Search Results - "Bray, Christopher D"

ortho-Quinone Methides in Natural Product Synthesis by Willis, Nicky J., Bray, Christopher D.

“…ortho‐Quinone methides (o‐QMs) are emerging as highly useful intermediates, the inherent reactivity of which can be used in linchpin reactions for the…”
Get full text

A new family of sesterterpenoids isolated around the Pacific Rim by Shirley, Harry J, Jamieson, Megan L, Brimble, Margaret A, Bray, Christopher D

“…Covering: 2009 up to the end of 2017 There has been a recent eruption in the number of known marine sesterterpenoids which have been isolated from Pacific Rim…”
Get more information

Single-molecule in vivo imaging of bacterial respiratory complexes indicates delocalized oxidative phosphorylation by Llorente-Garcia, Isabel, Lenn, Tchern, Erhardt, Heiko, Harriman, Oliver L., Liu, Lu-Ning, Robson, Alex, Chiu, Sheng-Wen, Matthews, Sarah, Willis, Nicky J., Bray, Christopher D., Lee, Sang-Hyuk, Shin, Jae Yen, Bustamante, Carlos, Liphardt, Jan, Friedrich, Thorsten, Mullineaux, Conrad W., Leake, Mark C.

“…Chemiosmotic energy coupling through oxidative phosphorylation (OXPHOS) is crucial to life, requiring coordinated enzymes whose membrane organization and…”
Get full text

Total synthesis of (+)-intricarene using a biogenetically patterned pathway from (-)-bipinnatin J, involving a novel transannular [5+2] (1,3-dipolar) cycloaddition by Tang, Bencan, Bray, Christopher D, Pattenden, Gerald

“…An asymmetric synthesis of the furanobutenolide-based macrocyclic diterpene (-)-bipinnatin J (4a) isolated from the gorgonian octocoral Pseudopterogorgonia…”
Get more information

Enamines from Terminal Epoxides and Hindered Lithium Amides by Hodgson, David M, Bray, Christopher D, Kindon, Nicholas D

“…A new reactivity mode of lithium amides with epoxides leads to hindered enamines. The reaction of some of these enamines with unactivated primary and secondary…”
Get full text

Generation and hetero-Diels-Alder reactions of an o-quinone methide under mild, anionic conditions: rapid synthesis of mono-benzannelated spiroketals by Bray, Christopher D

“…Deprotonation of o-hydroxybenzyl acetate with (i)PrMgCl provides a method of generating an o-quinone methide under mild, anionic conditions, such that highly…”
Get more information

A biomimetic approach towards phorone sesterterpenoids by Shirley, Harry J, Bray, Christopher D

“…We report an investigation towards a unified total synthesis of the Korean sponge derived sesterterpenoids, phorones A (1) and B (2), via a biomimetic…”
Get more information

Sultones and Sultines via a Julia-Kocienski Reaction of Epoxides by Smith, Geoffrey M. T., Burton, Paul M., Bray, Christopher D.

“…The development of the homologous Julia–Kocienski reaction has led to the discovery of two new reaction modes of epoxides with sulfones. These pathways allow…”
Get full text

A biomimetic total synthesis of (+)-intricarene by Tang, Bencan, Bray, Christopher D., Pattenden, Gerald

“…An asymmetric synthesis of the furanocembrane (−)-bipinnatin J ( 3a) found in gorgonian corals is described. Treatment of 3a with VO(acac) 2- t BuOOH, followed…”
Get full text

Total synthesis of (+)-Z-deoxypukalide, a furanobutenolide-based cembranoid isolated from the pacific octocoral Leptogorgia spp by Tang, Bencan, Bray, Christopher D., Pattenden, Gerald, Rogers, Joseph

“…A total synthesis of (+)-Z-deoxypukalide 3 using a combination of Stille and Nozaki–Hiyama–Kishi(NHK) coupling reactions as key steps, is described. During…”
Get full text

Stereocontrolled Synthesis of trans-Cyclopropyl Sulfones from Terminal Epoxides by Bray, Christopher D, de Faveri, Giorgio

“…Treatment of a range of (enantiopure) epoxides with the sodium salt of diethyl (phenylsulfonyl)methylphosphonate in DME at 140 °C for 4 h gives a variety of…”
Get full text

Direct conversion of epoxides into aziridines with N-arylphosphoramidates by Minicone, Fabrizio, Rogers, Wendy J., Green, James F.J., Khan, Mommna, Smith, Geoffrey M.T., Bray, Christopher D.

