Search Results - "Bitterwolf, Thomas E."

Photochemistry of the Permanganate Ion in Low-Temperature Frozen Matrices by Thornley, Wyatt A, Bitterwolf, Thomas E

“…Photolysis of the permanganate anion, MnO4 –, in tetralkylammonium tetrafluoroborate matrices at 85 K results in formation of a single product, the metastable…”
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Intramolecular CH Activation and Metallacycle Aromaticity in the Photochemistry of [FeFe]-Hydrogenase Model Compounds in Low-Temperature Frozen Matrices by Thornley, Wyatt A., Bitterwolf, Thomas E.

“…The [FeFe]‐hydrogenase model complexes [(μ‐pdt){Fe(CO)3}2], [(μ‐edt){Fe(CO)3}2], and [(μ‐mdt){Fe(CO)3}2], where pdt=1,3‐propanedithiolate,…”
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8-Aminoquinoline Functionalized Silica Nanoparticles: A Fluorescent Nanosensor for Detection of Divalent Zinc in Aqueous and in Yeast Cell Suspension by Rastogi, Shiva K, Pal, Parul, Aston, D. Eric, Bitterwolf, Thomas E, Branen, A. Larry

“…Zinc is one of the most important transition metal of physiological importance, existing primarily as a divalent cation. A number of sensors have been…”
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Photodynamics of [FeFe]-Hydrogenase Model Compounds with Bidentate Heterocyclic Ligands by Thornley, Wyatt, Wirick, Sarah A, Riedel-Topper, Maximilian, DeYonker, Nathan J, Bitterwolf, Thomas E, Stromberg, Christopher J, Heilweil, Edwin J

“…Two asymmetrically structured model compounds for the hydrogen-generating [Fe–Fe]-hydrogenase active site were investigated to determine the ultrafast…”
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Photolysis of Isoelectronic Ruthenium Nitrosyl and Diazonium Complexes in Frozen PVC Matrices: Retention of Dinitrogen on Ruthenium Following Photochemical Phenyl Radical Loss by Thornley, Wyatt A., Bitterwolf, Thomas E.

“…Photolysis of RuCl3(η1‐NO)(PPh3)2 in poly(vinyl chloride) (PVC) matrices at 85 K results in reversible linkage isomerism of the nitrosyl ligand to form the…”
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Photochemically Induced Intramolecular Six-Electron Reductive Elimination and Oxidative Addition of Nitric Oxide by the Nitridoosmate(VIII) Anion by Thornley, Wyatt A., Bitterwolf, Thomas E.

“…UV photolysis of the nitridoosmate(VIII) anion, OsO3N−, in low‐temperature frozen matrices results in nitrogen–oxygen bond formation to give the OsII nitrosyl…”
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Evidence for Photochemical Linkage Isomerism of the Phenylazo Ligand in M(CO)2(N2Ph)(PPh3)2 Cations (M = Fe and Ru) by Thornley, Wyatt A., Bitterwolf, Thomas E.

“…Frozen‐matrix photolysis studies of M(CO)2(N2Ph)(PPh3)2 cations (M = Fe and Ru) have revealed end‐on/side‐on photochemical linkage isomerism of the phenylazo…”
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Fluorescence Sensing of Zinc(II) Using Ordered Mesoporous Silica Material (MCM-41) Functionalized with N-(Quinolin-8-yl)-2-[3-(triethoxysilyl)propylamino]acetamide by Pal, Parul, Rastogi, Shiva K, Gibson, Charlene M, Aston, D. Eric, Branen, A. Larry, Bitterwolf, Thomas E

“…A novel fluorescent zinc sensor was designed and synthesized on ordered mesoporous silica material, MCM-41, with…”
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A mechanistic study of the low-temperature conversion of carbon monoxide to carbon dioxide over a cobalt oxide catalyst by Pollard, Matthew J., Weinstock, B. André, Bitterwolf, Thomas E., Griffiths, Peter R., Piers Newbery, A., Paine, John B.

