Alginate-modified surfactants functionalized metal-organic framework-based fluorescent film sensors for detection and adsorption of volatile aldehydes in water
Volatile aldehydes have an adverse impact on both human health and the environment, therefore, a fast, straightforward, highly accurate detection technique for the simultaneous detection and removal of several aldehydes is eagerly anticipated. Herein, novel APGF@ZIF-8 and APOF@ZIF-8 sensing material...
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| Published in: | International journal of biological macromolecules Vol. 259; p. 129080 |
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| Main Authors: | , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
Netherlands
Elsevier B.V
01-02-2024
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| Subjects: | |
| Online Access: | Get full text |
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| Summary: | Volatile aldehydes have an adverse impact on both human health and the environment, therefore, a fast, straightforward, highly accurate detection technique for the simultaneous detection and removal of several aldehydes is eagerly anticipated. Herein, novel APGF@ZIF-8 and APOF@ZIF-8 sensing materials were developed by coating fluorescent alginate-modified surfactants (APGF and APOF) into the ZIF-8 MOFs to produce quite porous fluorescent sensors (SBET up to 1519 m2/g). The detection capacity of the prepared sensors for benzaldehyde, glyoxal, formaldehyde, and acetaldehyde has been examined. The detection mechanism was suggested as hydrogen bonding formation between the sensors and volatile aldehydes as confirmed by Gaussian calculations. All the fluorescence spectra of aldehydes display remarkable linear detection relationships in the range of 0.05–200 μM with the limits of detection (LOD) values in the range of 0.001–0.18 μM (0.106–10.44 ppb). These sensors were utilized successfully to detect multiple volatile aldehydes in river water samples with satisfactory recoveries of 96–107 %. Interestingly, fluorescent APGF@ZIF-8/CS and APOF@ZIF-8/CS films as portable disposable removal techniques for benzaldehyde, glyoxal, formaldehyde, and acetaldehyde from water were fabricated. APOF@ZIF-8/CS exhibited an excellent formaldehyde adsorption capacity of 58.30 mg/g and an adsorption removal efficiency of 93.5 %. The adsorption process of biosorbent on various aldehydes was fitted by Freundlich adsorption isotherm. The adsorption kinetics followed Pseudo-second-order kinetic model.
•Dual-functional sensors were designed for sensing and removing aldehydes in water.•The alginate@ZIF-8 can detect 0.106 ppb level of aldehydes within 5 min.•The adsorption capacity was 58.30 mg/g and removal ratio of 93.5 %.•Sensing and removal was due to the hydrogen bonding interactions. |
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| Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ISSN: | 0141-8130 1879-0003 |
| DOI: | 10.1016/j.ijbiomac.2023.129080 |