Search Results - "Boscá, Francisco"
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BASHY Dyes Are Highly Efficient Lipid Droplet-Targeting Photosensitizers that Induce Ferroptosis through Lipid Peroxidation
Published in Bioconjugate chemistry (20-12-2023)“…Ferroptosis is an iron-dependent lipid-peroxidation-driven mechanism of cell death and a promising therapeutic target to eradicate cancer cells. In this study,…”
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2
Synthesis of Bis(amino acids) Containing the Styryl-cyclobutane Core by Photosensitized [2+2]-Cross-cycloaddition of Allylidene-5(4 H )-oxazolones
Published in International journal of molecular sciences (20-04-2023)“…The irradiation of 2-aryl-4-( -3'-aryl-allylidene)-5(4 )-oxazolones with blue light (456 nm) in the presence of [Ru(bpy) ](BF ) (bpy = 2,2'-bipyridine, 5% mol)…”
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3
Electronic and Functional Scope of Boronic Acid Derived Salicylidenehydrazone (BASHY) Complexes as Fluorescent Dyes
Published in Journal of organic chemistry (21-07-2017)“…A series of boronic acid derived salicylidenehydrazone (BASHY) complexes was prepared and photophysically characterized. The dye platform can be modified by…”
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4
Human Serum Albumin-Mediated Stereodifferentiation in the Triplet State Behavior of (S)- and (R)-Carprofen
Published in Journal of the American Chemical Society (11-08-2004)“…A remarkable stereodifferentiation has been observed in the interaction between the excited triplet state of carprofen (CP) and human serum albumin (HSA)…”
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5
Triplet Reactivity and Regio-/Stereoselectivity in the Macrocyclization of Diastereomeric Ketoprofen−Quencher Conjugates via Remote Hydrogen Abstractions
Published in Journal of the American Chemical Society (13-06-2007)“…Intramolecular excited triplet state interactions in diastereomeric compounds composed of a benzophenone chromophore (ketoprofen) and various hydrogen donor…”
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6
A continuous-flow catalytic process with natural hematite-alginate beads for effective water decontamination and disinfection: Peroxymonosulfate activation leading to dominant sulfate radical and minor non-radical pathways
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (01-05-2021)“…[Display omitted] •A natural Fe2O3 compound was effectively employed as stable heterogeneous PMS activator.•Hormuz Red Soil (HRS) was fully characterized (XRF,…”
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7
Photonucleophilic Aromatic Substitution of 6-Fluoroquinolones in Basic Media: Triplet Quenching by Hydroxide Anion
Published in Journal of organic chemistry (15-10-2004)“…Photoreaction of 1-ethyl-6-fluoro-7-(1-piperazinyl)-1,4-dihydro-4-oxoquinoline-3-carboxylic acid (norfloxacin, NFX) and other 6-fluoroquinolones in aqueous…”
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8
Stereoselective, Ruthenium-Photocatalyzed Synthesis of 1,2-Diaminotruxinic Bis-amino Acids from 4‑Arylidene-5(4H)‑oxazolones
Published in Journal of organic chemistry (04-03-2022)“…The irradiation of (Z)-2-phenyl-4-aryliden-5(4H)-oxazolones 1 in deoxygenated CH2Cl2 at 25 °C with blue light (465 nm) in the presence of [Ru(bpy)3](BF4)2…”
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9
Assessment of new immobilized photocatalysts based on Rose Bengal for water and wastewater disinfection
Published in Catalysis today (15-03-2023)“…The aim of this study was to evaluate the water disinfection capability of new immobilized photocatalysts based on the organic photosensitizer Rose Bengal (RB)…”
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10
Why is HSO5− so effective against bacteria? Insights into the mechanisms of Escherichia coli disinfection by unactivated peroxymonosulfate
Published in Water research (Oxford) (01-05-2024)“…•Superior E. coli disinfection efficacy occurred by unactivated PMS vs. PDS/H2O2.•Kinetic, biochemical, and genetic analyses defined the inactivation…”
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11
Visible Light‐Gated Organocatalysis Using a Ru II ‐Photocage
Published in Chemistry : a European journal (06-11-2020)“…Abstract The light‐gated organocatalysis via the release of 4‐ N , N ‐dimethylaminopyridine (DMAP) by irradiation of the [Ru(bpy) 2 (DMAP) 2 ] 2+ complex with…”
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12
Engineering the BASHY Dye Platform toward Architectures with Responsive Fluorescence
Published in Chemistry : a European journal (02-06-2023)“…A set of nine boronic‐acid‐derived salicylidenehydrazone (BASHY) complexes has been synthesized in good to very good chemical yields in a versatile…”
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13
Visible Light‐Gated Organocatalysis Using a RuII‐Photocage
Published in Chemistry : a European journal (06-11-2020)“…The light‐gated organocatalysis via the release of 4‐N,N‐dimethylaminopyridine (DMAP) by irradiation of the [Ru(bpy)2(DMAP)2]2+ complex with visible light was…”
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14
Assessment of new immobilized photocatalysts based on TiO2 for wastewater decontamination
Published in Journal of environmental chemical engineering (01-12-2023)“…With the main objective of overcoming the main drawbacks in the actual application of semiconductors in slurry in solar photocatalysis, new immobilized…”
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15
Photosensitized oxygenation reactions as an alternative towards the degradation of fenamates and related pollutants using visible light
Published in Journal of water process engineering (01-04-2024)“…Fenamates are a well-known family of non-steroidal anti-inflammatory compounds widely used in medicine. These compounds are found in surface waters and may be…”
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16
Photosensitized DNA Damage: The Case of Fluoroquinolones
Published in Photochemistry and photobiology (01-07-2009)“…This review focuses on DNA damage photosensitized by the fluoroquinolone (FQ) antibacterial drugs. The in vivo evidence for photocarcinogenesis mediated by FQs…”
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17
Solvent Effects in Hydrogen Abstraction from Cholesterol by Benzophenone Triplet Excited State
Published in Organic letters (05-08-2011)“…Hydrogen abstraction from the C-7 position of cholesterol (Ch) by triplet excited benzophenone (BZP) exhibits remarkable solvent-dependence in product studies…”
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18
Excited‐State Pathways of Four‐Coordinate N,C‐Chelate Organoboron Dyes
Published in ChemPhotoChem (01-01-2018)“…The excited‐state behavior of four‐coordinate N,C‐chelate organoboron dyes, based on arylisoquinoline ligands with varying degree of charge‐transfer character,…”
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19
Stereodifferentiating Drug−Biomolecule Interactions in the Triplet Excited State: Studies on Supramolecular Carprofen/Protein Systems and on Carprofen−Tryptophan Model Dyads
Published in The journal of physical chemistry. B (18-01-2007)“…Stereoselective interaction between a chiral nonsteroidal antiinflammatory drug, namely carprofen (CP), and human serum albumin (HSA) was studied, and the…”
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20
Seeking the mechanism responsible for fluoroquinolone photomutagenicity: a pulse radiolysis, steady-state, and laser flash photolysis study
Published in Free radical biology & medicine (01-02-2014)“…The mechanism responsible for the remarkable photomutagenicity of fluoroquinolone (FQ) antibiotics remains unknown. For this reason, it was considered…”
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