Search Results - "Birjkumar, Krishna Hassomal"
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A Stable Two-Coordinate Acyclic Silylene
Published in Journal of the American Chemical Society (18-04-2012)“…Simple two-coordinate acyclic silylenes, SiR2, have hitherto been identified only as transient intermediates or thermally labile species. By making use of the…”
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Stable GaX2, InX2 and TlX2 radicals
Published in Nature chemistry (01-04-2014)“…The chemistry of the Group 13 metals is dominated by the +1 and +3 oxidation states, and simple monomeric M (II) species are typically short-lived, highly…”
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Group 3 and Lanthanide Boryl Compounds: Syntheses, Structures, and Bonding Analyses of Sc−B, Y−B, and Lu−B σ-Coordinated NHC Analogues
Published in Journal of the American Chemical Society (23-03-2011)“…Reaction of [Ln(CH2SiMe3)2(THF) n ][BPh4] (Ln = Sc, Y, Lu ; n = 3, 4) with Li{B(NArCH)2}(THF)2 (Ar = 2,6-C6H3 iPr2) formed the first group 3 and lanthanide…”
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