Search Results - "Blaakmeer, E.S."
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Preactive Site in Ziegler–Natta Catalysts
Published in Journal of physical chemistry. C (13-06-2019)“…Ziegler–Natta catalysts are one of the most important industrial catalysts for the production of isotactic polypropylene, yet they are still not properly…”
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Probing Interactions between Electron Donors and the Support in MgCl2‑Supported Ziegler–Natta Catalysts
Published in Journal of physical chemistry. C (09-08-2018)“…Olefin polymerization using Ziegler–Natta catalysts (ZNCs) is an important industrial process. Despite this, fundamental insight into the inner working…”
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Solid-State NMR Investigations of MgCl2 Catalyst Support
Published in Journal of physical chemistry. C (24-03-2016)“…MgCl2 is a vital component of Ziegler–Natta catalysts for olefin polymerization. Here we synthesized anhydrous MgCl2 using different drying protocols and…”
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Satellite nutation of half integer quadrupolar nuclei: Theory and practice
Published in Journal of magnetic resonance (1997) (01-03-2019)“…[Display omitted] •Nutation profiles of satellite transitions are analysed for I = 3/2, 5/2, 7/2, 9/2.•An in-depth theoretical background of the 2D nutation…”
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Quadrupolar nutation NMR to discriminate central and satellite transitions: Spectral assignments for a Ziegler-Natta catalyst
Published in Journal of magnetic resonance (1997) (01-08-2017)“…[Display omitted] •We present a novel application of nutation NMR.•The spectral nutation profile of satellite transitions (STs) is analysed in detail.•STs of…”
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Solid-state NMR studies of Ziegler–Natta and metallocene catalysts
Published in Solid state nuclear magnetic resonance (01-06-2015)“…Ziegler–Natta catalysts are the workhorses of polyolefin production. However, although they have been used and intensively studied for half a century, there is…”
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