Search Results - "Brödner, Kerstin"
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Enantioselective Modular Synthesis of Cyclohexenones: Total Syntheses of (+)-Crypto- and (+)-Infectocaryone
Published in Organic letters (03-09-2010)“…A modular synthesis of cyclohexenones is described and applied to the first enantioselective total syntheses of (+)-crypto- and (+)-infectocaryone. Key steps…”
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2
A Configurational Switch Based on Iridium-Catalyzed Allylic Cyclization: Application in Asymmetric Total Syntheses of Prosopis, Dendrobate, and Spruce Alkaloids
Published in Chemistry : a European journal (12-10-2009)“…A method for the stereoselective synthesis of 2,6‐disubstituted piperidines has been developed that is based on the use of an intramolecular iridium‐catalyzed…”
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3
[2.2.2]Paracyclophane-TrienesAttractive Monomers for ROMP
Published in ACS macro letters (20-05-2014)“…Three derivatives of 4,7-substituted [2.2.2]paracyclophane-trienes were synthesized and used in ring-opening metathesis polymerization (ROMP), resulting in…”
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4
Stereoselective Synthesis of 2,6-Disubstituted Piperidines Using the Iridium-Catalyzed Allylic Cyclization as Configurational Switch: Asymmetric Total Synthesis of (+)-241 D and Related Piperidine Alkaloids
Published in Chemistry : a European journal (16-02-2009)“…Pressing the configurational switch: Use of enantiomeric Ir catalysts allows the vinylpiperidine building blocks 2 a and 2 b to be synthesized with high…”
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5
Water-Soluble Cruciforms and Distyrylbenzenes: Synthesis, Characterization, and pH-Dependent Amine-Sensing Properties
Published in Journal of organic chemistry (17-05-2013)“…Three water-soluble fluorescent aldehyde-substituted distyrylbenzene derivatives were prepared using Heck or Horner methodologies. Water solubility was…”
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6
Water-Soluble Distyrylbenzenes: One Core with Two Sensory Responses-Turn-On and Ratiometric
Published in Chemistry : a European journal (02-12-2011)“…The synthesis of four water‐soluble distyrylbenzenes (compounds 1–4) is reported. Their acidochromicity in aqueous media was investigated. Blue shifts and…”
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7
Ir-Catalysed Asymmetric Allylic Substitutions with Cyclometalated (Phosphoramidite)Ir Complexes-Resting States, Catalytically Active (π-Allyl)Ir Complexes and Computational Exploration
Published in Chemistry : a European journal (11-06-2010)“…Mechanistic aspects of allylic substitutions with iridium catalysts derived from phosphoramidites by cyclometalation were investigated. The determination of…”
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8
Azaacene Diradicals Based on Non‐Kekulé Meta‐Quinodimethane with Large Two‐Photon Cross‐Sections in the Infrared Spectral Region
Published in Angewandte Chemie International Edition (25-11-2024)“…Non‐Kekulé quinoidal azaacences m‐A (1 a,b) were synthesized and compared to their para‐ and ortho‐quinodimethane analogues. m‐A display high diradical…”
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9
Substituted Cyclopentannulated Tetraazapentacenes
Published in Chemistry : a European journal (16-11-2022)“…Brominated pentannulated dihydrotetraazapentacenes were prepared by gold‐ or palladium‐catalyzed 5‐endo‐dig cyclization of TIPS‐ethynylated…”
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10
Cyclopentannulated Dihydrotetraazapentacenes
Published in Chemistry : a European journal (24-02-2022)“…The transition‐metal‐catalyzed cyclization of bissilylethynylated N,N’‐dihydrotetraazapentacene (TIPS‐TAP‐H2) into bissilylated cyclopenta[fg,qr]pentacenes is…”
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11
Azaacene Diradicals Based on Non‐Kekulé Meta‐Quinodimethane with Large Two‐Photon Cross‐Sections in the Infrared Spectral Region
Published in Angewandte Chemie (25-11-2024)“…Non‐Kekulé quinoidal azaacences m‐A (1 a,b) were synthesized and compared to their para‐ and ortho‐quinodimethane analogues. m‐A display high diradical…”
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12
Ir-Catalyzed Asymmetric Allylic Substitutions with (Phosphoramidite)Ir Complexes-Resting States, Synthesis, and Characterization of Catalytically Active (π-Allyl)Ir Complexes
Published in Chemistry : a European journal (26-10-2009)“…(π‐Allyl)Ir complexes: A new and very simple one‐pot synthesis of (π‐allyl)Ir complexes derived from phosphoramidites L is presented (see scheme). Ready…”
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13
Pyridine-Substituted BODIPY as Fluorescent Probe for Hg2
Published in European journal of organic chemistry (01-04-2012)“…Dialkynylated BODIPYs bearing pyridine or dibutylaniline substituents have been synthesized, and their photophyisical properties in the presence of different…”
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14
Poly(para-phenylene vinylene) and Polynorbornadiene Containing Rod-Coil Block Copoylmers via Combination of Acyclic Diene Metathesis and Ring-Opening Metathesis Polymerization
Published in Macromolecular rapid communications. (27-05-2013)“…Poly(para‐phenylene vinylene) (PPV) and its derivatives are important semiconducting polymers for organic electronics. Herein, an alkene metathesis approach to…”
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15
Pyridine‐Substituted BODIPY as Fluorescent Probe for Hg 2
Published in European journal of organic chemistry (01-04-2012)“…Dialkynylated BODIPYs bearing pyridine or dibutylaniline substituents have been synthesized, and their photophyisical properties in the presence of different…”
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16
Stereoselective Synthesis of a cis-1,2-Dialkylcyclopentane Building Block and Its Application in Isoprostane Synthesis (5-ent-F2c-IsoP)
Published in European Journal of Organic Chemistry (01-05-2008)“…The all‐cis substituted cyclopentane 3a, an analogue of the Corey lactone, has been prepared from a readily available nortricyclanone derivative by a five‐step…”
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Syntheses of New Chiral Phosphane Ligands by Diastereoselective Conjugate Addition of Phosphides to Enantiomerically Pure Acceptor-Substituted Olefins from the Chiral Pool
Published in European Journal of Organic Chemistry (01-08-2005)“…A variety of new chiral phosphanes were prepared by highly diastereoselective additions of phosphanes to α,β‐unsaturated carbonyl compounds and related…”
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