Search Results - "Berlinguette, Curtis P."
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An industrial perspective on catalysts for low-temperature CO2 electrolysis
Published in Nature nanotechnology (01-02-2021)“…Electrochemical conversion of CO 2 to useful products at temperatures below 100 °C is nearing the commercial scale. Pilot units for CO 2 conversion to CO are…”
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CO2 electrochemical catalytic reduction with a highly active cobalt phthalocyanine
Published in Nature communications (09-08-2019)“…Molecular catalysts that combine high product selectivity and high current density for CO 2 electrochemical reduction to CO or other chemical feedstocks are…”
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Electrocatalytic Alloys for CO2 Reduction
Published in ChemSusChem (10-01-2018)“…Electrochemically reducing CO2 using renewable energy is a contemporary global challenge that will only be met with electrocatalysts capable of efficiently…”
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π covalency in the halogen bond
Published in Nature communications (03-07-2020)“…Halogen bonds are a highly directional class of intermolecular interactions widely employed in chemistry and chemical biology. This linear interaction is…”
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Water Oxidation Catalysis: Electrocatalytic Response to Metal Stoichiometry in Amorphous Metal Oxide Films Containing Iron, Cobalt, and Nickel
Published in Journal of the American Chemical Society (07-08-2013)“…Photochemical metal–organic deposition (PMOD) was used to prepare amorphous metal oxide films containing specific concentrations of iron, cobalt, and nickel to…”
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High‐Throughput Synthesis of Mixed‐Metal Electrocatalysts for CO2 Reduction
Published in Angewandte Chemie International Edition (22-05-2017)“…The utilization of CO2 as a feedstock requires fundamental breakthroughs in catalyst design. The efficiencies and activities of pure metal electrodes towards…”
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Photoelectrochemical oxidation of organic substrates in organic media
Published in Nature communications (30-08-2017)“…There is a global effort to convert sunlight into fuels by photoelectrochemically splitting water to form hydrogen fuels, but the dioxygen byproduct bears…”
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Homogeneous water oxidation catalysts containing a single metal site
Published in Chemical communications (Cambridge, England) (01-01-2013)“…The recent recognition that a single metal site is capable of mediating the multiple electron and proton transfer events associated with water oxidation…”
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Facile Photochemical Preparation of Amorphous Iridium Oxide Films for Water Oxidation Catalysis
Published in Chemistry of materials (25-02-2014)“…Light-driven decomposition of Ir(acac)3 spin-cast on a conducting glass substrate produces a thin conformal film of amorphous iridium oxide, a-IrO x . The…”
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Photochemical Route for Accessing Amorphous Metal Oxide Materials for Water Oxidation Catalysis
Published in Science (American Association for the Advancement of Science) (05-04-2013)“…Large-scale electrolysis of water for hydrogen generation requires better catalysts to lower the kinetic barriers associated with the oxygen evolution reaction…”
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Bis(tridentate) Ruthenium–Terpyridine Complexes Featuring Microsecond Excited-State Lifetimes
Published in Journal of the American Chemical Society (01-08-2012)“…A series of heteroleptic bis(tridentate) ruthenium(II) complexes, each bearing a substituted 2,2′:6′,2″-terpyridine (terpy) ligand, is characterized by room…”
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Accounting for the Dynamic Oxidative Behavior of Nickel Anodes
Published in Journal of the American Chemical Society (10-02-2016)“…The dynamic behavior of the anodic peak for amorphous nickel oxy/hydroxide (a-NiO x ) films in basic media was investigated. Chronocoulometry of films with…”
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A self-driving laboratory advances the Pareto front for material properties
Published in Nature communications (22-02-2022)“…Useful materials must satisfy multiple objectives, where the optimization of one objective is often at the expense of another. The Pareto front reports the…”
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Strain Engineering Electrocatalysts for Selective CO2 Reduction
Published in ACS energy letters (12-04-2019)“…Lattice strain can enhance the activity and selectivity of electrochemical reactions by breaking the linear scaling relationship. Notwithstanding, the explicit…”
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Managing Hydration at the Cathode Enables Efficient CO2 Electrolysis at Commercially Relevant Current Densities
Published in ACS energy letters (08-05-2020)“…Gas-fed CO2 electrochemical flow reactors are appealing platforms for the electrolytic conversion of CO2 into fuels and chemical feedstocks at commercially…”
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Bioelectrocatalysis with a palladium membrane reactor
Published in Nature communications (31-03-2023)“…Enzyme catalysis is used to generate approximately 50,000 tons of value-added chemical products per year. Nearly a quarter of this production requires a…”
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Electrolysis of CO2 to Syngas in Bipolar Membrane-Based Electrochemical Cells
Published in ACS energy letters (09-12-2016)“…The electrolysis of CO2 to syngas (CO + H2) using nonprecious metal electrocatalysts was studied in bipolar membrane-based electrochemical cells. Electrolysis…”
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Ring walking as a regioselectivity control element in Pd-catalyzed C-N cross-coupling
Published in Nature communications (24-05-2022)“…Ring walking is an important mechanistic phenomenon leveraged in many catalytic C-C bond forming reactions. However, ring walking has been scarcely studied…”
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Indirect H2O2 synthesis without H2
Published in Nature communications (26-01-2024)“…Industrial hydrogen peroxide (H 2 O 2 ) is synthesized using carbon-intensive H 2 gas production and purification, anthraquinone hydrogenation, and…”
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Electrolytic CO2 Reduction in Tandem with Oxidative Organic Chemistry
Published in ACS central science (26-07-2017)“…Electrochemical reduction of CO2 into carbon-based products using excess clean electricity is a compelling method for producing sustainable fuels while…”
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