorganic chemistry (30-04-2007)“…The reactions of 237NpO2 with excess iodate under acidic hydrothermal conditions result in the isolation of the neptunium(IV), neptunium(V), and neptunium(VI)…”
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Syntheses, Structure, Magnetism, and Optical Properties of the Ordered Mixed-Lanthanide Sulfides γ-LnLn‘S3 (Ln = La, Ce; Ln‘ = Er, Tm, Yb)
Published in Chemistry of materials (06-02-2007)“…γ-LnLn‘S3 (Ln = La, Ce; Ln‘ = Er, Tm, Yb) have been prepared as dark red to black single crystals by the reaction of the respective lanthanides with sulfur in…”
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Hydrothermal synthesis, structure, and magnetic properties of Pu(SeO 3) 2
Published in Journal of solid state chemistry (01-03-2008)“…The reaction between PuO 2 and SeO 2 under mild hydrothermal conditions results in the formation of Pu(SeO 3) 2 as brick-red prisms. This compound adopts the…”
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Capitalizing on Differing Coordination Environments and Redox Potentials to Prepare an Ordered Heterobimetallic UVI/NpIV Diphosphonate
Published in Angewandte Chemie (International ed.) (04-08-2008)“…Order out of chaos: The reduction of NpVI to NpIV readily occurs under mild hydrothermal conditions in the presence of phosphonates, sharply contrasting with…”
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Product evolution in the Np(IV) fluorophosphate system
Published in Journal of solid state chemistry (01-01-2007)“…The reaction of 237NpO 2 with Cs 2CO 3, Ga 2O 3, H 3PO 4, and HF under mild hydrothermal conditions leads to the formation of NpFPO 4 after 4 days at 180 °C…”
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