Search Results - "Bielawski, Christopher W"
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Surface Modification of Water Purification Membranes
Published in Angewandte Chemie International Edition (18-04-2017)“…Polymeric membranes are an energy‐efficient means of purifying water, but they suffer from fouling during filtration. Modification of the membrane surface is…”
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From Conception to Realization: An Historial Account of Graphene and Some Perspectives for Its Future
Published in Angewandte Chemie International Edition (03-12-2010)“…There has been an intense surge in interest in graphene during recent years. However, graphene‐like materials derived from graphite oxide were reported in…”
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A eutectic mixture of galactitol and mannitol as a phase change material for latent heat storage
Published in Energy conversion and management (01-10-2015)“…Cyclic stability of the eutectic mixture of galactitol and D-mannitol. [Display omitted] •A eutectic mixture of galactitol/mannitol was studied as a phase…”
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Photoswitchable Organocatalysis: Using Light To Modulate the Catalytic Activities of N‑Heterocyclic Carbenes
Published in Journal of the American Chemical Society (01-08-2012)“…A 4,5-dithienylimidazolium salt was found to undergo electrocyclic isomerization upon exposure to UV radiation (λ irr = 313 nm) under neutral and basic…”
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Elucidating the Structure of Poly(dopamine)
Published in Langmuir (17-04-2012)“…Herein we propose a new structure for poly(dopamine), a synthetic eumelanin that has found broad utility as an antifouling agent. Commercially available…”
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Methods for activating and characterizing mechanically responsive polymers
Published in Chemical Society reviews (01-01-2013)“…Mechanically responsive polymers harness mechanical energy to facilitate unique chemical transformations and bestow materials with force sensing (e.g.,…”
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High-Performance Supercapacitors Based on Poly(ionic liquid)-Modified Graphene Electrodes
Published in ACS nano (25-01-2011)“…We report a high-performance supercapacitor incorporating a poly(ionic liquid)-modified reduced graphene oxide (PIL:RG-O) electrode and an ionic liquid (IL)…”
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Real-Time, in Situ Monitoring of the Oxidation of Graphite: Lessons Learned
Published in Chemistry of materials (14-03-2017)“…Graphite oxide (GO) and its constituent layers (i.e., graphene oxide) display a broad range of functional groups and, as such, have attracted significant…”
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Photoswitchable Metal-Mediated Catalysis: Remotely Tuned Alkene and Alkyne Hydroborations
Published in Organometallics (24-05-2013)“…A photochromic dithienylethene-annulated N-heterocyclic carbene (NHC)–Rh(I) complex was synthesized and found to undergo reversible electrocyclic ring closure…”
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10
Molecular Recognition of Methionine-Terminated Peptides by Cucurbit[8]uril
Published in Journal of the American Chemical Society (26-09-2018)“…This Article describes the molecular recognition of peptides containing an N-terminal methionine (Met) by the synthetic receptor cucurbit[8]uril (Q8) in…”
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Graphite oxide: a selective and highly efficient oxidant of thiols and sulfides
Published in Organic & biomolecular chemistry (07-11-2011)“…The selective oxidation of thiols to disulfides and sulfides to sulfoxides using graphite oxide (GO), a heterogeneous carbocatalyst obtained from low cost,…”
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Controlled Catalyst Transfer Polycondensation and Surface-Initiated Polymerization of a p‑Phenyleneethynylene-Based Monomer
Published in Journal of the American Chemical Society (03-04-2013)“…Herein, we describe a catalyst transfer polycondensation that enabled access to well-defined poly(p-phenyleneethynylene) (PPE), a prominent conjugated polymer…”
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A Photoswitchable Olefin Metathesis Catalyst
Published in Organometallics (23-01-2017)“…A dithienylethene-functionalized N-heterocyclic carbene-Ru(II) complex was synthesized and found to undergo a reversible photoisomerization which influenced…”
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Polymer Brushes via Controlled, Surface-Initiated Atom Transfer Radical Polymerization (ATRP) from Graphene Oxide
Published in Macromolecular rapid communications. (02-02-2010)“…A method for growing polymers directly from the surface of graphene oxide is demonstrated. The technique involves the covalent attachment of an initiator…”
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Graphite Oxide as an Auto-Tandem Oxidation-Hydration-Aldol Coupling Catalyst
Published in Advanced synthesis & catalysis (07-03-2011)“…Graphite oxide (GO) was found to function as an auto‐tandem oxidation–hydration–aldol coupling catalyst for the formation of chalcones in a single reaction…”
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Tuning the Electronic Properties of Carbenes: A Systematic Comparison of Neighboring Amino versus Amido Groups
Published in Organometallics (23-04-2012)“…A related series of six-membered carbenes featuring adjoining amino and/or amido groups (i.e, a diaminocarbene, a monoamido-aminocarbene (3), and a a…”
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Computational Investigations of the Effects of N-Heterocyclic Carbene Ligands on the Mechanism, Reactivity, and Regioselectivity of Rh-Catalyzed Hydroborations
Published in ACS catalysis (20-03-2020)“…Density functional theory calculations were performed to study the effects of N-heterocyclic carbene (NHC) ligands on the Rh-catalyzed hydroboration of styrene…”
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Arrested Catalysis: Controlling Kumada Coupling Activity via a Redox-Active N-Heterocyclic Carbene
Published in Journal of the American Chemical Society (14-07-2010)“…Optimized syntheses for 1,3-dimesitylnaphthoquinimidazolium chloride [1H][Cl] and the corresponding silver−NHC complex [AgCl(1)] (2) were developed, enabling…”
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Molecular Catch Bonds and the Anti-Hammond Effect in Polymer Mechanochemistry
Published in Journal of the American Chemical Society (28-08-2013)“…While the field of polymer mechanochemistry has traditionally focused on the use of mechanical forces to accelerate chemical processes, theoretical…”
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Polymer mechanochemistry: the design and study of mechanophores
Published in Polymer international (01-01-2013)“…The burgeoning field of polymer mechanochemistry has garnered significant interest in recent years. Mechanochemical transformations are those that are promoted…”
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