Search Results - "Beyer, Martin K"
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Mechanochemistry: The Mechanical Activation of Covalent Bonds
Published in Chemical reviews (01-08-2005)“…Beyer and Clausen-Schaumann give a survey of the classical works in mechanochemistry. Beyer and Clausen-Schaumann put the key mechanochemical phenomena into…”
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2
Hydrated metal ions in the gas phase
Published in Mass spectrometry reviews (01-07-2007)“…Studying metal ion solvation, especially hydration, in the gas phase has developed into a field that is dominated by a tight interaction between experiment and…”
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Carbon Dioxide Activation at Metal Centers: Evolution of Charge Transfer from Mg .+ to CO2 in [MgCO2(H2O)n].+, n=0–8
Published in Angewandte Chemie International Edition (04-05-2020)“…We investigate activation of carbon dioxide by singly charged hydrated magnesium cations Mg .+(H2O)n, through infrared multiple photon dissociation (IRMPD)…”
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Activation of Methane by Oligomeric (Al₂O₃)x⁺ (x=3,4,5): The Role of Oxygen-Centered Radicals in Thermal Hydrogen-Atom Abstraction
Published in Angewandte Chemie (International ed.) (22-02-2008)“…A matter of radical sites and bond energies: Experimental and theoretical studies show that the cationic polynuclear aluminum oxide clusters, which are…”
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Mechanical Activation Drastically Accelerates Amide Bond Hydrolysis, Matching Enzyme Activity
Published in Angewandte Chemie International Edition (15-07-2019)“…Amide bonds, which include peptide bonds connecting amino acids in proteins and polypeptides, give proteins and synthetic polyamides their enormous strength…”
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Diatomic [CuO]+ and Its Role in the Spin-Selective Hydrogen- and Oxygen-Atom Transfers in the Thermal Activation of Methane
Published in Angewandte Chemie International Edition (16-05-2011)“…The final piece in an intriguing puzzle: More than ten years after its theoretical prediction to serve as a powerful converter of methane to methanol, the bare…”
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Activation of a Copper Biscarbene Mechano‐Catalyst Using Single‐Molecule Force Spectroscopy Supported by Quantum Chemical Calculations
Published in Chemistry : a European journal (16-06-2021)“…Single‐molecule force spectroscopy allows investigation of the effect of mechanical force on individual bonds. By determining the forces necessary to…”
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Asymmetric Solvation of the Zinc Dimer Cation Revealed by Infrared Multiple Photon Dissociation Spectroscopy of Zn2+(H2O)n (n = 1–20)
Published in International journal of molecular sciences (02-06-2021)“…Investigating metal-ion solvation—in particular, the fundamental binding interactions—enhances the understanding of many processes, including hydrogen…”
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9
Dynamic Strength of the Silicon−Carbon Bond Observed over Three Decades of Force-Loading Rates
Published in Journal of the American Chemical Society (19-03-2008)“…The mechanical strength of individual Si−C bonds was determined as a function of the applied force-loading rate by dynamic single-molecule force spectroscopy,…”
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10
Decomposition of Copper Formate Clusters: Insight into Elementary Steps of Calcination and Carbon Dioxide Activation
Published in ChemistryOpen (Weinheim) (01-12-2019)“…The decomposition of copper formate clusters is investigated in the gas phase by infrared multiple photon dissociation of Cu(II)n(HCO2)2n+1−, n≤8. In…”
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Collisional Activation of N2O Decomposition and CO Oxidation Reactions on Isolated Rhodium Clusters
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (12-09-2013)“…The reactions of nitrous oxide decorated rhodium clusters, Rh n N2O+ (n = 5, 6), have been studied by Fourier transform ion cyclotron resonance mass…”
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12
Theoretical simulation of the infrared signature of mechanically stressed polymer solids
Published in Beilstein journal of organic chemistry (17-08-2017)“…Mechanical stress leads to deformation of strands in polymer solids, including elongation of covalent bonds and widening of bond angles, which changes the…”
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13
Multiconfigurational Character of Repulsive A 2 Σ g + State Leaves Strong Signature in the Photodissociation Spectrum of Zn 2
Published in Journal of the American Chemical Society (19-06-2024)“…For the excitation to a repulsive state of a diatomic molecule, one expects a single broad peak in the photodissociation spectrum. For Zn , however, two peaks…”
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Gas-Phase Ion Chemistry of Small Gold Cluster Anions
Published in Organometallics (12-07-2010)“…The reactivity of small anionic gold clusters (Au n −, n = 1−4) toward small organic molecules was investigated by Fourier transform ion cyclotron resonance…”
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Multiconfigurational Character of Repulsive A2Σg + State Leaves Strong Signature in the Photodissociation Spectrum of Zn2
Published in Journal of the American Chemical Society (05-06-2024)“…For the excitation to a repulsive state of a diatomic molecule, one expects a single broad peak in the photodissociation spectrum. For Zn2 +, however, two…”
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Simplified Multiple-Well Approach for the Master Equation Modeling of Blackbody Infrared Radiative Dissociation of Hydrated Carbonate Radical Anions
Published in Journal of the American Chemical Society (30-11-2022)“…Blackbody infrared radiative dissociation (BIRD) in a collision-free environment is a powerful method for the experimental determination of bond dissociation…”
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Evidence for Electron Transfer in the Reactions of Hydrated Monovalent First-Row Transition-Metal Ions M(H2O) n +, M = V, Cr, Mn, Fe, Co, Ni, Cu, and Zn, n < 40, toward 1‑Iodopropane
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (21-12-2017)“…Hydrated metal ions in the gas phase serve as model systems to investigate the impact of hydration on the chemistry of monovalent transition-metal centers. As…”
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18
Photodissociation spectroscopy of protonated leucine enkephalin
Published in Physical chemistry chemical physics : PCCP (03-05-2017)“…Protonated leucine enkephalin (YGGFL) was studied by ultraviolet photodissociation (UVPD) from 225 to 300 nm utilizing an optical parametric oscillator tunable…”
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Toward Detection of FeH + in the Interstellar Medium: Infrared Multiple Photon Dissociation Spectroscopy of Ar 2 FeH
Published in The journal of physical chemistry letters (30-06-2022)“…The iron hydride molecular cation FeH is expected to be present in the interstellar medium. Because of the lack of laboratory data, it is yet to be identified…”
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Thermal NH Bond Activation on Anionic and Cationic Platinum Clusters: Non‐Predetermined Reaction Pathways Indicate Transitions to a Bulk Surface Reactivity
Published in Chemistry : a European journal (24-08-2009)“…Reactions of cationic and anionic platinum clusters Ptn+/−, n=1–5, with NH3 are studied by FT‐ICR mass spectrometry and DFT calculations. With cationic…”
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