Search Results - "Bernardinelli, Gerald"

Enantioselective Organocatalytic Conjugate Addition of Aldehydes to Vinyl Sulfones and Vinyl Phosphonates as Challenging Michael Acceptors by Sulzer‐Mossé, Sarah, Alexakis, Alexandre, Mareda, Jiri, Bollot, Guillaume, Bernardinelli, Gerald, Filinchuk, Yaroslav

“…Chiral framework: Chiral amines with pyrrolidine frameworks catalyze the enantioselective conjugate addition of a wide range of aldehydes to various vinyl…”
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Effective Concentration as a Tool for Quantitatively Addressing Preorganization in Multicomponent Assemblies:  Application to the Selective Complexation of Lanthanide Cations by Canard, Gabriel, Koeller, Sylvain, Bernardinelli, Gérald, Piguet, Claude

“…The beneficial entropic effect, which may be expected from the connection of three tridentate binding units to a strain-free covalent tripod for complexing…”
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The Use of N-Alkyl-2,2′-bipyrrolidine Derivatives as Organocatalysts for the Asymmetric Michael Addition of Ketones and Aldehydes to Nitroolefins by Andrey, Olivier, Alexakis, Alexandre, Tomassini, Axel, Bernardinelli, Gerald

“…The direct Michael addition of aldehydes and ketones to nitroolefins, catalyzed by N‐i‐Pr‐2,2′‐bipyrrolidine, is described. The desired 1,4‐adducts are…”
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C3 Vanadium(V) Amine Triphenolate Complexes: Vanadium Haloperoxidase Structural and Functional Models by MBA, Miriam, PONTINI, Marta, LOVAT, Silvia, ZONTA, Cristiano, BERNARDINELLI, Gerald, KÜNDIG, Peter E., LICINI, Giulia

“…The C 3 vanadium(V) amine triphenolate complex 1f has been characterized as a structural and functional model of vanadium haloperoxidases. The complex…”
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Chiral ruthenium Lewis acid-catalyzed nitrile oxide cycloadditions by Brinkmann, Yasmin, Madhushaw, Reniguntala J., Jazzar, Rodolphe, Bernardinelli, Gerald, Kündig, E. Peter

“…The synthesis of the chiral ligand ( R, R)-BIPHOP-F is detailed. Its coordination to a cationic cyclopentadienyl ruthenium fragment generates [Ru (acetone)( R,…”
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Asymmetric ruthenium-catalyzed 1,4-additions of aryl thiols to enones by Bădoiu, Andrei, Bernardinelli, Gerald, Besnard, Céline, Kündig, E Peter

“…Well defined, stable, one-point binding ruthenium complexes and selectively bind and activate alpha,beta-unsaturated carbonyl compounds for cycloaddition…”
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Iron- and Ruthenium-Lewis Acid Catalyzed Asymmetric 1,3-Dipolar Cycloaddition Reactions between Enals and Diaryl Nitrones by Bădoiu, Andrei, Bernardinelli, Gerald, Mareda, Jiri, Kündig, E. Peter, Viton, Florian

“…The highly tuned, one‐point binding cationic cyclopentadienyl‐iron and ‐ruthenium complexes 1 and 2 that incorporate chiral bidentate…”
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An Iminoboronate Construction Set for Subcomponent Self-Assembly by Hutin, Marie, Bernardinelli, Gérald, Nitschke, Jonathan R.

“…Recently we have demonstrated a series of systems in which complex structures were created from simple amine and aldehyde subcomponents by copper(I)‐templated…”
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Cyclometalated Iridium(III) Complexes as Photosensitizers for Long-Range Electron Transfer: Occurrence of a Coulomb Barrier by Hanss, David, Freys, Jonathan C., Bernardinelli, Gérald, Wenger, Oliver S.

