Microwave assisted co-operative dynamics and structural variations in chlorobenzene-acetonitrile solutions

Molecular interactions between CBZ-ACN at 8.845 GHz of microwave frequency region confer structural behavior of molecules such that either monomers or multimers are present in the agreed binary mixtures. Effect of microwave frequency on molecular interactions and hydrogen bonding between C≡N (nitril...

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Bibliographic Details
Published in:Bangladesh journal of scientific and industrial research Vol. 57; no. 2; pp. 85 - 90
Main Authors: Birajdar, SS, Gaikwad, JW, Suryawanshi, DB
Format: Journal Article
Language:English
Published: 26-06-2022
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Summary:Molecular interactions between CBZ-ACN at 8.845 GHz of microwave frequency region confer structural behavior of molecules such that either monomers or multimers are present in the agreed binary mixtures. Effect of microwave frequency on molecular interactions and hydrogen bonding between C≡N (nitrile) molecule and Cl (chlorine) molecule of CBZ and ACN binary solutions has been studied using X-band microwave technique at 301ºK. Co-operative dynamics and hydrogen bonding between nitrile and chlorine group molecules has been thoroughly explicated thereby obtaining static dielectric constant, excess permittivity, Kirkwood correlation factor using Luzar model and Bruggeman factor. Bangladesh J. Sci. Ind. Res. 57(2), 85-90, 2022
ISSN:0304-9809
2224-7157
DOI:10.3329/bjsir.v57i2.60404