Search Results - "Boyarskiy, Vadim P"
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Metal-Mediated and Metal-Catalyzed Reactions of Isocyanides
Published in Chemical reviews (08-04-2015)“…Ways in which osocyanides are used in organic chemistry are examined. Chemoselectivity and bond-making processes in relation to MCRs are also reviewed…”
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The halogen bond with isocyano carbon reduces isocyanide odor
Published in Nature communications (10-06-2020)“…Predominantly, carbon atoms of various species function as acceptors of noncovalent interactions when they are part of a π-system. Here, we report on the…”
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3
Facile Gold-Catalyzed Heterocyclization of Terminal Alkynes and Cyanamides Leading to Substituted 2‑Amino-1,3-Oxazoles
Published in Organic letters (17-07-2015)“…Facile gold-catalyzed heterocyclization based upon intermolecular trapping of the generated α-oxo gold carbenes with various cyanamides R2R3NCN (R2/R3 =…”
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π-π Noncovalent Interaction Involving 1,2,4- and 1,3,4-Oxadiazole Systems: The Combined Experimental, Theoretical, and Database Study
Published in Molecules (Basel, Switzerland) (18-09-2021)“…A series of -pyridyl ureas bearing 1,2,4- ( , , and ) and 1,3,4-oxadiazole moiety ( , , ) was prepared and characterized by HRMS, H and C NMR spectroscopy, as…”
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5
Room Temperature Synthesis of Bioactive 1,2,4-Oxadiazoles
Published in International journal of molecular sciences (01-03-2023)“…1,2,4-Oxadiazole is an essential motif in drug discovery represented in many experimental, investigational, and marketed drugs. This review covers synthetic…”
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Synthesis of 3-(Pyridin-2-yl)quinazolin-2,4(1 H, 3 H )-diones via Annulation of Anthranilic Esters with N -pyridyl Ureas
Published in International journal of molecular sciences (21-04-2023)“…A new route for the synthesis of quinazolin-2,4(1 3 )-diones and thieno [2,3- ]pyrimidine-2,4(1 ,3 )-diones substituted by pyridyl/quinolinyl moiety in…”
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Rhodamines NN: A Novel Class of Caged Fluorescent Dyes
Published in Angewandte Chemie (International ed.) (03-05-2010)“…A bright future: The reaction of diazomethane with acid chlorides obtained from N,N,N′,N′‐tetraalkylrhodamines affords…”
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Application of palladium complexes bearing acyclic amino(hydrazido)carbene ligands as catalysts for copper-free Sonogashira cross-coupling
Published in Journal of catalysis (01-09-2015)“…[Display omitted] •Palladium-[amino(hydrazido)carbene] complexes as catalysts for Sonogashira reaction.•Catalytic system generates internal alkynes in 75–96%…”
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Hybrid 2D Supramolecular Organic Frameworks (SOFs) Assembled by the Cooperative Action of Hydrogen and Halogen Bonding and π⋯π Stacking Interactions
Published in International journal of molecular sciences (01-02-2024)“…The - and -isomers of 6-(3-(3,4-dichlorophenyl)-1,2,4-oxadiazol-5-yl)cyclohex-3-ene-1-carboxylic acid ( - and - ) were obtained by the reaction of…”
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Conformation-Associated C···dz2-PtII Tetrel Bonding: The Case of Cyclometallated Platinum(II) Complex with 4-Cyanopyridyl Urea Ligand
Published in International journal of molecular sciences (05-04-2024)“…The nucleophilic addition of 3-(4-cyanopyridin-2-yl)-1,1-dimethylurea (1) to cis-[Pt(CNXyl)2Cl2] (2) gave a new cyclometallated compound 3. It was…”
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11
Rhodamine Spiroamides for Multicolor Single-Molecule Switching Fluorescent Nanoscopy
Published in Chemistry : a European journal (19-10-2009)“…The design, synthesis, and evaluation of new rhodamine spiroamides are described. These molecules have applications in optical nanoscopy based on random…”
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When a Side Reaction Is a Benefit: A Catalyst-Free Route to Obtain High-Molecular Cobaltocenium-Functionalized Polysiloxanes by Hydroamination
Published in Polymers (14-10-2024)“…Cobaltocenium-containing (co)polysiloxanes (Cc-PDMSs) with terminal and side groups were synthesized by the reaction of catalyst-free hydroamination between…”
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Unusual Formation of 1,2,4-Oxadiazine Core in Reaction of Amidoximes with Maleic or Fumaric Esters
Published in Molecules (Basel, Switzerland) (01-11-2022)“…We have developed a simple and convenient method for the synthesis of 3-aryl- and 3-hetaryl-1,2,4-oxadiazin-5-ones bearing an easily functionalizable…”
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14
Masked Rhodamine Dyes of Five Principal Colors Revealed by Photolysis of a 2-Diazo-1-Indanone Caging Group: Synthesis, Photophysics, and Light Microscopy Applications
Published in Chemistry : a European journal (06-10-2014)“…Caged rhodamine dyes (Rhodamines NN) of five basic colors were synthesized and used as “hidden” markers in subdiffractional and conventional light microscopy…”
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Palladium-Functionalized Polysiloxane Drop-Casted on Carbon Paper as a Heterogeneous Catalyst for the Suzuki-Miyaura Reaction
Published in Polymers (06-10-2024)“…In this work, a Pd(II)- -cyclometalated complex was grafted to polysiloxanes via azide-alkyne cycloaddition. The obtained polymer-metal complex (Pd-PDMS) acts…”
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Piezo-Responsive Hydrogen-Bonded Frameworks Based on Vanillin-Barbiturate Conjugates
Published in Molecules (Basel, Switzerland) (01-09-2022)“…A concept of piezo-responsive hydrogen-bonded π-π-stacked organic frameworks made from Knoevenagel-condensed vanillin–barbiturate conjugates was proposed…”
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17
Intra-/Intermolecular Bifurcated Chalcogen Bonding in Crystal Structure of Thiazole/Thiadiazole Derived Binuclear (Diaminocarbene)PdII Complexes
Published in Crystals (Basel) (27-02-2018)“…The coupling of cis-[PdCl2(CNXyl)2] (Xyl = 2,6-Me2C6H3) with 4-phenylthiazol-2-amine in molar ratio 2:3 at RT in CH2Cl2 leads to binuclear (diaminocarbene)PdII…”
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Molecular Switching through Chalcogen-Bond-Induced Isomerization of Binuclear (Diaminocarbene)PdII Complexes
Published in Inorganics (01-06-2023)“…Binuclear diaminocarbene complexes, which form as a regioisomer mixture in the reaction between isocyanide–palladium(II) complex cis-[PdCl2(CNXyl)2] and…”
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Coupling of Thiazole-2-Amines with Isocyanide Ligands in bis-(Isocyanide) Platinum Complex: A New Type of Reactivity
Published in Inorganics (01-12-2022)“…The treatment of cis-[PtCl2(XylNC)2] with thiazol-2-amines in a 2:1 ratio leads to a regioisomeric mixture of two binuclear complexes. These regioisomers are…”
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Photostable, Amino Reactive and Water-Soluble Fluorescent Labels Based on Sulfonated Rhodamine with a Rigidized Xanthene Fragment
Published in Chemistry : a European journal (18-02-2008)“…Highly water soluble fluorescent dyes were synthesized and transformed into new amino reactive fluorescent labels for biological microscopy. To this end,…”
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