Search Results - "Boyer, Cyrille"
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Seeing the Light: Advancing Materials Chemistry through Photopolymerization
Published in Angewandte Chemie International Edition (08-04-2019)“…The application of photochemistry to polymer and material science has led to the development of complex yet efficient systems for polymerization, polymer…”
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Stereo‑, Temporal and Chemical Control through Photoactivation of Living Radical Polymerization: Synthesis of Block and Gradient Copolymers
Published in Journal of the American Chemical Society (12-08-2015)“…Nature has developed efficient polymerization processes, which allow the synthesis of complex macromolecules with a perfect control of tacticity as well as…”
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3
Exploiting Metalloporphyrins for Selective Living Radical Polymerization Tunable over Visible Wavelengths
Published in Journal of the American Chemical Society (22-07-2015)“…The use of metalloporphyrins has been gaining popularity particularly in the area of medicine concerning sensitizers for the treatment of cancer and…”
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4
Photoinitiated Polymerization‐Induced Self‐Assembly (Photo‐PISA): New Insights and Opportunities
Published in Advanced science (01-07-2017)“…The polymerization‐induced self‐assembly (PISA) process is a useful synthetic tool for the efficient synthesis of polymeric nanoparticles of different…”
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Visible Light Photocatalytic Thiol–Ene Reaction: An Elegant Approach for Fast Polymer Postfunctionalization and Step-Growth Polymerization
Published in Macromolecules (10-02-2015)“…An elegant approach for fast polymer postfunctionalization and step-growth polymerization (via addition reaction) under aerobic condition was developed from…”
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Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications
Published in Progress in polymer science (01-12-2020)“…Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain…”
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Light-Regulated Polymerization under Near-Infrared/Far-Red Irradiation Catalyzed by Bacteriochlorophyll a
Published in Angewandte Chemie International Edition (18-01-2016)“…Photoregulated polymerizations are typically conducted using high‐energy (UV and blue) light, which may lead to undesired side reactions. Furthermore, as the…”
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A Versatile 3D and 4D Printing System through Photocontrolled RAFT Polymerization
Published in Angewandte Chemie International Edition (09-12-2019)“…Reversible addition‐fragmentation chain‐transfer (RAFT) polymerization is a valuable tool for synthesizing macromolecules with controlled topologies and…”
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A Robust and Versatile Photoinduced Living Polymerization of Conjugated and Unconjugated Monomers and Its Oxygen Tolerance
Published in Journal of the American Chemical Society (09-04-2014)“…Controlled/living radical polymerization techniques have transformed polymer chemistry in the last few decades, affording the production of polymers with…”
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10
Effective Utilization of NIR Wavelengths for Photo‐Controlled Polymerization: Penetration Through Thick Barriers and Parallel Solar Syntheses
Published in Angewandte Chemie International Edition (27-01-2020)“…This contribution details an efficient and controlled photopolymerization regulated by far‐red (λ=680 nm) and NIR (λ=780 and 850 nm) light in the presence of…”
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11
Mediating Reaction Orthogonality in Polymer and Materials Science
Published in Angewandte Chemie International Edition (25-01-2021)“…Selective control of chemical reactions is critical for the proper regulation of processes ranging from intricate biological systems to large scale industrial…”
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12
Oxygen Tolerance Study of Photoinduced Electron Transfer–Reversible Addition–Fragmentation Chain Transfer (PET-RAFT) Polymerization Mediated by Ru(bpy)3Cl2
Published in Macromolecules (08-07-2014)“…This study reports a highly efficient photoredox catalyst, Ru(bpy)3Cl2, capable of controlling the polymerization of methacrylates, acrylates, and acrylamides…”
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13
Utilizing the electron transfer mechanism of chlorophyll a under light for controlled radical polymerization
Published in Chemical science (Cambridge) (01-01-2015)“…Efficient photoredox catalysts containing transition metals, such as iridium and ruthenium, to initiate organic reactions and polymerization under visible…”
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100th Anniversary of Macromolecular Science Viewpoint: Photochemical Reaction Orthogonality in Modern Macromolecular Science
Published in ACS macro letters (16-07-2019)“…The ability to perform multiple chemical reactions independently (orthogonally) in a single reaction vessel can allow simplified reaction protocols for…”
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15
Polymerization Induced Microphase Separation for the Fabrication of Nanostructured Materials
Published in Angewandte Chemie International Edition (26-10-2023)“…Polymerization induced microphase separation (PIMS) is a strategy used to develop unique nanostructures with highly useful morphologies through the microphase…”
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Controlling Molecular Weight Distributions through Photoinduced Flow Polymerization
Published in Macromolecules (14-11-2017)“…Molecular weight distribution plays an important role by giving specific properties to polymeric materials. Despite the recent progress in controlled/“living”…”
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Polymerization-Induced Self-Assembly Using Visible Light Mediated Photoinduced Electron Transfer–Reversible Addition–Fragmentation Chain Transfer Polymerization
Published in ACS macro letters (15-09-2015)“…The ruthenium-based photoredox catalyst, Ru(bpy)3Cl2, was employed to activate reversible addition–fragmentation chain transfer (RAFT) dispersion…”
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Rational Design of Photocatalysts for Controlled Polymerization: Effect of Structures on Photocatalytic Activities
Published in Chemical reviews (23-03-2022)“…Over the past decade, the use of photocatalysts (PCs) in controlled polymerization has brought new opportunities in sophisticated macromolecular synthesis…”
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Bioactive Synthetic Polymers
Published in Advanced materials (Weinheim) (01-01-2022)“…Synthetic polymers are omnipresent in society as textiles and packaging materials, in construction and medicine, among many other important applications…”
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Organic photocatalysts for cleaner polymer synthesis
Published in Science (American Association for the Advancement of Science) (27-05-2016)“…Metal-free catalysts enable synthesis of polymers for biomedical and electronics applications The material properties of synthetic polymers can be tuned by…”
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