Search Results - "Betham, Michael"
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N-H Carbazole Synthesis from 2-Chloroanilines via Consecutive Amination and C−H Activation
Published in Journal of organic chemistry (08-12-2006)“…N-H carbazoles can be produced from 2-chloroanilines and aryl bromides via consecutive catalytic amination and C−H activation. In many instances, this can be…”
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Simple rhodium-chlorophosphine pre-catalysts for the ortho-arylation of phenols
Published in Chemical communications (Cambridge, England) (01-01-2008)“…Simple chlorodiisopropylphosphine adducts of rhodium, either pre-formed or formed in situ, prove to be highly effective catalysts for the ortho-arylation of…”
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Simple Palladacyclic and Platinacyclic Catalysts for the 1,4-Conjugate Addition of Arylboronic Acids and Arylsiloxanes to Enones
Published in Organometallics (03-12-2007)“…A range of palladacyclic, platinacyclic, and pincer-based catalysts have been tested for activity in 1,4-conjugate addition reactions. π-Acidic palladacycles…”
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Iron−Phosphine, −Phosphite, −Arsine, and −Carbene Catalysts for the Coupling of Primary and Secondary Alkyl Halides with Aryl Grignard Reagents
Published in Journal of organic chemistry (03-02-2006)“…Simple catalysts formed in situ from iron chloride and a wide range of monodentate and bidentate phosphines and arsines have been screened in the coupling of…”
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Solvent-free aerobic oxidative cleavage of methyl oleate to biobased aldehydes over mechanochemically synthesized supported AgAu nanoparticles
Published in ChemPlusChem (Weinheim, Germany) (01-10-2023)“…The performance of mechanochemically synthesized supported bimetallic AgAu nanoalloy catalysts was evaluated in the oxidative cleavage of methyl oleate, a…”
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Intramolecular direct arylation in the synthesis of fluorinated carbazoles
Published in Tetrahedron (23-06-2008)“…The amination of 2-chloroanilines with aryl bromides and subsequent intramolecular direct arylation can be exploited in the synthesis of a range of fluorinated…”
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Hydroxylamine O-benzyl ether as an ammonia equivalent in the catalytic amination of aryl halides
Published in Tetrahedron letters (17-12-2007)“…Hydroxylamine O-benzyl ether acts as an effective ammonium surrogate in the amination of aryl bromides. The palladium catalysed amination of aryl bromides with…”
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Anion complexation via C-H...X interactions using a palladacyclic receptor
Published in Chemical communications (Cambridge, England) (07-06-2008)“…A novel organometallic receptor binds anions in solution and in the solid state, with complexes stabilised through a series of C-HX interactions, as evidenced…”
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An evaluation of phosphine and carbene adducts of phosphite- and phosphinite-based palladacycles in the coupling of alkyl bromides with aryl boronic acids
Published in Tetrahedron (10-10-2005)“…A range of palladacyclic catalysts and their phosphine and carbene adducts were tested in the Suzuki coupling of an alkyl bromide with phenylboronic acid and…”
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Asymmetric styrene dimerisation using mixed palladium–indium catalysts
Published in Tetrahedron (10-10-2005)“…Catalysts formed in situ from mixtures of palladium acetate, indium(III) triflate and a chiral non-chelating bis(phosphite) ligand give good to excellent…”
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Ruthenium PCP–bis(phosphinite) pincer complexes
Published in Inorganica Chimica Acta (10-04-2006)“…The reactions of [RuHCl(CO)(PPh 3) 3] with resorcinol bis(phosphinite) pincer ligands lead to complexes of the general formula [RuCl(PCP)(CO)(PPh 3)]…”
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The influence of steric bulk on the geometry of triarylphosphite-based palladacycles and their tricyclohexylphosphine adducts
Published in Polyhedron (06-03-2006)“…An exploration of the role of steric bulk on the synthesis and geometries of both simple triarylphosphite palladium (II) complexes ( A) and their dimeric…”
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Remarkable Differences in Catalyst Activity and Selectivity for the Production of Methyl Propanoate versus CO−Ethylene Copolymer by a Series of Palladium Complexes of Related C4-Bridged Diphosphines
Published in Organometallics (27-11-2000)“…The C4-bridged diphosphines cis- and trans-1,2-bis(diphenylphosphinomethyl)cyclohexane (cis, 1a; trans, 1b) and…”
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