Search Results - "Bowyer, Walter J"

Solvent Effects on Heterogeneous Rate Constants for Indium Mediated Allylations by Mora, Kathryn E, Musa, Megan A, Robinson, Troy J, Mylod, Gabriella, Bowyer, Walter J

“…Indium mediated allylation is a highly selective tool for synthetic chemists to create carbon–carbon bonds, but the first step, heterogeneous reaction of allyl…”
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Nature of the intermediates formed during indium mediated allylation under Barbier conditions. Spectroscopic and experimental data on allylindium species by Bowyer, Walter J., Singaram, Bakthan, Sessler, Anne M.

“…[Display omitted]…”
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Heterogeneous Rate Constants for Indium Mediated Allylations: Cinnamyl Chloride in Ethanol/Water Mixtures by Hill, Alexa N, Delaney, Katherine M, Sullivan, Tessa R, Mylod, Gabriella, Kiesow, Katrina H, Bowyer, Walter J

“…Indium mediated allylation (IMA) offers a powerful tool to synthetic chemists for creating carbon–carbon bonds. However, its rate limiting step, the…”
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Reactivity of Magnesium Surfaces during the Formation of Grignard Reagents by Teerlinck, Cynthia E, Bowyer, Walter J

“…A reaction cell which allows for photomicrographic observation of magnesium surfaces during formation of Grignard reagents is described. As the reaction…”
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Determining Proton Diffusion in Polymer Films by Lifetimes of Luminescent Complexes Measured in the Frequency Domain by Bowyer, Walter J, Xu, Wenying, Demas, J. N

“…Polymer-supported luminescent metal complexes represent an important class of oxygen, pH, and ion sensors. The diffusion properties of the analyte into the…”
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Measurement of Heterogeneous Reaction Rates: Three Strategies for Controlling Mass Transport and Their Application to Indium-Mediated Allylations by Olson, Isabel A, Bacon, Wendi A, Baez Sosa, Yessica Y, Delaney, Katherine M, Forte, Salvador A, Guglielmo, Michael A, Hill, Alexa N, Kiesow, Katrina H, Langenbacher, Rachel E, Xun, Yuhan, Young, Ryan O, Bowyer, Walter J

“…We describe three new strategies for determining heterogeneous reaction rates using photomicroscopy to measure the rate of retreat of metal surfaces: (i)…”
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Measurement of Heterogeneous Reaction Rates during Indium-Mediated Allylation by Olson, Isabel A, Sessler, Anne M, Connell, Jodi L, Giordano, Esthefanie, Baez Sosa, Yessica Y, Zavaleta, Salvador W, Bowyer, Walter J

“…Indium-mediated allylation provides remarkable stereo- and regioselectivity, and it proceeds easily and in high yield in aqueous solutions. In spite of its…”
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Determining Oxygen Diffusion Coefficients in Polymer Films by Lifetimes of Luminescent Complexes Measured in the Frequency Domain by Bowyer, Walter J, Xu, Wenying, Demas, J. N

“…Polymer films doped with luminescent ruthenium complexes are proving to be important oxygen sensors. We describe a technique using lifetime measurements in the…”
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Absolute Kinetic Rate Constants and Activation Energies for the Formation of Grignard Reagents by Beals, Bridget J, Bello, Zainab I, Cuddihy, Kathleen P, Healy, Ethan M, Koon-Church, Stephanie E, Owens, Jane M, Teerlinck, Cynthia E, Bowyer, Walter J

“…This paper reports the first absolute rate constants for the formation of Grignard reagents from magnesium metal and organohalides. The theory that allows…”
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Fluorescence Imaging of the Heterogeneous Reduction of Oxygen by Bowyer, Walter J, Xie, Jian, Engstrom, Royce C

“…The reduction of oxygen at a variety of solid electrodes was spatially imaged using fluorescence microscopy. Hydroxide produced during electrolysis of oxygen…”
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Structural consequences of electron-transfer reactions. Part 18. Redox-induced hapticity changes: effect of substituents on arene bending in a series of rhodium complexes by Bowyer, Walter J, Merkert, Jon W, Geiger, William E, Rheingold, Arnold L

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Replication of the conversion of goethite to hematite to make pigments in both furnace and campfire by Lin, Zhenyu, Natoli, Julia M., Picuri, Jules C., Shaw, Sophia E., Bowyer, Walter J.

“…[Display omitted] •Conversion of brown goethite to red hematite is replicated in wood fires.•Heating ochre as powder or lump easily generates clean…”
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Can X-ray Diffraction Distinguish Natural from Anthropogenic Hematite? Replication of the Conversion of Natural Goethite in Both Furnace and Campfire by Picuri, Jules C., Natoli, Julia M., Shaw, Sophia E., Shyam, Shruthi P., VanHoesen, Stephen R., Lin, Zhenyu, Bowyer, Walter J.

“…Hematite, the mineral that gives color to bright red iron ochres, occurs naturally, but there is much evidence that early humans sometimes artificially…”
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Structural consequences of electron-transfer reactions. 11. Electrochemically induced changes in hapticity in mixed-sandwich compounds of iridium and rhodium by Bowyer, Walter J, Geiger, William E

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A Novel Format for Seminar during the Senior Year of the College Chemistry Curriculum by Bowyer, Walter J., Kaydos, Janet A.

“…A new format for the "senior seminar" is described. Rather than having students and guest speakers present seminars on a miscellany of topics, we find it…”
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Fabrication of band microelectrode arrays from metal foil and heat-sealing fluoropolymer film by Odell, David M, Bowyer, Walter J

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Electrochemical reduction of vicinal dinitro compounds by Bowyer, Walter J, Evans, Dennis H

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Electrochemical measurements in submicroliter volumes by Bowyer, Walter J, Clark, Mary Elizabeth, Ingram, Jennifer L

“…A method for performing three-electrode voltammetry in total solution volumes is described. Through this method, both aqueous and nonaqueous solutions can be…”
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Visualization of the areal distribution of the reactivity of magnesium surfaces in the formation of Grignard reagents by Koon, Stephanie E, Oyler, Cynthia E, Hill, John H. M, Bowyer, Walter J

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An electrochemical study of the reduction of mono- and bis(iron) cyclophane complexes by Bowyer, Walter J, Geiger, William E, Boekelheide, Virgil

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