Re(CO)3‑Templated Formation of Aza(dibenzo)dipyrromethenes

The Re(CO)3 unit was used to template the formation of aza(dibenzopyrro)methene (ADBM) in the presence of pyridine or N-methylimidazole. The products of these template reactions are six-coordinate complexes, with a facial arrangement of the carbonyls, a bidentate ADBM, and a sixth ligand (pyridin...

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Bibliographic Details
Published in:	Inorganic chemistry Vol. 55; no. 7; pp. 3209 - 3211
Main Authors:	Crandall, Laura A., Bogdanowicz, Catherine A., Hasheminasab, Abed, Chanawanno, Kullapa, Herrick, Richard S., Ziegler, Christopher J.
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 04-04-2016
Online Access:	Get full text
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Summary:	The Re(CO)3 unit was used to template the formation of aza(dibenzopyrro)methene (ADBM) in the presence of pyridine or N-methylimidazole. The products of these template reactions are six-coordinate complexes, with a facial arrangement of the carbonyls, a bidentate ADBM, and a sixth ligand (pyridine or N-methylimiadozle). Three types of ADBM ligands are produced from these reactions, depending on the degree of hydrolysis; bis(imine)-terminated, bis(oxo)-terminated, and mixed-imine/oxo chelates were formed.
Bibliography:	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	0020-1669 1520-510X
DOI:	10.1021/acs.inorgchem.5b02934