Search Results - "Bettinger, Holger F"

Pushing the Limits of Acene Chemistry: The Recent Surge of Large Acenes by Tönshoff, Christina, Bettinger, Holger F.

“…Acenes, consisting of linearly fused benzene rings, are an important fundamental class of organic compounds with various applications. Hexacene is the largest…”
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Photogeneration of Octacene and Nonacene by Tönshoff, Christina, Bettinger, Holger F

“…Take it to the limit: Parent acenes larger than heptacene have eluded synthesis for decades. When 1,2‐diketone bridges in suitably designed tetraketone…”
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Evolution of the Optical Gap in the Acene Series: Undecacene by Shen, Bin, Tatchen, Jörg, Sanchez‐Garcia, Elsa, Bettinger, Holger F.

“…Undecacene, the largest member of the acene family, was photogenerated in a polymer matrix under cryogenic conditions from a precursor with two α‐diketone…”
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Boradigermaallyl: (4+3) Cycloaddition‐Initiated Boron Insertion into Benzene by Kern, Ralf H., Schneider, Meike, Eichele, Klaus, Schubert, Hartmut, Bettinger, Holger F., Wesemann, Lars

“…The 2π electron 1,3‐dipole boradigermaallyl, valence‐isoelectronic to an allyl cation, is synthesized from a bis(germylene). It reacts with benzene at room…”
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Heptacene: Characterization in Solution, in the Solid State, and in Films by Einholz, Ralf, Fang, Treliant, Berger, Robert, Grüninger, Peter, Früh, Andreas, Chassé, Thomas, Fink, Reinhold F, Bettinger, Holger F

“…Acenes comprise an important class of organic semiconducting materials. As graphene nanoribbons of ultimate width, they are valuable atom-precise model systems…”
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Construction of an Internally B3N3-Doped Nanographene Molecule by Krieg, Matthias, Reicherter, Florian, Haiss, Peter, Ströbele, Markus, Eichele, Klaus, Treanor, Michael-John, Schaub, Renald, Bettinger, Holger F.

“…The synthesis of a hexa‐peri‐hexabenzocoronene (HBC) with a central borazine core is described. The solid‐state structure of this BN‐doped HBC (BN‐HBC) is…”
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Synthesis, Stability, and Photochemistry of Pentacene, Hexacene, and Heptacene: A Matrix Isolation Study by Mondal, Rajib, Tönshoff, Christina, Khon, Dmitriy, Neckers, Douglas C, Bettinger, Holger F

“…The photochemical bisdecarbonylation of bridged α-diketones (Strating−Zwanenburg reaction) to give the oligoacenes pentacene (2), hexacene (3), and heptacene…”
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BN-Phenanthryne: Cyclotetramerization of an 1,2-Azaborine Derivative by Müller, Matthias, Maichle-Mössmer, Cäcilia, Bettinger, Holger F.

“…Thermolysis of 9‐azido‐9‐borafluorene in heptane solution produces the tetramer of a BN‐phenanthryne. The isolation of the self‐trapping product provides…”
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The Longest Acenes by Bettinger, Holger F., Tönshoff, Christina

“…For a long time, the largest known member of the acene series was hexacene, consisting of six linearly fused benzene rings. The next higher member, heptacene,…”
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Synthesis and Characterization of a Boron–Nitrogen−Boron Zigzag-Edged Benzo[fg]tetracene Motif by Fingerle, Michael, Maichle-Mössmer, Cäcilia, Schundelmeier, Simon, Speiser, Bernd, Bettinger, Holger F

“…The boron–nitrogen−boron (BNB) zigzag edged benzo­[fg]­tetracene is accessible from 4-butyl-2,6-diphenylaniline in four steps in good yields. The two mesityl…”
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On-Surface Synthesis of BN-Substituted Heteroaromatic Networks by Sánchez-Sánchez, Carlos, Brüller, Sebastian, Sachdev, Hermann, Müllen, Klaus, Krieg, Matthias, Bettinger, Holger F, Nicolaï, Adrien, Meunier, Vincent, Talirz, Leopold, Fasel, Roman, Ruffieux, Pascal

“…We report on the bottom-up fabrication of BN-substituted heteroaromatic networks achieved by surface-assisted polymerization and subsequent…”
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The Dewar Isomer of 1,2‐Dihydro‐1,2‐azaborinines: Isolation, Fragmentation, and Energy Storage by Edel, Klara, Yang, Xinyu, Ishibashi, Jacob S. A., Lamm, Ashley N., Maichle‐Mössmer, Cäcilia, Giustra, Zachary X., Liu, Shih‐Yuan, Bettinger, Holger F.