“…Treatment of terminal epoxides with N-arylphosphoramidate anions leads directly to N-aryl aziridines. Existing methods for this transformation employ either…”
Get full text

Corrigendum to “Single-molecule in vivo imaging of bacterial respiratory complexes indicates delocalized oxidative phosphorylation” [Biochim. Biophys. Acta 1837(6) (2014) 811–824 DOI: 10.1016/j.bbabio.2014.01.020] by Llorente-Garcia, Isabel, Lenn, Tchern, Erhardt, Heiko, Harriman, Oliver L., Liu, Lu-Ning, Robson, Alex, Chiu, Sheng-Wen, Matthews, Sarah, Willis, Nicky J., Bray, Christopher D., Lee, Sang-Hyuk, Shin, Jae Yen, Bustamante, Carlos, Liphardt, Jan, Friedrich, Thorsten, Mullineaux, Conrad W., Leake, Mark C.

Get full text

Synthesis and C-Alkylation of Hindered Aldehyde Enamines by Hodgson, David M, Bray, Christopher D, Kindon, Nicholas D, Reynolds, Nigel J, Coote, Steven J, Um, Joann M, Houk, K. N

“…A new reactivity mode of hindered lithium amides with terminal epoxides is described whereby aldehyde enamines are produced via a previously unrecognized…”
Get full text

2-Ene-1,4-diols by Dimerization of Terminal Epoxides using Hindered Lithium Amides by Hodgson, David M, Bray, Christopher D, Kindon, Nicholas D

“…Reaction of hindered lithium amides with readily available (enantiopure) terminal epoxides gives 2-ene-1,4-diols via carbenoid dimerization of the…”
Get full text

Sultones and Sultines via a Julia-Kocienski Reaction of Epoxides by Smith, Geoffrey M. T., Burton, Paul M., Bray, Christopher D.

“…The development of the homologous Julia–Kocienski reaction has led to the discovery of two new reaction modes of epoxides with sulfones. These pathways allow…”
Get full text

A biogenetically patterned synthetic approach to the unusual furan methylenecyclobutanol moiety in providencin by Bray, Christopher D., Pattenden, Gerald

“…Irradiation of a solution of α,β-unsaturated aldehyde 10 in benzene leads to the methylenecyclobutanol 11 by way of a novel intramolecular C–H insertion…”
Get full text

Spiroketal Formation by Cascade Oxidative Dearomatization: An Ap­proach to the Phorbaketal Skeleton by Shirley, Harry J., Bray, Christopher D.

“…Addition of PhI(OAc)2 to phenols that have meta‐linked hydroxy ketones results in cascade oxidative dearomatizing spirocyclization to give tricyclic…”
Get full text

The Perfused, Pulseless Supracondylar Humeral Fracture: Intermediate-Term Follow-up of Vascular Status and Function by Scannell, Brian P., MD, Jackson, J.Benjamin, MD, Bray, Christopher, MD, Brighton, Brian K., MD, Frick, Steven L., MD, Roush, Timothy S., MD

“…Background This study provides intermediate-term follow-up data on the vascular status of a cohort of children with a perfused, pulseless supracondylar humeral…”
Get full text

Orthobiologics in Pediatric Sports Medicine by Bray, Christopher C., MD, Walker, Clark M., MD, Spence, David D., MD

“…Orthobiologics are biological substances that allow injured muscles, tendons, ligaments, and bone to heal more quickly. They are found naturally in the body;…”
Get full text