Search Results - "Blitz, Mark"
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1
Accelerated chemistry in the reaction between the hydroxyl radical and methanol at interstellar temperatures facilitated by tunnelling
Published in Nature chemistry (01-09-2013)“…Understanding the abundances of molecules in dense interstellar clouds requires knowledge of the rates of gas-phase reactions between uncharged species…”
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2
Solving the OH + Glyoxal Problem: A Complete Theoretical Description of Post-Transition-State Energy Deposition in Activated Systems
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (29-02-2024)“…Activated chemistry in coupled reaction systems has broadened our understanding of the chemical kinetics. In the case of intermediates formed in gas phase…”
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3
A gas-to-particle conversion mechanism helps to explain atmospheric particle formation through clustering of iodine oxides
Published in Nature communications (09-09-2020)“…Emitted from the oceans, iodine-bearing molecules are ubiquitous in the atmosphere and a source of new atmospheric aerosol particles of potentially global…”
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4
Studies on the Kinetics of the CH + H2 Reaction and Implications for the Reverse Reaction, 3CH2 + H
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (16-03-2023)“…The reaction of CH radicals with H2 has been studied by the use of laser flash photolysis, probing CH decays under pseudo-first-order conditions using…”
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5
HO2 + NO2: Kinetics, Thermochemistry, and Evidence for a Bimolecular Product Channel
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (20-10-2022)“…A master equation (ME) analysis of available experimental data has been carried out on the reaction HO2 + NO2 + M ⇋ HO2NO2 + M (1a)/(−1a). The analysis, based…”
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6
Studies on the Kinetics of the CH + H 2 Reaction and Implications for the Reverse Reaction, 3 CH 2 + H
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (16-03-2023)“…The reaction of CH radicals with H has been studied by the use of laser flash photolysis, probing CH decays under pseudo-first-order conditions using…”
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7
Kinetics of the Gas-Phase Reactions of syn- and anti-CH3CHOO Criegee Intermediate Conformers with SO2 as a Function of Temperature and Pressure
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (11-04-2024)“…Kinetics of reactions between SO2 and CH3CHOO Criegee intermediate conformers have been measured at temperatures between 242 and 353 K and pressures between 10…”
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8
Kinetics of the Gas-Phase Reactions of syn - and anti -CH 3 CHOO Criegee Intermediate Conformers with SO 2 as a Function of Temperature and Pressure
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (11-04-2024)“…Kinetics of reactions between SO and CH CHOO Criegee intermediate conformers have been measured at temperatures between 242 and 353 K and pressures between 10…”
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9
Structure-switching M3L2 Ir(iii) coordination cages with photo-isomerising azo-aromatic linkers (Data accessibility: data are available at https://doi.org/10.5518/438)
Published in Chemical science (Cambridge) (14-11-2018)“…Cyclotriguaiacylene has been functionalised with 3- or 4-pyridyl-azo-phenyl groups to form a series of molecular hosts with three azobenzene-type groups that…”
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10
Experimental and Theoretical Investigation of the Reaction of NH2 with NO at Very Low Temperatures
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (31-08-2023)“…The first experimental study of the low-temperature kinetics of the gas-phase reaction between NH2 and NO has been performed. A pulsed laser…”
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11
Experimental and Theoretical Investigation of the Reaction of NH 2 with NO at Very Low Temperatures
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (31-08-2023)“…The first experimental study of the low-temperature kinetics of the gas-phase reaction between NH and NO has been performed. A pulsed laser…”
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12
Unimolecular Kinetics of Stabilized CH3CHOO Criegee Intermediates: syn-CH3CHOO Decomposition and anti-CH3CHOO Isomerization
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (06-10-2022)“…The kinetics of the unimolecular decomposition of the stabilized Criegee intermediate syn-CH3CHOO has been investigated at temperatures between 297 and 331 K…”
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13
The Gas-phase Reaction of NH2 with Formaldehyde (CH2O) is not a Source of Formamide (NH2CHO) in Interstellar Environments
Published in Astrophysical journal. Letters (01-09-2022)“…The first experimental study of the low-temperature kinetics of the gas-phase reaction of NH2 with formaldehyde (CH2O) has been performed. This reaction has…”
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14
Laser Photolysis Kinetic Study of OH Radical Reactions with Methyl tert-Butyl Ether and Trimethyl Orthoformate under Conditions Relevant to Low Temperature Combustion: Measurements of Rate Coefficients and OH Recycling
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (20-12-2018)“…Methyl tertiary butyl ether (MTBE) and trimethyl orthoformate (TMOF) are potential biofuel ethers and could replace conventional fossil fuels, or act as…”
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Kinetics of the Reactions of Hydroxyl Radicals with Furan and Its Alkylated Derivatives 2‑Methyl Furan and 2,5-Dimethyl Furan
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (17-09-2020)“…Furans are promising second generation biofuels with comparable energy densities to conventional fossil fuels. Combustion of furans is initiated and controlled…”
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16
Ab Initio and Statistical Rate Theory Exploration of the CH (X2Π) + OCS Gas-Phase Reaction
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (10-08-2023)“…The first theoretical results regarding the gas-phase reaction mechanism and kinetics of the CH (X2Π) + OCS reaction are presented here. This reaction has a…”
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17
OH Kinetics with a Range of Nitrogen-Containing Compounds: N‑Methylformamide, t‑Butylamine, and N‑Methyl-propane Diamine
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (09-12-2021)“…Emissions of amines and amides to the atmosphere are significant from both anthropogenic and natural sources, and amides can be formed as secondary pollutants…”
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18
Measurements of Low Temperature Rate Coefficients for the Reaction of CH with CH2O and Application to Dark Cloud and AGB Stellar Wind Models
Published in The Astrophysical journal (10-11-2019)“…Rate coefficients have been measured for the reaction of CH radicals with formaldehyde, CH2O, over the temperature range of 31-133 K using a pulsed Laval…”
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19
Measurements of Rate Coefficients for Reactions of OH with Ethanol and Propan-2-ol at Very Low Temperatures
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (16-07-2015)“…The low temperature kinetics of the reactions of OH with ethanol and propan-2-ol have been studied using a pulsed Laval nozzle apparatus coupled with pulsed…”
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20
Determination of the absorption cross sections of higher-order iodine oxides at 355 and 532 nm
Published in Atmospheric chemistry and physics (18-09-2020)“…Iodine oxides (IxOy) play an important role in the atmospheric chemistry of iodine. They are initiators of new particle formation events in the coastal and…”
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