“…Six cyclometalated iridium(III) complexes were investigated to assess their potential as photosensitizers for long‐range electron transfer, and two of them…”
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Racemic and Enantiopure Synthesis and Physicochemical Characterization of the Novel Taste Enhancer N-(1-Carboxyethyl)-6-(hydroxymethyl)pyridinium-3-ol Inner Salt by Villard, Renaud, Robert, Fabien, Blank, Imre, Bernardinelli, Gérald, Soldo, Tomislav, Hofmann, Thomas

“…Convenient syntheses were developed to obtain on a multigram scale the novel taste enhancer N-(1-carboxyethyl)-6-(hydroxymethyl)pyridinium-3-ol 1, called…”
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A Straightforward, One-Pot Protocol for the Synthesis of Fused 3-Aminotriazoles by Comas, Horacio, Bernardinelli, Gérald, Swinnen, Dominique

“…A simple protocol for the synthesis of 3-amino-[1,2,4]triazolo[4,3-a]pyridines is reported. The newly developed one-pot methodology involves the reaction of…”
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Helicate, Macrocycle, or Catenate: Dynamic Topological Control over Subcomponent Self-Assembly by Hutin, Marie, Schalley, Christoph A., Bernardinelli, Gérald, Nitschke, Jonathan R.

“…The aqueous reaction between equimolar amounts of 2‐(2‐(2‐aminoethoxy)ethoxy)ethanamine, 1,10‐phenanthroline‐2,9‐dialdehyde and copper(I) produced a dimeric…”
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Bulky Chiral Carbene Ligands and Their Application in the Palladium-Catalyzed Asymmetric Intramolecular α-Arylation of Amides by Kündig, E. Peter, Seidel, Thomas M, Jia, Yi-xia, Bernardinelli, Gérald

“…Bring on the big cats: New, C2‐symmetric bulky N‐heterocyclic carbene ligands bring major improvements in the palladium‐catalyzed asymmetric intramolecular…”
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Tetrahedral Assembly with Lanthanides: Toward Discrete Polynuclear Complexes by Hamacek, Josef, Bernardinelli, Gérald, Filinchuk, Yaroslav

“…We report on the preparation of discrete 3D tetrametallic edifices containing trivalent lanthanides (Eu–Lu). Their formation is thermodynamically controlled…”
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Proton-coupled electron transfer from a luminescent excited state by Freys, Jonathan C, Bernardinelli, Gérald, Wenger, Oliver S

“…A luminescent cationic iridium complex with a 2,2'-biimidazole ligand forms hydrogen-bonded 1 : 1 adducts with benzoate anions; photoexcitation of the metal…”
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Non-racemic (scalemic) planar-chiral five-membered metallacycles: routes, means, and pitfalls in their synthesis and characterization by Djukic, Jean-Pierre, Hijazi, Akram, Flack, Howard D, Bernardinelli, Gérald

“…This critical review provides a systematic classification of the synthetic routes to planar-chiral five-membered metallacycles into several routes, namely C-H…”
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New Chiral N-Heterocyclic Carbene Ligands in Palladium-Catalyzed α-Arylations of Amides: Conformational Locking through Allylic Strain as a Device for Stereocontrol by Jia, Yi-Xia, Katayev, Dmitry, Bernardinelli, Gérald, Seidel, Thomas M., Kündig, E. Peter

“…New Enders/Herrmann‐type chiral N‐heterocyclic carbene (NHC) ligands have been developed and applied in asymmetric palladium‐catalyzed intramolecular…”
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Self-Sorting Chiral Subcomponent Rearrangement During Crystallization by Hutin, Marie, Cramer, Christopher J, Gagliardi, Laura, Shahi, Abdul Rehaman Moughal, Bernardinelli, Gérald, Cerny, Radovan, Nitschke, Jonathan R

“…The incorporation of enantiopure 1-amino-2,3-propanediol as a subcomponent into a dicopper double helicate resulted in perfect chiral induction of the…”
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Self‐Assembly of a Trinuclear Luminescent Europium Complex by Zebret, Soumaila, Dupont, Nathalie, Bernardinelli, Gérald, Hamacek, Josef

“…Triangular luminescent box: Self‐assembly of a new multidentate receptor with europium cations results in the formation of trinuclear discrete complexes. X‐ray…”
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Self-Assembly of the First Discrete 3d−4f−4f Triple-Stranded Helicate by Riis-Johannessen, Thomas, Bernardinelli, Gérald, Filinchuk, Yaroslav, Clifford, Sarah, Favera, Natalia Dalla, Piguet, Claude

“…The connection of an additional bidentate chelating unit at the extremity of a segmental bis-tridentate ligand in L5 provides an unprecedented sequence of…”
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