Search Results - "Boyd, Peter D W"
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Supramolecular Fullerene-Porphyrin Chemistry. Fullerene Complexation by Metalated “Jaws Porphyrin” Hosts
Published in Journal of the American Chemical Society (12-06-2002)“…Porphyrins and fullerenes are spontaneously attracted to each other. This new supramolecular recognition element is explored in discrete, soluble,…”
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Synthesis and antimalarial and antituberculosis activities of a series of natural and unnatural 4-methoxy-6-styryl-pyran-2-ones, dihydro analogues and photo-dimers
Published in Bioorganic & medicinal chemistry (15-02-2012)“…Previous studies have identified the 3,6-dialkyl-4-hydroxy-pyran-2-one marine microbial metabolites pseudopyronines A and B to be modest growth inhibitors of…”
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Diboryl and Diboranyl Porphyrin Complexes: Synthesis, Structural Motifs, and Redox Chemistry: Diborenyl Porphyrin or Diboranyl Isophlorin?
Published in Chemistry : a European journal (01-01-2007)“…The syntheses of diboryl porphyrin complexes [(BX2)2(ttp)] (ttp: dianion of tetra‐p‐tolylporphyrin) and the BB single‐bond diboranyl complexes [(BX)2(ttp)]…”
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Reduction of a Chelating Bis(NHC) Palladium(II) Complex to [{μ-bis(NHC)}₂Pd₂H]⁺: A Terminal Hydride in a Binuclear Palladium(I) Species Formed under Catalytically Relevant Conditions
Published in Angewandte Chemie (International ed.) (23-08-2010)“…Half‐way house: The first palladium(I) N‐heterocyclic carbene complex has been isolated in high yield by the base‐assisted reduction of a palladium(II)…”
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Fullerene−Porphyrin Constructs
Published in Accounts of chemical research (01-04-2005)“…Porphyrins and fullerenes are spontaneously attracted to each other. This new supramolecular recognition element can be used to construct discrete host−guest…”
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Corrole as a Binucleating Ligand: Preparation, Molecular Structure and Density Functional Theory Study of Diboron Corroles
Published in Journal of the American Chemical Society (12-03-2008)“…The reactions of BF3·OEt2 with four triaryl corroles (H3Cor) give the complexes [(B2OF2)(Cor)]- in which the corrole acts as a binucleating ligand. The new…”
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Noncovalent endo-binding of fullerenes to diprotonated bisporphyrins
Published in Physical chemistry chemical physics : PCCP (07-12-2011)“…Noncovalent binding of fullerenes to bisporphyrins was studied in the gas phase by energy-dependent collision-induced dissociation (CID) with Xe under…”
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Synthesis of the C59N+ Carbocation. A Monomeric Azafullerene Isoelectronic to C60
Published in Journal of the American Chemical Society (09-04-2003)“…A heterofullerene isoelectronic to C60 is reported. The azafullerenium cation C59N+ can be isolated in good yield as a carborane salt via the two-electron…”
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Extending the Range of Neutral N-Donor Ligands Available for Metal Catalysts: N-[1-Alkylpyridin-4(1H)-ylidene]amides in Palladium-Catalyzed Cross-Coupling Reactions
Published in Inorganic chemistry (07-11-2011)“…N-[1-Alkylpyridin-4(1H)-ylidene]amides (PYAs) are a new class of easily prepared, neutral N-donor ligands that share some features in common with…”
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Calix[4]arene-Linked Bisporphyrin Hosts for Fullerenes: Binding Strength, Solvation Effects, and Porphyrin−Fullerene Charge Transfer Bands
Published in Journal of the American Chemical Society (13-12-2006)“…A calix[4]arene scaffolding has been used to construct bisporphyrin (“jaws” porphyrin) hosts for supramolecular binding of fullerene guests. Fullerene…”
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Artifacts in the Electron Paramagnetic Resonance Spectra of C60 Fullerene Ions: Inevitable C120O Impurity
Published in Journal of the American Chemical Society (24-04-2002)“…Aspects of the electron paramagnetic resonance (EPR) spectra of C60 n - fulleride ions (n = 2, 3) and the EPR signal observed in solid C60 are reinterpreted…”
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Iron(II) Tris-[N 4-substituted-3,5-di(2-pyridyl)-1,2,4-triazole] Complexes: Structural, Magnetic, NMR, and Density Functional Theory Studies
Published in Inorganic chemistry (20-07-2009)“…Eight mononuclear iron(II) complexes of N 4-3,5-di(2-pyridyl)-1,2,4-triazole (Rdpt) ligands have been prepared and characterized. In all cases the…”
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Isolating Benzenium Ion Salts
Published in Journal of the American Chemical Society (19-02-2003)“…When partnered with carborane anions, arenium ions are remarkably stable. Previously investigated only at subambient temperatures in highly superacidic media,…”
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Extending Supramolecular Fullerene-Porphyrin Chemistry to Pillared Metal-Organic Frameworks
Published in Proceedings of the National Academy of Sciences - PNAS (16-04-2002)“…Porphyrins and fullerenes are spontaneously attracted to each other. This supramolecular recognition element can be exploited to produce ordered arrays of…”
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Nucleation of Antiferromagnetically Coupled Chromium Dihalides: from Small Clusters to the Solid State
Published in Inorganic chemistry (05-04-2010)“…The nucleation of chromium dihalide clusters is investigated by studying clusters of the form Cr n X2n (n ≤ 4, X = F, Cl, Br, and I) for different spin states…”
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Molecular Structure of the Solvated Proton in Isolated Salts. Short, Strong, Low Barrier (SSLB) H-bonds
Published in Journal of the American Chemical Society (20-11-2002)“…Large, inert, weakly basic carborane anions of the icosahedral type CHB11R5X6 - (R = H, Me; X = Cl, Br) allow ready isolation and structural characterization…”
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(4R)-4-[(1R)-1,2-Dihydroxy-ethyl]-1-[(1R)-1-phenyl-ethyl]pyrrolidin-2-one
Published in Acta crystallographica. Section E, Structure reports online (01-09-2008)“…The title compound, C(14)H(19)NO(3), was obtained as one of the two isomers of a Sharpless asymmetric dihydroxy-lation reaction of…”
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Porphyrin−Fullerene Host−Guest Chemistry
Published in Journal of the American Chemical Society (01-11-2000)Get full text
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Bis(1-ferrocenylbutane-1,3-dionato-κ2O,O′)copper(II) and bis(1,3-diferrocenylpropane-1,3-dionato-κ2O,O′)copper(II)
Published in Acta crystallographica. Section C, Crystal structure communications (01-12-2006)“…The title compounds, [CuFe2(C5H5)2(C9H8O2)2], (I), and [CuFe4(C5H5)4(C13H9O2)2], (II), are four‐coordinate square‐planar copper(II) complexes with two…”
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Density Functional Theory Study on the Mechanism of the Reductive Cleavage of CO2 by a Bis-β-Diketoiminatediiron Dinitrogen Complex
Published in Inorganic chemistry (06-09-2010)“…Density functional theory has been used to analyze the detailed reaction mechanism for the reductive cleavage of CO2 by a dinitrogen bridged…”
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