Search Results - "Boganov, S. E."

Dichlorosilylene–hydrogen chloride complex: direct IR spectroscopic detection in argon matrix by Boganov, S. E., Promyslov, V. M., Egorov, M. P.

“…A 1: 1 donor–acceptor complex between SiCl 2 and HCl was detected by matrix IR spectroscopy. The existence of the complex was previously predicted…”
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Nonclassical complex of dichlorosilylene with CO: direct spectroscopic detection by Boganov, S. E., Promyslov, V. M., Lalov, A. V., Syroeshkin, M. A., Egorov, M. P.

“…A complex between SiCl 2 and CO of the 1:1 composition with coordination of the silylene to the C atom of carbon monoxide is detected in Ar matrices using FTIR…”
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Current trends in organic chemistry: contribution of the N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences by Egorov, M. P., Ananikov, V. P., Baskir, E. G., Boganov, S. E., Bogdan, V. I., Vereshchagin, A. N., Vil’, V. A., Dalinger, I. L., Dilman, A. D., Eliseev, O. L., Zlotin, S. G., Knyazeva, E. A., Kogan, V. M., Kononov, L. O., Krayushkin, M. M., Krylov, V. B., Kustov, L. M., Levin, V. V., Lichitsky, B. V., Medvedev, M. G., Nifantiev, N. E., Rakitin, O. A., Sakharov, A. M., Svitanko, I. V., Smirnov, G. A., Stakheev, A. Yu, Syroeshkin, M. A., Terent’ev, A. O., Tomilov, Yu. V., Tretyakov, E. V., Trushkov, I. V., Fershtat, L. L., Chaliy, V. A., Shirinian, V. Z.

“…A key goal of organic chemistry is to develop new principles for the control of reactions, which can be used to create promising materials demanded in all…”
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Complexes of dichlorosilylene with allyl chloride and allyl bromide: matrix IR spectroscopy and quantum chemical studies by Boganov, S. E., Promyslov, V. M., Rynin, S. S., Krylova, I. V., Zaitseva, G. S., Egorov, M. P.

“…Formation of donor-acceptor complexes between dichlorosilylene, SiCl 2 , and allyl halides, AllHal(Hal= Cl, Br) was detected in Ar matrixes using matrix IR…”
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Gas phase kinetic and theoretical studies of reactions of germylenes and dimethylstannylene by Boganov, S. E., Egorov, M. P., Faustov, V. I., Krylov, I. V., Nefedov, O. M., Becerra, R., Walsh, R.

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Mechanism of thermal decomposition of allyltrichlorosilane with formation of three labile intermediates: dichlorosilylene, allyl radical, and atomic chlorine by Boganov, S. E., Promyslov, V. M., Krylova, I. V., Zaitseva, G. S., Egorov, M. P.

“…It is experimentally found that allyltrichlorosilane dissociates under vacuum pyrolysis (~10 –2 Torr) at temperatures above 1100 K to form three labile…”
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The electronic structure of 5-methylhexa-1,2,4-triene-1,3-diyl, the first representative of highly delocalized triplet ethynylvinylcarbenes, from ESR spectroscopy data and quantum chemical calculations by Misochko, E. Ya, Akimov, A. V., Masitov, A. A., Korchagin, D. V., Aldoshin, S. M., Boganov, S. E., Shavrin, K. N., Gvozdev, V. D., Egorov, M. P., Nefedov, O. M.

“…The ESR spectrum of the first representative of highly conjugated triplet ethynylvinylcarbenes, 5-methylhexa-1,2,4-triene-1,3-diyl ( 1 ), was recorded in solid…”
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Direct detection of chlorosilylene and time resolved study of some of its reactions in the gas-phase using a new photochemical precursor by Becerra, R., Boganov, S.E., Egorov, M.P., Krylova, I.V., Nefedov, O.M., Walsh, R.

“…Chlorosilylene, ClSiH, was prepared by 193 nm laser flash photolysis of 1-chloro-1-silacyclopent-3-ene in the gas phase. ClSiH was monitored in real time at…”
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Complexes of carbene analogs with Lewis bases: matrix IR spectroscopy and quantum-chemical studies by Boganov, S. E., Faustov, V. I., Egorov, M. P., Nefedov, O. M.

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Room temperature observation of GeH2 and the first time-resolved study of some of its reactions by Becerra, R., Boganov, S.E., Egorov, M.P., Nefedov, O.M., Walsh, R.

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Matrix isolation of silacyclopentadienes : UV-vis and IR spectra and photochemical interconversion by KHABASHESKU, V. N, BALAJI, V, BOGANOV, S. E, NEFEDOV, O. M, MICHL, J

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First gas-phase detection of dimethylgermylene and time-resolved study of some of its reactions by Becerra, R., Boganov, S.E., Egorov, M.P., Lee, V.Ya, Nefedov, O.M., Walsh, R.

“…Using a laser flash photolysis/laser probe technique, applied to two different gaseous precursor molecules, we report absorption signals in the wavelength…”
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The low-temperature matrix stabilization and IR spectrum of dimethylgermanone, Me2Ge=O by Khabashesku, V. N., Boganov, S. E., Nefedov, O. M.

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Intramolecular stabilization of the silylene center due to the donor-acceptor interaction with a valence-unbonded nitrogen atom. A theoretical consideration by Rynin, S. S., Boganov, S. E., Karlov, S. S., Egorov, M. P.

“…The structure and thermochemistry of typical reactions of cyclic silylenes, 2,5,8-trimethyl-1-sila-2,5,8-triazacycloocta-3,6-dien-1-ylidene and…”
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Quantum chemical study of σ-dimerization reaction of 1-silacycloprop-2-enes by Boganov, S. E., Promyslov, V. M., Baskir, E. G., Egorov, M. P., Nefedov, O. M.

“…The PBE/TZ2P method was used to study a concerted σ-dimerization reaction of 1-silacycloprop-2-enes having substituents with different electron effects. The…”
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Study of complexation between difluorostannylene and aromatics by matrix IR spectroscopy by Boganov, S. E., Egorov, M. P., Nefedov, O. M.

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Computational study of reaction pathways in the course of interaction of deactivated silylenes with buta-1,3-diene by Rynin, S.S., Faustov, V.I., Boganov, S.E., Egorov, M.P., Nefedov, O.M.

“…The PESs of systems including deactivated silylenes (SiHHal, SiHal 2, Hal = F, Cl, and 2-silaimidazol-2-ylidene, SiN 2H 2C 2H 2) and buta-1,3-diene have been…”
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Matrix IR-spectroscopic and quantum-chemical study of difluorostannylene complexation with dinitrogen by Boganov, S. E., Faustov, V. I., Egorov, M. P., Nefedov, O. M.

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Interconversions of the silylene-to-silene and germylene-to-germene types: direct spectroscopic studies and calculations by Khabashesku, V. N., Boganov, S. E., Kudin, K. N., Margrave, J. L., Michl, J., Nefedov, O. M.

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Quantum chemical study of interactions of carbenes and their analogs of the EH2 and EHX types (E = Si, Ge, Sn; X = F, Cl, Br) with HX and H2, respectively: the insertion and substituent exchange reactions by Boganov, S. E., Promyslov, V. M., Faustov, V. I., Egorov, M. P., Nefedov, O. M.

“…Interactions of carbenes and carbene analogs EH 2 and EHX with HX and H 2 (E = C, Si, Ge, Sn; X = F, Cl, Br), respectively, were studied by quantum chemical…”
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