“…A nanocrystalline cobalt oxide (Co 3O 4)-based catalyst formed by heating a basic cobalt(II) carbonate precursor in air at 250–300 °C has been shown to exhibit…”
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Multivariate Analysis of Micro-Raman Spectra of Thermoplastic Polyurethane Blends Using Principal Component Analysis and Principal Component Regression by Weakley, Andrew Todd, Warwick, P.C. Temple, Bitterwolf, Thomas E., Aston, D. Eric

“…Probing the specific hydrogen-bonding behavior of thermoplastic poly-urethane (TPU) blends using vibrational spectroscopies remains the sin qua non for…”
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Role of a Metal–Metal Bonded Dimer Dication in the One-Electron Oxidation of Rh(η5‑C5H5)(CO)(PPh3) and Related Compounds by Trupia, Sabrina, Bitterwolf, Thomas E, Geiger, William E

“…The anodic oxidation mechanism of RhCp­(CO)­(PPh3), 1, has been studied in CH2Cl2/0.1 M [NBu4]­[PF6]. This complex and its analogue RhCp­(PPh3)2 had been…”
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Photochemistry and reaction intermediates of the bimetallic Group VIII cyclopentadienyl metal carbonyl compounds, (η5-C5H5)2M2(CO)4 and their derivatives by Bitterwolf, Thomas E

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X-ray photoelectron spectroscopic analysis of the surface chemistry of silica nanowires by Beaux, Miles F., Bridges, Nathan J., DeHart, Morgan, Bitterwolf, Thomas E., McIlroy, David N.

“…► Silica nanowires are capable of very high surface hydroxyl concentrations. ► Surface hydroxyl concentration corresponds to the pH of aqueous storage media. ►…”
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Photochemical Carbonylation of Ethane under Supercritical Conditions by Bitterwolf, Thomas E., Lukmanova Kline, Dinara, Linehan, John C., Yonker, Clement R., Addleman, R. Shane

“…Feasible photocatalysis: The rhodium catalyst [Rh(CO)(PMe3)2Cl] photochemically transforms ethane to propionaldehyde in single‐phase mixtures of ethane and in…”
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Mechanisms and intermediates in the photochemistry of M2(CO)6(η5-C5H5)2, where M=Cr, Mo and W, and their ring-coupled analogs by Bitterwolf, Thomas E

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Interplay among Tetrahedrane, Butterfly Diradical, and Planar Rhombus Structures in the Chemistry of the Binuclear Iron Carbonyl Phosphinidene Complexes Fe2(CO)6(PX)2 by Silaghi-Dumitrescu, Ioan, Bitterwolf, Thomas E, King, R. Bruce

“…Density functional theory studies on a series of Fe2(CO)6(PX)2 derivatives show the tetrahedrane to be the most stable for the alkyl (X = Me, t Bu), P−H (X =…”
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Activation of the S-H group in Fe(mu(2)-SH)Fe clusters: S-H bond strengths and free radical reactivity of the Fe(mu(2)-SH)Fe cluster by Franz, James A, Lee, Suh-Jane, Bowden, Thomas A, Alnajjar, Mikhail S, Appel, Aaron M, Birnbaum, Jerome C, Bitterwolf, Thomas E, Dupuis, Michel

“…Absolute rate constants were determined for the abstraction of hydrogen atoms from (OC)(3)Fe(mu-SH)(2)Fe(CO)(3) (Fe(2)S(2)H(2)) and…”
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Photochemically Induced Intramolecular Six-Electron Reductive Elimination and Oxidative Addition of Nitric Oxide by the Nitridoosmate(VIII) Anion by Thornley, Wyatt A., Bitterwolf, Thomas E.

“…UV photolysis of the nitridoosmate(VIII) anion, OsO3N−, in low‐temperature frozen matrices results in nitrogen–oxygen bond formation to give the OsII nitrosyl…”
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Activation of the S−H Group in Fe(μ2-SH)Fe Clusters: S−H Bond Strengths and Free Radical Reactivity of the Fe(μ2-SH)Fe Cluster by Franz, James A, Lee, Suh-Jane, Bowden, Thomas A, Alnajjar, Mikhail S, Appel, Aaron M, Birnbaum, Jerome C, Bitterwolf, Thomas E, Dupuis, Michel

“…Absolute rate constants were determined for the abstraction of hydrogen atoms from (OC)3Fe(μ-SH)2Fe(CO)3 (Fe 2 S 2 H 2 ) and (OC)3Fe(μ-SCH3)(μ-SH)Fe(CO)3 (Fe 2…”
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Stopped-Flow Ultra-Rapid-Scanning Fourier Transform Infrared Spectroscopy on the Millisecond Time Scale by Reback, Matthew L., Roske, Christopher W., Bitterwolf, Thomas E., Griffiths, Peter R., Manning, Christopher J.

“…Full-range mid-infrared spectra were measured during the reaction of CpCo(CO)2 with nitrosyl chloride by interfacing a rapid-mixing stopped-flow device with an…”
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