Search Results - "Boyke, Christine A"
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Precursors to [FeFe]-Hydrogenase Models: Syntheses of Fe2(SR)2(CO)6 from CO-Free Iron Sources
Published in Inorganic chemistry (04-08-2008)“…This report describes routes to iron dithiolato carbonyls that do not require preformed iron carbonyls. The reaction of FeCl2, Zn, and Q2S2C n H2n (Q+ = Na+,…”
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Diferrous Cyanides as Models for the Fe-only Hydrogenases
Published in Journal of the American Chemical Society (10-08-2005)“…The first systematic study of diferrous dicyano dithiolates is described. Oxidation of [Fe2(S2C2H4)(CN)2(CO)4]2- in the presence of cyanide and tertiary…”
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Precursors to [FeFe]-Hydrogenase Models: Syntheses of Fe 2 (SR) 2 (CO) 6 from CO-Free Iron Sources
Published in Inorganic chemistry (04-08-2008)Get full text
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Nuclear Resonance Vibrational Spectroscopy and Electron Paramagnetic Resonance Spectroscopy of 57Fe-Enriched [FeFe] Hydrogenase Indicate Stepwise Assembly of the H‑Cluster
Published in Biochemistry (Easton) (05-02-2013)“…The [FeFe] hydrogenase from Clostridium pasteurianum (CpI) harbors four Fe–S clusters that facilitate the transfer of an electron to the H-cluster, a…”
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NRVS and EPR Spectroscopy of 57Fe-enriched [FeFe] Hydrogenase Indicate Stepwise Assembly of the H-cluster
Published in Biochemistry (Easton) (24-01-2013)“…The [FeFe] hydrogenase from Clostridium pasteurianum (CpI) harbors four Fe–S clusters that facilitate electron transfer to the H-cluster, a ligand-coordinated…”
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Precursors to [FeFe]-Hydrogenase Models: Syntheses of Fe sub(2)(SR) sub(2)(CO) sub(6) from CO-Free Iron Sources
Published in Inorganic chemistry (04-08-2008)“…This report describes routes to iron dithiolato carbonyls that do not require preformed iron carbonyls. The reaction of FeCl sub(2), Zn, and Q sub(2)S sub(2)C…”
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[Fe2(SR)2(mu-CO)(CNMe)6]2+ and analogues: a new class of diiron dithiolates as structural models for the H(ox)Air state of the fe-only hydrogenase
Published in Journal of the American Chemical Society (24-11-2004)“…Low-temperature oxidation of Fe(2)(S(2)C(n)H(2n)(CNMe)(6-x)(CO)x (n = 2, 3; x = 2, 3) affords a family of mixed carbonyl-isocyanides of the type…”
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Diferrous structural and functional models of the iron-only hydrogenases
Published 01-01-2006“…The Fe-only hydrogenases catalyze the interconversion between protons and dihydrogen. The active site consists of a diiron dithiolate with a terminal CO and…”
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Diferrous structural and functional models of the iron-only hydrogenases
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Dissertation -
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[Fe2(SR)2(μ-CO)(CNMe)6]2+ and Analogues: A New Class of Diiron Dithiolates as Structural Models for the Ho x Air State of the Fe-Only Hydrogenase
Published in Journal of the American Chemical Society (24-11-2004)“…Low-temperature oxidation of Fe2(S2C n H2 n )(CNMe)6 - x (CO) x (n = 2, 3; x = 2, 3) affords a family of mixed carbonyl-isocyanides of the type [Fe2(S2C n H2 n…”
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