“…The photochemistry of 1,2‐dihydro‐1,2‐azaborinine derivatives was studied under matrix isolation conditions and in solution. Photoisomerization occurs…”
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Synthesis and Photodimerization of 2- and 2,3-Disubstituted Anthracenes: Influence of Steric Interactions and London Dispersion on Diastereoselectivity by Geiger, Thomas, Haupt, Anne, Maichle-Mössmer, Cäcilia, Schrenk, Claudio, Schnepf, Andreas, Bettinger, Holger F

“…There is increased evidence that the effect of bulky groups in organic, organometallic, and inorganic chemistry is not only repulsive but can be attractive…”
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Hexacene on Cu(110) and Ag(110): Influence of the Substrate on Molecular Orientation and Interfacial Charge Transfer by Sättele, Marie S, Windischbacher, Andreas, Greulich, Katharina, Egger, Larissa, Haags, Anja, Kirschner, Hans, Ovsyannikov, Ruslan, Giangrisostomi, Erika, Gottwald, Alexander, Richter, Mathias, Soubatch, Serguei, Tautz, F. Stefan, Ramsey, Michael G, Puschnig, Peter, Koller, Georg, Bettinger, Holger F, Chassé, Thomas, Peisert, Heiko

“…Hexacene, composed of six linearly fused benzene rings, is an organic semiconductor material with superior electronic properties. The fundamental understanding…”
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Demonstrating the Impact of the Adsorbate Orientation on the Charge Transfer at Organic–Metal Interfaces by Boné, Thomas Georg, Windischbacher, Andreas, Sättele, Marie S, Greulich, Katharina, Egger, Larissa, Jauk, Thomas, Lackner, Florian, Bettinger, Holger F, Peisert, Heiko, Chassé, Thomas, Ramsey, Michael G, Sterrer, Martin, Koller, Georg, Puschnig, Peter

“…Charge-transfer processes at molecule–metal interfaces play a key role in tuning the charge injection properties in organic-based devices and thus, ultimately,…”
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Synthesis of the [11]Cyclacene Framework by Repetitive Diels–Alder Cycloadditions by Bauer, John B., Diab, Fatima, Maichle-Mössmer, Cäcilia, Schubert, Hartmut, Bettinger, Holger F.

“…The Diels–Alder cycloaddition between bisdienes and bisdienophile incorporating the 7-oxa-bicyclo[2.2.1]heptane unit are well known to show high…”
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Superelectrophilicity of 1,2‐Azaborine: Formation of Xenon and Carbon Monoxide Adducts by Edel, Klara, Ishibashi, Jacob S. A., Liu, Shih‐Yuan, Bettinger, Holger F.

“…The BN analogue of ortho‐benzyne, 1,2‐azaborine, is shown to bind carbon monoxide and a xenon atom under matrix isolation conditions, demonstrating its…”
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Solvation of Large Polycyclic Aromatic Hydrocarbons in Helium: Cationic and Anionic Hexabenzocoronene by Kappe, Miriam, Calvo, Florent, Schöntag, Johannes, Bettinger, Holger F, Krasnokutski, Serge, Kuhn, Martin, Gruber, Elisabeth, Zappa, Fabio, Scheier, Paul, Echt, Olof

“…The adsorption of helium on charged hexabenzocoronene (Hbc, C H ), a planar polycyclic aromatic hydrocarbon (PAH) molecule of symmetry, was investigated by a…”
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Bridging the Gap between Pentacene and Perfluoropentacene: Synthesis and Characterization of 2,3,9,10-Tetrafluoropentacene in the Neutral, Cationic, and Dicationic States by Shen, Bin, Geiger, Thomas, Einholz, Ralf, Reicherter, Florian, Schundelmeier, Simon, Maichle-Mössmer, Cäcilia, Speiser, Bernd, Bettinger, Holger F

“…The thermal and photochemical syntheses of 2,3,9,10-tetrafluoropentacene (F4PEN) from 6,13-etheno bridged precursors were investigated computationally and…”
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1,2-Azaborine: The Boron-Nitrogen Derivative of ortho-Benzyne by Edel, Klara, Brough, Sarah A., Lamm, Ashley N., Liu, Shih-Yuan, Bettinger, Holger F.

“…The BN analogue of ortho‐benzyne, 1,2‐azaborine, is generated by flash vacuum pyrolysis, trapped under cryogenic conditions, and studied by direct…”
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