Search Results - "Bolte, Benoit"
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Gold(I)-Catalyzed Rearrangement of Propargyl Benzyl Ethers: A Practical Method for the Generation and in Situ Transformation of Substituted Allenes
Published in Journal of the American Chemical Society (02-06-2010)“…A series of benzyl propargyl ethers react with a gold(I) catalyst to furnish variously substituted allenes via a 1,5-hydride shift/fragmentation sequence. This…”
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2
Total Syntheses of the 3H‑Pyrrolo[2,3‑c]quinolone-Containing Alkaloids Marinoquinolines A–F, K, and Aplidiopsamine A Using a Palladium-Catalyzed Ullmann Cross-Coupling/Reductive Cyclization Pathway
Published in Journal of organic chemistry (17-01-2020)“…Compounds 1–6 and 11 representing key members of the marinoquinoline family of natural products, together with the related marine alkaloid aplidiopsamine A…”
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3
Modular Total Syntheses of the Marine-Derived Resorcylic Acid Lactones Cochliomycins A and B Using a Late-Stage Nozaki–Hiyama–Kishi Macrocyclization Reaction
Published in Journal of organic chemistry (02-01-2015)“…The natural products cochliomycin A (1) and cochliomycin B (2), two resorcylic acid lactones obtained from marine sources, have been prepared in a concise and…”
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4
Gold and Brønsted Acid Catalyzed Hydride Shift onto Allenes: Divergence in Product Selectivity
Published in Journal of the American Chemical Society (25-05-2011)“…A series of allenyl ethers can be transformed into various fused or spiro tetrahydrofurans and tetrahydropyrans following a hydride shift/cyclization sequence…”
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5
Alkyl Ethers as Traceless Hydride Donors in Brønsted Acid Catalyzed Intramolecular Hydrogen Atom Transfer
Published in Angewandte Chemie International Edition (22-05-2018)“…A new protocol for the deoxygenation of alcohols and the hydrogenation of alkenes under Brønsted acid catalysis has been developed. The method is based on the…”
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6
Chemical syntheses of the cochliomycins and certain related resorcylic acid lactones
Published in Tetrahedron letters (25-10-2017)“…[Display omitted] •All of the reported syntheses of the resorcylic acid lactones known as the cochliomycins are described.•Novel methods for assembling the…”
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7
Total Syntheses of the Resorcylic Acid Lactones Paecilomycin F and Cochliomycin C Using an Intramolecular Loh-Type α‑Allylation Reaction for Macrolide Formation
Published in Organic letters (02-09-2016)“…Subjection of the resorcylic ester 16 to a Nozaki–Hiyama–Kishi reaction afforded the 12-membered lactone 17, while treatment of it under the Loh-type…”
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8
Chemoenzymatic Total Syntheses of the Enantiomers of the Protoilludanes 8‑Deoxydihydrotsugicoline and Radudiol
Published in Journal of organic chemistry (04-03-2016)“…Chemoenzymatic and stereoselective total syntheses of the non-natural enantiomeric forms of the recently isolated protoilludane natural products…”
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9
Total Synthesis of (+)-Viridianol, a Marine-Derived Sesquiterpene Embodying the Decahydrocyclobuta[d]indene Framework
Published in Journal of organic chemistry (16-11-2018)“…A total synthesis of the title sesquiterpene 4 is described that starts with the chiral, non-racemic cis-1,2-dihydrocatechol 10 obtained through the whole-cell…”
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10
Total Syntheses of the 3 H -Pyrrolo[2,3- c ]quinolone-Containing Alkaloids Marinoquinolines A-F, K, and Aplidiopsamine A Using a Palladium-Catalyzed Ullmann Cross-Coupling/Reductive Cyclization Pathway
Published in Journal of organic chemistry (17-01-2020)“…Compounds - and representing key members of the marinoquinoline family of natural products, together with the related marine alkaloid aplidiopsamine A ( ),…”
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11
Studies on the Photochemical Rearrangements of Enantiomerically Pure, Polysubstituted, and Variously Annulated Bicyclo[2.2.2]octenones
Published in Journal of organic chemistry (04-08-2017)“…A series of enantiomerically pure bicyclo[2.2.2]octenones, including the lactone-annulated system 26, has been prepared by engaging derivatives of an…”
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12
Synthetic Studies on the Marine-Derived Sesquiterpene (+)-Viridianol: Divergent Behaviour of Two Structurally Related, Ring-Fused Cyclopropanes Under the Same Hydrogenolytic Conditions
Published in Critical studies in media communication (01-01-2019)“…Hydrogenolytic cleavage of the ring-fused cyclopropane 11 using hydrogen in the presence of platinum oxide afforded the gem-dimethylated cyclohexane 12 in 99?%…”
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13
Alkyl Ethers as Traceless Hydride Donors in Brønsted Acid Catalyzed Intramolecular Hydrogen Atom Transfer
Published in Angewandte Chemie (22-05-2018)“…A new protocol for the deoxygenation of alcohols and the hydrogenation of alkenes under Brønsted acid catalysis has been developed. The method is based on the…”
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Journal Article